WU Sheng-li
,
LIU Xiao-qin
,
ZHOU Qi
,
XU Jian
,
LIU Cheng-song
钢铁研究学报(英文版)
The reduction degradation characteristics of typical sinter, pellet and lump ore were tested with the reducing gas conditions simulating two kinds of iron-making processes. The results show that, in the same condition of gas composition and temperature, the reduction degradation degree (RDI＜3.15 mm) of sinter is high, RDI＜3.15 mm of lump ore is low and RDI＜3.15 mm of pellet is in the middle level. With two kinds of gas composition simulating different iron-making processes, the reduction degradation indices (RDI) of three kinds of iron ores all present the tendency of “inverted V-shape” in the temperature range from 450 to 650 ℃, and the RDI reach the maximum value at 550 ℃. The reduction degradation degrees of iron ores are extended when mixing the gas with hydrogen to increase the reduction potential, and the influence extent is discrepant for different iron ores. Colligating the increase amplitude of grains in small size fraction, the influence of reducing gas on lump ore is the greatest, the influence on sinter is the second, and the sensitivity of pellet on the reducing gas properties change is relatively small. As for the degradation form, lump ore and sinter both present the degradation of cracking, and the distribution of small grains generated from the cracking is in the range from 0.5 to 6.3 mm uniformly. The lump ore presents surface cracking, while sinter presents integral cracking. The pellet presents the degradation of surface stripping, and the proportion of grains smaller than 0.5 mm is the highest, which is up to 90% in the grains smaller than 3.15 mm.
关键词:
sinter
,
pellet
,
lump ore
,
low temperature reduction degradation characteristic
,
gas property
刘守平
,
周上祺
,
王佳眉
,
任勤
腐蚀学报（英文）
用金相显微镜、扫描电镜、X射线衍射仪和X射线能谱仪对天然气井油管悬挂器腐蚀失效进行了检测分析，并对天然气井油管悬挂器用35CrMo钢进行了盐雾试验，结果表明，天然气中的水和CO2是引起腐蚀的主要介质，腐蚀产物主要是FeCO3，高速天然气冲刷和钢中的非金属夹杂加剧了腐蚀的速度.
CORROSION FAILURE ANALYSIS OF AN OIL TUBE USED IN NATURAL GAS WELL
LIU Shou-ping,ZHOU Shang-qi,WANG Jia-mei,REN Qin
Chongqing University
A failed oil tube used in natural gas well was examined by optical microscope,scanning electron microscope ,X-ray diffractometer and X-ray spectrometer.Corrosion behavior of 35CrMo steel samples of the oil tube were investigated by means of salt spray tests in the laboratory.The results show that CO2 and H2O are primary factors in the corrosion of oil tube.The corrosion product is FeCO3,non-metallic inclusions in the steel and erosion of natural gas fluid played an important role in accelerating the corrosion.
oil tube;
natural gas well；
35CrMo steel；
failure analysis；
corrosion
关键词:
悬挂器
,
null
,
null
,
null
徐卫兵
,
戈明亮
,
何平笙
应用化学
doi:10.3969/j.issn.1000-0518.2001.09.011
用熔融插层法制备聚甲醛/蒙脱土纳米复合材料,用X射线衍射研究聚甲醛及复合材料的微观结构,表明复合材料是纳米复合材料.用DSC法研究其非等温结晶行为,对所得数据分别用Jeziorny法、Ozawa法和Liu法进行处理.结果表明,Jeziorny法和Liu法处理非等温结晶过程比较理想.聚甲醛及聚甲醛/有机蒙脱土纳米复合材料的结晶活化能分别为334.6和196.9 kJ/mol,说明有机蒙脱土的加入,降低了聚甲醛的结晶活化能,且t1/z缩短,起到了异相成核的作用.
关键词:
聚甲醛
,
蒙脱土
,
纳米复合材料
,
非等温结晶动力学
王平华
,
徐国永
应用化学
doi:10.3969/j.issn.1000-0518.2004.08.007
用熔融复合法制备聚丙烯/凹凸棒土纳米复合材料,用DSC法研究其非等温结晶行为,对所得的数据分别用Jeziorny法、Ozawa法和Liu法进行处理.结果表明,Jeziorny法和Liu法处理非等温结晶过程比较理想.聚丙烯及聚丙烯/凹凸棒土纳米复合材料的结晶活化能分别为194.1和162.8 kJ/mol,表明凹凸棒土的加入,降低了聚丙烯的结晶活化能,且t1/2缩短,起到了异相成核作用.
关键词:
聚丙烯
,
凹凸棒土
,
纳米复合材料
,
非等温结晶动力学
Scripta Materialia
A recent comment on a previously published paper addressed the invalid explanation of the off diagonal interdiflusion coefficients of the beta-Ni(Al,Cr) phase in the Ni-Cr-Al system according to the symmetric property of the thermodynamic matrix. In this paper, the experimental data presented by Hou et al. was reanalyzed and the interdiffusion coefficient matrix was estimated again. The results of the analysis have been discussed in terms of a brief reply to the comments of Liu and Liang. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
关键词:
Diffusion;Intermetallic compound;Ni-Cr-Al
邓超
,
邵玮
,
李春忠
高分子材料科学与工程
采用元机纳米锑掺杂二氧化锡(ATO)和有机聚醚酯(PEE)协同提高聚时苯二甲酸乙二酯(PET)的抗静电性能,合成了聚对苯二甲酸乙二酯-聚醚酯/锑掺杂二氧化锡纳米复合材料(PET-PEE/ATO).使用Czawa方程和Liu-Mo方程研究了PET-PEE/ATO纳米复合材料的非等温结晶过程.Ozawa方程研究发现,在非等温结晶过程中,PET、PET-PEE、PET/ATO、PET-PEE/ATO的成核性能依次提高.Liu-Mo方程发现,ATO和PEE的加入分别促进了异相成核作用和加快了结晶生长,PET-PEE/ATO结晶成核性能最好,结晶速率最快.
关键词:
聚对苯二甲酸乙二酯
,
有机聚醚酯
,
无机纳米锑掺杂二氧化锡
,
纳米复合材料
,
非等温结晶动力学
席俊华
,
季振国
,
刘坤
,
王超
,
杜鹃
无机材料学报
doi:10.3724/SP.J.1077.2006.01506
利用溶胶-凝胶法结合高温热处理在硅衬底上制备了掺Mn硅酸锌薄膜, 用XRD、SEM、UV-Vis吸收谱和PL谱测试了样品的结晶性能与光学性能, 并分析了热处理温度对掺Mn硅酸锌薄膜的结晶性能和光学性能的影响. 实验结果发现, ZnO的适量存在对掺Mn薄膜的发光有增强作用. 进一步的分析认为, 这一现象的机理可由G.G. Qin提出的量子约束-发光中心 (QCLC) 模型进行解释, ZnO中受激发的电子和空穴通过隧穿效应到达硅酸锌基体中复合发光, 从而增强发光强度.
关键词:
硅酸锌
,
ZnO
,
photoluminescence
,
quantum confinement-luminescence center
Materials Research Bulletin
Through analysis of the latest experimental results reported in the literature and obtained in our laboratory, we have extended our previous quantum confinement/luminescence center model for the photoluminescence mechanism of porous Si and of nanometer-silicon-particle-embedded Si oxide films (G.G. Qin and Y.Q. Jia, Solid State Commun. 86, 559 (1993)). We consider that there are three main types of competitive photoexcitation/photoemission processes and that the process in which photoexcitation occurs in the nanometer silicon particles (NSPs) while photoemission occurs in the luminescence centers (LCs) in the SiOx layers very close to the NSPs is usually the major one. We discuss under what conditions the other two types of processes will dominate. We believe that the extended quantum confinement/luminescence center model is a physical model that is suitable for the photoluminescence from silicon oxide films embedded with NSPs or nanometer Ge particles (NGPs), as well as from oxidized porous Si. (C) 1999 Elsevier Science Ltd.
关键词:
oxides;luminescence;defects;blue-light emission;visible luminescence;optical-properties;nanocrystals;mechanism;dependence;sio2-films;absorption;spectra;defects
