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Oxygen Behavior in Bulk Amorphous Zr-base Alloy

Keqiang QIU , Qingsheng ZHANG , Aimin WANG , Haifeng ZHANG , Bingzhe DING , Zhuangqi HU

材料科学技术(英文)

Bulk Zr55Al10Ni5Cu30 metallic glass plates with a dimension of 85mm×35mm×4mm and a complicated plate were fabricated by injecting casting method using spongy zirconium and industrial purity aluminum, nickel and copper as raw materials. It was shown that the holding time of liquid metals at elevated temperatures had a great influence on the oxygen content of the plates due to the contamination resulting from the atmosphere. Increasing holding time resulted in the increase of oxygen content in the injected alloy. The glass transition temperatures of the bulk metallic glass plates are higher than that reported in the literature and crystallization temperature is lower for the one with higher oxygen content at the same heating rate. The extension of the undercooled liquid region ΔTX reaching about 87 K is 3 K higher than that previously reported and 26 K higher than that with oxygen content of 0.076 wt pct for the one with oxygen content as high as 0.065 wt pct. Therefore the oxygen content of the alloy has a significant influence on the glass forming ability and thermal stability of bulk metal glass. It is suggested that direct correlation between high glass forming ability and large ΔTX is only valid for a well-defined low oxygen concentration or has to be reconsidered by incorporating oxygen as an additional alloying element.

关键词: Zr-base amorphous alloy , null , null

强旋流中颗粒运动特性的直接数值模拟

桂南 , 樊建人 , 陈松

工程热物理学报

本文采用直接数值模拟计算了Re=669,S=1.42强旋流中的颗粒运动特性.计算的部分流动条件依照SommerfeId & Qiu的实验条件进行模化.模拟的结果揭示了旋流近场的颗粒运动的浓度、速度的时均量和脉动值的统计分布特性.

关键词: 旋流 , 颗粒运动 , 直接数值模拟 , 统计特性

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