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TRANSFORMATION CHARACTERISTIC OF TWO WAY SHAPE MEMORY MATERIAL CONSTRAINED BY STRESS

LIN Guangming HUANG Yuanshi ZHANG Jinxiu Zhongshan University , Guangzhou , China LIN Guangming , Associate Professor , Dept.of Physics , Zhongshan University , Guangzhou 510275 , China

金属学报(英文版)

The snap-acting transition and two way shape memory (TWSM) effect have been obtained in a TWSM spring made of Ni51Ti49 alloy using the constrained effect of stress on driving force of TWSM material.When the snap-acting transition has been realized:M_s= M_f and A_s=A_f;hysteresis is rectangular,the height (TWSM effect) and width (hysteresis) of the rectangle can be readjusted by means of constrained stress.The results of resistance measurments show that,the snap-acting TWSM effect mentioned above was supplied mainly from the transformation of P←→R.The thermodynamic model has also been proposed to ac- count for the snap-acting transformation.

关键词: transformation thermodynamics , null , null , null

1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....

关键词:

表面包覆法合成的LiN0.8Co0.2O2材料的结构表征

刘欣艳 , 赵煜娟 , 夏定国

功能材料

LiNi0.8Co0.2O2是锂离子电池界公认的最有希望取代商业化正极材料LiCoO2的新型正极材料之一.本文所研究的复合正极材料LiNi0.8Co0.2O2是由细小的晶粒构成的球形颗粒,单一相,属于R3m空间群.对复合材料LiNi0.8Co0.2O2的Co-K和Ni-K的XANES分析可知,在600~850℃范围温度对于钴元素的影响不明显,而对于镍元素的影响比较显著,随着Ni-K边位置向高能量移动LiNi0.8Co0.2O2正极材料的放电容量升高.复合材料LiNi0.8Co0.2O2和LiNiO2的Ni-K边XANES相似,表明少量钴的引入对晶体结构的改变不是太多,但是峰的强度较高和峰的位置向高能量移动,表明钴Co对Ni的局域结构进行了调制.

关键词: LiNi0.8Co0.2O2 , XANES , 正极材料 , 局域结构

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