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光谱和电化学方法研究黄芩素与核酸相互作用的机理

郭蒙 , 王淑敏 , 王佳丽 , 李丹 , 高庆宇 , 李丽敏

应用化学 doi:10.3724/SP.J.1095.2014.30232

在pH=3.22的NaAc-HAc溶液中,应用循环伏安法、方波伏安法、荧光光谱法、紫外可见光谱法和黏度法研究了黄芩素(BAI)与鲱鱼精子DNA(fsDNA)之间的相互作用,发现二者通过沟槽作用形成一电活性较高的复合物,fsDNA为BAI提供了一个低极性的疏水环境导致BAI的峰电流显著增强,增强的峰电流与fsDNA在7.0×10-8 ~7.0×10-6 g/mL浓度范围内呈正比,由此建立了一种测定核酸的新方法,检测限达到4.1×10-8 g/mL.

关键词: 黄芩素 , 核酸 , 电化学 , 沟槽作用

TRACKING OBSERVATION ON SUBSURFACE CRACK IN BEARING STEEL GCr15 UNDER ROLLING CONTACT

CHEN Longqing Zhengzhou Institute of Technology , Zhengzhou , China CHEN Qing Luoyang Institute of Technology , Luoyang , China

金属学报(英文版)

Based on the sequent tracking observation on spalling of steel GCr15 under rolling contact fa- tigue,an expression for estimating the propagation of subsurface cracks was derived.The rol- ling contact fatigue life was found to be markedly related to the subsurface crack propagation angle.A new explanation of reason why the rolling contact fatigue life can be prolonged by residual compressive stress and retained austenite was advanced.

关键词: contact fatigue , null , null , null , null

Influence of Rolling Reductions on Recrystallization Texture in Commercially Pure Al

MAO Weimin University of Science and Technology , Beijing , 100083 , China.

材料科学技术(英文)

The recrystallization texture in commercially pure Al is investigated after the samples are rolled differently and annealed.The samples with low rol- ling reductions could be generally recovered or recrystallized in situ and characterized by the re- tained G{110}<001>component.This recovery process decreases during annealing with the increase of reduction.The appearance of the B/R{359}. <132>and R{123}<634>components de- pending on the rolling reduction is investigated and the less developed Cube{100}<001>component in commercially pure ahninium is also discussed.

关键词: recrystallization , null , null , null

Improved Nonlinear Equation Method for Numerical Prediction of Jominy EndQuench Curves

SONG Yuepeng , LIU Guoquan , LIU Shengxin , LIU Jiantao , FENG Chengming

钢铁研究学报(英文版)

Without considering the effects of alloying interaction on the Jominy endquench curves, the prediction results obtained by YU Baihai′s nonlinear equation method for multialloying steels were different from those experimental ones reported in literature. Some alloying elements have marked influence on Jominy endquench curves of steels. An improved mathematical model for simulating the Jominy endquench curves is proposed by introducing a parameter named alloying interactions equivalent (Le). With the improved model, the Jominy endquench curves of steels so obtained agree very well with the experimental ones.

关键词: Jominy endquench curve;nonlinear equation method;alloying interaction parameter;computer simulation

DL-EPR法评价2205双相不锈钢晶间腐蚀敏感性

徐菊良 , 邓博 , 孙涛 , 李劲 , 蒋益明

金属学报 doi:10.3724/SP.J.1037.2009.00598

利用Thermo-Calc软件并结合金相显微镜,定性研究了2205双相不锈钢在800℃下敏化不同时间后的微观组织演变过程.通过研究扫描速率、介质成分、介质温度和试样表面状态优化了双环电化学动电位再活化法(DL-EPR),并用该优化方法研究了2205双相不锈钢晶间腐蚀敏感性.结果表明:DL-EPR法能定量评价σ相对2205双相不锈钢晶间腐蚀敏感性的影响,随敏化时间延长,σ相含量增多,晶jian 腐蚀敏感性也随之增加.腐蚀形貌的观测验证了这一规律,

关键词: 2205双相不锈钢 , DL-EPR , 晶间腐蚀敏感性 , σ相

Intergrain interaction, coercivity and Henkel plot for NdFeB magnets

Ruwei GAO , Wei CHEN , Jiancheng ZHANG , Weicun FONG , Wei LI , Xiumei LI

材料科学技术(英文)

For both sintered and nanocomposite NdFeB magnets, deltaM(H) of the Henkel plot increases from zero, and reaches a peak, then decreases and changes to the negative values with increasing applied field. This shows that the intergrain interaction changes from the exchange-coup ling type into the magnetostatic interaction type. The magnetic field corresponding to the peak of deltaM(H) is slightly smaller than the coercivity of magnet. The peak of deltaM(H) for aligned sintered magnet is greater than that for misaligned magnet. deltaM(H) peak of the nanocomposite NdFeB magnets increases with decreasing grain sizes. It indicates that the effect of alignment field on the properties of magnet is similar to that of exchange-coupling interaction.

关键词:

INFLUENCE OF SURFACE HARDENING ON CONTACT FATIGUE LIFE OF NODULAR CAST IRON

TAO Zengyi LUO Jiaming Huazhong University of Science and Technology , Wuhan , China TAO Zengyi , Faculty of Metallic Materials , Dept.of Mechanical Engineering No.2 , Huazhong University of Science and Technology , Wuhan 430074 , China

金属学报(英文版)

The influence of laser surface melting and induction hardening on the surface structure,con- tact fatigue life and failure behaviour of the nodular cast iron has been investigated.The con- tact fatigue life can be improved by both laser treatment and induction hardening,but the fail- ure process and type are different from each other.The former is due to lumpy and deep spal- ling caused by crack propagation between the quenching zone and the substrate,and the latter is due to nubby and surface flaking caused by the oil wedged action into surface cracks.

关键词: surface hardening , null , null , null

MgO掺杂对BaSrTiO3介质陶瓷性能的影响

曲远方 , 张连松 , 李远亮

稀有金属材料与工程

通过实验,研究了MgO掺杂对BaSrTiO3陶瓷介电性能的影响和机理.观察了样品的微观形貌,讨论了氧化镁在调整Ba1-xSrxTiO3铁电陶瓷的介电-温度特性的作用.结果表明,氧化镁掺杂对Ba1-xSrxTiO3系介质陶瓷产生了压峰和移峰作用.借助扫描电镜对所制得的样品进行了分析,氧化镁掺杂使Bai.SrxTiO3系介质陶瓷的结构细晶化.以实验结果和微观结构分析为依据探讨了氧化镁掺杂改性作用的机理.

关键词: Ba1-xSrTiO3 , 介电特性 , MgO , 掺杂

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