LIN Guangming HUANG Yuanshi ZHANG Jinxiu Zhongshan University
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Guangzhou
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China LIN Guangming
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Associate Professor
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Dept.of Physics
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Zhongshan University
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Guangzhou 510275
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China
金属学报(英文版)
The snap-acting transition and two way shape memory (TWSM) effect have been obtained in a TWSM spring made of Ni51Ti49 alloy using the constrained effect of stress on driving force of TWSM material.When the snap-acting transition has been realized:M_s= M_f and A_s=A_f;hysteresis is rectangular,the height (TWSM effect) and width (hysteresis) of the rectangle can be readjusted by means of constrained stress.The results of resistance measurments show that,the snap-acting TWSM effect mentioned above was supplied mainly from the transformation of P←→R.The thermodynamic model has also been proposed to ac- count for the snap-acting transformation.
关键词:
transformation thermodynamics
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中国腐蚀与防护学报
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关键词:
刘欣艳
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赵煜娟
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夏定国
功能材料
LiNi0.8Co0.2O2是锂离子电池界公认的最有希望取代商业化正极材料LiCoO2的新型正极材料之一.本文所研究的复合正极材料LiNi0.8Co0.2O2是由细小的晶粒构成的球形颗粒,单一相,属于R3m空间群.对复合材料LiNi0.8Co0.2O2的Co-K和Ni-K的XANES分析可知,在600~850℃范围温度对于钴元素的影响不明显,而对于镍元素的影响比较显著,随着Ni-K边位置向高能量移动LiNi0.8Co0.2O2正极材料的放电容量升高.复合材料LiNi0.8Co0.2O2和LiNiO2的Ni-K边XANES相似,表明少量钴的引入对晶体结构的改变不是太多,但是峰的强度较高和峰的位置向高能量移动,表明钴Co对Ni的局域结构进行了调制.
关键词:
LiNi0.8Co0.2O2
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XANES
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正极材料
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局域结构