GUO Zhongcheng
,
LIU Hongkang
,
WANG Zhiyin
,
WANG Min(Department of Metallurgy
,
Kunming institute of Technology
,
Kunming 650093
,
China) Manuscript received 8 May 1995
金属学报(英文版)
The Effects of heat treatment temperature on the hardness,wear resistance and structure of the amorphous Ni-W-P-SiC composite coatings have been investigated.The results show that Ni-W-P-SiC composite coatings are amorphous under 300℃, partially crystalline at 300-400℃,and crystalline when heat treatment temperature reaches 400℃,the crystals being fine Ni3P phase particles.The hardness,wear resistance and the crystallization temperature of the composite coatings increase when an additive is added into the bath.The hardness and wear resistance of the coatings increase with increasing heat treatment temperature,and they will reach their peak values when the heat treatment temperature reaches 400℃.Corrosion experiment indicates that the corrosion resistance of amorphous Ni-W-P-SiC composite coatings in various kinds of corrosive media except nitric acid is better than that of stainless steel 1Cr18Ni9Ti.Scanning electron microscopy observation shows that the additive has no effect on the surface appearance of the coatings,but the current density and the pH value have considerable effects on the surface appearance.
关键词:
:electrodeposition
,
null
,
null
Xuefeng YANG
金属学报(英文版)
doi:10.1016/S1006-7191(08)60123-4
The phenomena of tuyere upward-warp have been found at No.6 blast furnace in Kunming Steel Company China after its blow-in, which has made a great impact on the practical production of the furnace. Thus, a number of efforts have been made to elucidate the mechanism of this phenomenon. The results of investigation and tests revealed that the enrichment and expansion of zinc in the tuyere bricks is the main factor leading to the tuyere upward-warp. The eroding behavior of zinc is that the inner structure of the tuyere bricks turns from dense to loose with entering, enriching and expanding of zinc, which forms spot-like→stripe-like→ditch-like→vein-like→tumor-like eroding passage. Additionally, it is found that the sequence of deleterious elements entering the tuyere refractory is K, Na, Zn and Pb, respectively. Finally, the phenomena and process of zinc crystallization and growth in the refractory have been clearly observed and recorded during this investigation.
关键词:
Blast furnace
,
tuyere
,
refractory
,
zinc
,
erosion
,
deleterious elements