材料期刊网

Surface Carbon Chemical States of Ion Implanted AISI 440C Martensitic Stainless Steel

Jie JIN , Feng-bin LIU , Yun-bo CHEN , Ke-wei GAO

钢铁研究学报

关键词:

La对Fe-P-N合金Snoek-Ke-K■ster峰的影响

戢景文 , 魏全金 , 张国福 , 赖祖涵 , 陈廷国

金属学报

研究了F? P—N合金加?对Snoek—Ke-Koster(SKK)峰的影响,发现与合金含La,P的原子浓度比(C_(La)/C_p)有关:对于C_(La)/C_p较大(例如4.56和2.6)的合金,La有明显增强SKK阻?效应:对于C_(La)/C_p=0.27的P过饱和合金,La对SKK峰无明显影响。

关键词: 内耗 , Snoek-Ke-Koster peak , Fe-P-La-N alloy

Crystal structure and photoluminescence of Tb3+ doped Y3GaO6

Journal of Alloys and Compounds

A solid solution with formula (Y1-xTbx)(3)GaO6 (x = 0-0.5) was prepared by solid-state reaction method. Powder X-ray diffraction (XRD) shows that Y3GaO6 is isostructural to Gd3GaO6 (Cmc2(1)), and the lattice parameters are a = 8.8364(1) angstrom, b = 11.0899(1) angstrom and c = 5.3937(1) angstrom. Atomic parameters were derived by Rietveld refinement of the XRD pattern. Photoluminescence (PL) spectra show a strong green emission of 543 nm from the D-5(4) -> F-7(5) transition of Th3+ at room and liquid nitrogen temperature. There is a wide saturation range of the PL intensity for the Th3+ content from x = 0.04-0.20, and a long life time about 1200 mu s for the green 543 nm emission at room temperature. (c) 2006 Elsevier B.V. All rights reserved.

关键词: Y3GaO6;crystal structure;Tb3+ doped;photoluminescence;luminescence properties;dependence;y3al5o12;phosphor;ions;ce3+;tb-3;uv

A systematic study on crystal structure and magnetic properties of Ln(3)GaO(6) (Ln = Nd, Sm, Eu, Gd, Tb, Dy, Ho and Er)

Journal of Solid State Chemistry

The crystal structures of a series of compounds with the composition Ln(3)GaO(6)(Ln = Nd, Sm, Eu, Gd, Tb, Dy, Ho and Er) synthesized by solid-state reaction at 1400degreesC are investigated. X-ray diffraction shows that Ln3GaO6 has a non-centro symmetric orthorhombic structure (space group Cmc2(1)). Lattice parameters a, b, c and cell volume and the average distances between Ln(l)-O, Ln(2)-O of these compounds decrease with the decreasing of the radii of trivalent Ln ions, which accord with the expected lanthanide contraction behavior. There are two sites of seven-fold coordination for Ln atoms with oxygens, and Ga atoms are in oxygen tetrahedra which are distorted and elongated along the a-axis. Magnetization measurements indicate that the susceptibility X changes with temperature in Curie-type manner. (C) 2004 Elsevier Inc. All rights reserved.

关键词: Ln(3)GaO(6);crystal structure;Rietveld refinement;X-ray diffraction;garnets

Optical spectra of Ln(3+)(Nd3+, Sm3+, Dy3+, Ho3+, Er3+)-doped Y3GaO6

Journal of Luminescence

Ln(3+) (Ln = Nd, Sm, Eu, Gd, Dy, Ho, Er)-doped Y3GaO6 compounds were prepared by solid-state reaction, and their optical spectra such as absorption, photoluminescence, excitation and time-resolved spectra have been measured for Ln Nd, Sm, Dy, Ho, Er. X-ray powder diffraction shows that the lattice parameters of the compounds (Y(0.96)Ln(0.04))(3)GaO6 decrease with the decrease of the radii of trivalent Ln(3+) ions, indicating that Ln(3+) ions have substituted for y(3+) ions in the lattice. Optical spectra show that there are obvious absorptions at ultraviolet to visible region. The strong emissions in visible and infra-red region show that Y3GaO6 is a suitable host for rare-earth-doped laser crystal and phosphor materials. (C) 2004 Elsevier B.V. All rights reserved.

关键词: crystal-field;absorption-spectra;luminescence;y3ga5o12;glasses;garnet;y2o3;ions;laf3;tb3

Optical properties of (Y1-xTmx)(3)GaO6 and subsolidus phase relation of Y2O3-Ga2O3-Tm2O3

Journal of Solid State Chemistry

A serial of samples in Y2O3-Ga2O3-Tm2O3 pseudo-ternary system are prepared by solid-state chemical reaction method. The range of solid solution in (Y1-xTmx)(3)GaO6 is 0 < x < 0.384. Powder X-ray diffraction shows that the compounds crystallize in Gd3GaO6 (Cmc2(1))-type structure. The solid solubilities of Y3+xGa5-xO12 (x = 0-0.77) and Tm3+xGa5-xO12 (x = 0-0.62) are 37.5-47.11 at% Y2O3, and 37.5-45.26 at% Tm2O3, respectively. PL spectra of Tm-doped Y3GaO6 show that there is a sharp blue emission at similar to 456 nm from the D-1(2) -> F-3(4) transition at room temperatures with two lifetimes (similar to 5 and similar to 15 mu s) and a narrow saturation range of PL intensity for the Tm3+ content from x = 0.005 to 0.03. The sharp emission and long lifetime of (Y1-xTmx)(3)GaO6 indicate that Y3GaO6 is a potential phosphor and laser crystal host material. (c) 2005 Elsevier Inc. All rights reserved.

关键词: Tm3+ -doped Y3GaO6;Y2O3-Ga2O3-Tm2O3 system;(Y1-xTmx)(3)Ga5O12 solid;solution;luminescence;crystal-structure;luminescence;phosphor;cations;ions;tb3

不同温度下碳源对AOA-SBR工艺PAO与GAO竞争释磷的影响

张兰河 , 李德生 , 王旭明 , 张海丰

硅酸盐通报

为了提高生物除磷效率,研究采用AOA-SBR工艺进行了长期连续除磷实验,考察不同温度下碳源(乙酸钠、丙酸钠、葡萄糖)对PAO与GAO竞争的影响.结果表明:当温度由10℃升高至25℃时,利用丙酸钠作为碳源时,污泥含磷量与含糖量分别从7.2％和5.1％升高至7.9％和6.3％,PHA转化量升高了23.1 mg/L,厌氧释磷量从105.9 mg/L升高至149.9 mg/L,VSS/MLSS由71％降低至65％;利用乙酸钠作为碳源时,污泥含磷量与含糖量分别从6.9％和5.3％升高至7.6％和6.7％,PHA转化量升高了23.9 mg/L,厌氧释磷量从73.8 mg/L升高至108.8 mg/L,VSS/MLSS由73％降低至71％;利用葡萄糖作为碳源时,污泥含磷量与含糖量分别从5.8％和6.3％升高至6.6％和8.8％,PHA转化量升高了33.2 mg/L,厌氧释磷量从37.4 mg/L升高至43.2 mg/L,VSS/MLSS由80％升高至88％.当温度升高至30℃时,3个反应器均出现厌氧末期PHA浓度下降和糖原浓度升高,厌氧释磷量减少,污泥含磷量均下降,污泥含糖量上升,VSS/MLSS均很高.与葡萄糖相比,采用乙酸钠和丙酸钠作为碳源,有利于PAO生长繁殖,PAO为优势菌种,抑制GAO增殖.同时,低温更有利于PAO的生长繁殖.

关键词: 温度 , 碳源 , SBR , PAO与GAO

Congratulations to Prof. Dr. WEI Shoukun's 100th Birthday

金属学报(英文版)

关键词:

Dedicated to Prof. Dr. WEI Shoukun's 100th birthday

稀有金属（英文版）

关键词:

SNOEK-Ke-K■STER PEAK OF INTERNAL FRICTION IN Fe-P-N ALLOYS

Y.Y.Che , G. Y.Zeng , Y. C. Xu and J. W , Ji(College of Science , Northeastern University , Shenyang 110006 , China)

金属学报(英文版)

The internal friction and precipitate phases of the deformed Fe-P-N alloys have been investigated. It has been found that the ratio of depends on the content of P and the relation holds if the content of N is lower than 30wt.ppm and the content of P is lower than 640wt.ppm. It shows that the intercept K2 is related to the presence of the atomic pairs and clusters of P in the alloy matrix.

关键词: internal friction , null