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Mechanical behaviour and microstructure evolution of superplastic Mg-8.4 wt pct Li alloy and effect of grain size and phase ratio on its elongation

Furong CAO , Jianzhong CUI , Jinglin WEN , Fang LEI

材料科学技术(英文)

Mechanical properties and microstructure evolution of Mg-8.4 wt pet Li alloy have been investigated. The superplastic elongation-to-failure 920% at 573 K and initial strain rate of 5 x 10(-4) s(-1) at low nominal stress 2 MPa has been demonstrated. It was shown through optical microstructure that the average grain sizes at gauge length section before and after superplastic tension and at grip section were 7.5 mu m, 31.7 mu m and 20 mu m respectively, indicating significant deformation induced grain growth and static grain growth. Comparison of experiment data with published data for superplastic Mg-Li alloys shows that fine grain size and about 50 to 50 phase ratio contribute to achieving the largest superplasticity. Some related research works in other alloys are compiled and further evidences to such theoretic argument are provided.

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ON SPINODAL BOUNDARIES OF Al-Li ALLOYS

WEI Yinghui , WANG Xiaotian (School of Materials Scince and Engineering , Xi'an Jiaotong University , Xi'an 710049 , China Manuscript received 10 Mareh , 1994)

金属学报(英文版)

The spinodal decomposition can occur in Al-Li alloys containing 5.8-14.2 at.% Li at room temperature. The modutated structure wavelength is approximately 3.1 nm for com mercial Al-LI alloys. The limit composition of the miscibility gap is 3.66 -16.06 at.%Li at 298 K. The highest temperature of the miscibility gap is 377 K.

关键词: : Al-Li alloy , null , null

大爆炸核合成相关的8Li(d, p)9Li反应截面测量

李志宏 , 柳卫平 , 白希祥 , 郭冰 , 连钢 , 颜胜权 , 王宝祥 , 陆昀 , 曾晟 , 苏俊

原子核物理评论 doi:10.3969/j.issn.1007-4627.2005.01.006

利用8Li次级束测量了质心系能量7.8 MeV 2H(8Li, 9Li)1H反应的角分布, 导出了8Li(d, p)9Li反应的天体物理S因子及9Li→8Li+n虚衰变的渐近归一化系数.

关键词: 8Li(d,p)9Li反应 , 角分布 , 天体物理S因子 , 渐近归一化系数

CRYSTAL STRUCTURE OF γ-Li_xFe_2O_3 WITH ELECTROCHEMICAL INSERTION OF Li

HUANG Jianshun CHEN Junming Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , China Research Associate , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai 200050 , China

金属学报(英文版)

Crystal structure of γ-Li_xFe_2O_3,inserted Li electrochemically,was studied by Moss- bauer spectroscopy together with X-ray diffraction,XPS and electrochemical method,On the insertion of Li at low current density,the crystal structure is keeping original spinel; while at higher current density or by thermal activation,owing to violent movement of Li~+ ions,part of crystal structure transforms into rock type similar to face-centered cubic structure of ferrous oxide.The transition channels during insertion of Li~+ ions and limitation of Li~+ ions inserted were discussed.

关键词: null , null , null

STRUCTURE FEATURES IN BINARY-LIQUID LI-TL ALLOYS

Journal of Chemical Physics

With the help of potential mapping techniques, molecular dynamics simulations have been performed to study the local structure features in binary liquid Li-Tl alloys. The generalized nonlocal model pseudopotentials have been chosen as the bases for our calculations. Both the bond orientational order and pair analysis approach have been adopted as the basic structural functions to examine the structure features in binary liquid Li-Tl alloys. In addition, bonded pairs with various symmetries, icosahedra, defective icosahedra, Frank-Kasper polyhedra, etc., formed in the Li-Tl alloys are examined in detail, and the relationship between the structure features and composition has been established. The results show that the distribution of attractive parts of the potentials play an important role in characterizing the Liquid structure. Finally, the results are discussed in detail. (C) 1995 American Institute of Physics.

关键词: variational thermodynamic calculations;bond-orientational order;rapidly quenched metals;molecular-dynamics;sd metals;glasses;crystallization;transitions;solids

Electrochemical impedance studies of the initial-stage corrosion of 310S stainless steel beneath thin film of molten (0.62Li, 0.38K)(2)CO(3) at 650 degrees C

Corrosion Science

Electrochemical impedance spectroscopy (EIS) has been used to study the initial-stage corrosion of 310S stainless steel beneath thin film of molten (0.62Li, 0.38 K)(2)CO(3) at 650 degrees C in air. Two-electrode system is used to fabricate molten-salt film. The thickness of molten salt approximated from electrolyte resistance decreases rapidly until it is smaller than 6 mg/cm(2). The appearance of diffusion-related impedance at the end of the test is linked to the severe loss of molten salt which causes twisted diffusion paths. More molten salt on the surface of 310S causes a longer lithiation process and more profound degradation of the oxide film. (C) 2010 Elsevier Ltd. All rights reserved.

关键词: Stainless steel;Molten salts;EIS;Hot corrosion;surface characterization methods;bipolar plate materials;carbonate;fuel-cells;hot-corrosion;alkali carbonates;polarization curves;ni;alloy;temperature;air

Al—Li合金的晶界断裂

姚大平 , 张匀 , 胡壮麒 , 李依依

材料研究学报

本文研究了两种晶粒组织的二元Al-Li 合金拉伸性能与断裂行为。结果表明Al-Li 合金力学性能与晶粒尺寸有关,其断裂行为决定于PFZ 内平面滑移或晶界沉淀相与滑移的交互作用。

关键词: Al—Li合金 , intergranular fracture , planar slip

Effect of Li(3)N additive on the hydrogen storage properties of Li-Mg-N-H system

Journal of Materials Research

The effect of Li(3)N additive on the Li-Mg-N-H system was examined with respect to the reversible dehydrogenation performance. Screening Study with varying Li(3)N additions (5, 10, 20, and 30 mol%) demonstrates that all are effective for improving the hydrogen desorption capacity. Optimally, incorporation of 10 mol% Li(3)N improves the practical capacity from 3.9 wt% to approximately 4.7 wt% hydrogen at 200 degrees C, which drives the dehydrogenation reaction toward completion. Moreover, the capacity enhancement persists well over 10 de-/rehydrogenation cycles. Systematic x-ray diffraction examinations indicate that Li(3)N additive transforms into LiNH(2) and LiH phases and remains during hydrogen cycling. Combined structure/property investigations suggest that the LiNH(2) "seeding" should be responsible for the capacity enhancement, which reduces the kinetic barrier associated with the nucleation of intermediate LiNH(2). In addition, the concurrent incorporation of LiH is effective for mitigating the ammonia release.

关键词: complex hydrides;improvement;mixtures;imides;amide;h-2

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