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Corrosion Resistance of High Performance Weathering Steel for Bridge Building Applications

CHEN Ai-hua , XU Jian-qiu , LI Ran , LI Hua-long

钢铁研究学报(英文版)

The mechanical properties, corrosion resistance and microstructures of high performance steel (HPS) was investigated by tensile testing machine, Charpy V-Notch (CVN) testing machine, cyclic immersion corrosion tester, XRD, optical microscopy (OM), scanning electron microscopy (SEM), and electron probe micro-analyzer (EPMA). The results showed that significant differences existed in the tensile strength, yield strength and impact toughness between HPS and PCS. After 72 h cyclic immersion accelerated corrosion test, the inner rust layer on HPS was composed of α-FeOOH phase and denser than that on PCS that was a mixture of α-FeOOH and Fe3O4. The rust formed on HPS provides better protection and HPS has lower corrosion rates than PCS. Copper and chromium in HPS enrich in the rust layer and enhance the compactness of the rust layer. Based on the results of the accelerated corrosion tests and rust layer analysis, the roles of Cu and Cr against corrosion are discussed, providing HPS with chemical specification which has been industrially successful to produce weathering steel for bridge structure.

关键词: HPS , corrosion resistance , microstructure , mechanical property

Effects of Rolling Processes on Yield Ratio and Formability of Hot Rolled Gas Cylinder Steel

JIA Yue-cai , GUO Hai-rong , LI Ran , LI Hua-long

钢铁研究学报(英文版)

Deep drawing properties of hot rolled gas cylinder steel was investigated by using HP295 steel in terms of microstructure, texture, yield ratio, plastic strain ratio (r-value) and plastic anisotropy (Δr). The grains in the hot strip were largely equiaxed, and the texture was weak, containing α- and γ-fibre. Reheating temperature, finish rolling temperature and cooling rate after rolling influenced the ferrite-pearlite band formation significantly, and the yield ratio increased steeply with decreasing coiling temperature below 630 ℃. The anisotropy is relatively high due to retained severe ferrite-pearlite band. A mechanism of the band formation due to manganese segregation is elaborated and confirmed validly, from which the measures to avoid the band formation are worked out. Rolling parameters have been optimized by the measures, and industrial production of the gas cylinder steel has been made possible with much improved r-and Δr-values, while meeting other specifications.

关键词: yield ratio , formability , ferrite-pearlite band , texture , plastic anisotropy

ON SPINODAL BOUNDARIES OF Al-Li ALLOYS

WEI Yinghui , WANG Xiaotian (School of Materials Scince and Engineering , Xi'an Jiaotong University , Xi'an 710049 , China Manuscript received 10 Mareh , 1994)

金属学报(英文版)

The spinodal decomposition can occur in Al-Li alloys containing 5.8-14.2 at.% Li at room temperature. The modutated structure wavelength is approximately 3.1 nm for com mercial Al-LI alloys. The limit composition of the miscibility gap is 3.66 -16.06 at.%Li at 298 K. The highest temperature of the miscibility gap is 377 K.

关键词: : Al-Li alloy , null , null

大爆炸核合成相关的8Li(d, p)9Li反应截面测量

李志宏 , 柳卫平 , 白希祥 , 郭冰 , 连钢 , 颜胜权 , 王宝祥 , 陆昀 , 曾晟 , 苏俊

原子核物理评论 doi:10.3969/j.issn.1007-4627.2005.01.006

利用8Li次级束测量了质心系能量7.8 MeV 2H(8Li, 9Li)1H反应的角分布, 导出了8Li(d, p)9Li反应的天体物理S因子及9Li→8Li+n虚衰变的渐近归一化系数.

关键词: 8Li(d,p)9Li反应 , 角分布 , 天体物理S因子 , 渐近归一化系数

CRYSTAL STRUCTURE OF γ-Li_xFe_2O_3 WITH ELECTROCHEMICAL INSERTION OF Li

HUANG Jianshun CHEN Junming Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , China Research Associate , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai 200050 , China

金属学报(英文版)

Crystal structure of γ-Li_xFe_2O_3,inserted Li electrochemically,was studied by Moss- bauer spectroscopy together with X-ray diffraction,XPS and electrochemical method,On the insertion of Li at low current density,the crystal structure is keeping original spinel; while at higher current density or by thermal activation,owing to violent movement of Li~+ ions,part of crystal structure transforms into rock type similar to face-centered cubic structure of ferrous oxide.The transition channels during insertion of Li~+ ions and limitation of Li~+ ions inserted were discussed.

关键词: null , null , null

Al—Li合金的晶界断裂

姚大平 , 张匀 , 胡壮麒 , 李依依

材料研究学报

本文研究了两种晶粒组织的二元Al-Li 合金拉伸性能与断裂行为。结果表明Al-Li 合金力学性能与晶粒尺寸有关,其断裂行为决定于PFZ 内平面滑移或晶界沉淀相与滑移的交互作用。

关键词: Al—Li合金 , intergranular fracture , planar slip

Effect of Li(3)N additive on the hydrogen storage properties of Li-Mg-N-H system

Journal of Materials Research

The effect of Li(3)N additive on the Li-Mg-N-H system was examined with respect to the reversible dehydrogenation performance. Screening Study with varying Li(3)N additions (5, 10, 20, and 30 mol%) demonstrates that all are effective for improving the hydrogen desorption capacity. Optimally, incorporation of 10 mol% Li(3)N improves the practical capacity from 3.9 wt% to approximately 4.7 wt% hydrogen at 200 degrees C, which drives the dehydrogenation reaction toward completion. Moreover, the capacity enhancement persists well over 10 de-/rehydrogenation cycles. Systematic x-ray diffraction examinations indicate that Li(3)N additive transforms into LiNH(2) and LiH phases and remains during hydrogen cycling. Combined structure/property investigations suggest that the LiNH(2) "seeding" should be responsible for the capacity enhancement, which reduces the kinetic barrier associated with the nucleation of intermediate LiNH(2). In addition, the concurrent incorporation of LiH is effective for mitigating the ammonia release.

关键词: complex hydrides;improvement;mixtures;imides;amide;h-2

SUPERPLASTICITY OF A RAPIDLY SOLIDIFIED AI-Li ALLOY

MANG Weishi WANG Guozhi ZHANG Yongchang HU Zhuangqi SHI Changxu Institute of Metal Research , Academia Sinica , Shenyang , China Yongchang Associate Professor , Institute of Metal Research , Academia Sinica , Shenyang 110015 , China

金属学报(英文版)

A rapidly solidified microcrystalline Al-Li-Cu-Mg-Zr alloy and its superplasicity have been investigated.An optimum tensile elongation of 585% was obtained at 540℃ and strain rate 1.67×10~(-2)s~(-1).The superplastic Al-Li alloy is manufaetured using thermomechanical pro- cessing:solution,overaging,warm rolling and recrystallization.Microstructural changes in thermomechanical processing and cavitation occurred during superplastic deformation have been observed.The superplastic failure of alloy may be caused mainly by nucleation and growth of cavities as well as the linkage around grains.

关键词: superplasticity , null , null , null

Al-Li合金强韧化机理及途径

甘卫平 , 周兆锋 , 杨伏良

材料导报

概述了Al-Li合金强韧化的内部机理和外部机理,并在此基础上阐述了提高Al-Li合金强韧性的主要途径.

关键词: Al-Li合金 , 强韧性 , 途径

Preparation of Li-B alloy and study of its microstructure and discharge characteristics

Zhijian LIU , Zhiyou LI , Wei DUAN , Xuanhui QU , Baiyun HUANG , Siqi ZHANG

材料科学技术(英文)

A LI-B alloy has been prepared using a pretreated amorphous B powder and pure Li ingot as starting materials by continually slow addition of B powder and intensified stirring in the process of melting. The microstructure and the discharge characteristic of the materials have been investigated. Results show that the problem of temperature control in synthesis would be modified by means of continual addition of B powder, the Li7B6 would be more finery distributed in the metal Li by means of intensified stirring. The discharge characteristic of the Li-B alloy using amorphous B as starting materials is almost the same with that of using crystalline B.

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