材料期刊网

ASTUDY OF VALENCE OF YTTRIUM IN Y_2O_3 Mo CATHODE

J.S.Wang1 , 2) , M.L.Zhou2) , J.X.Zhang2) , Z.R.Nie2) T.Y.Zuo2) and G.J.Zhang2) 1) State Key Laboratory of Materials Chemistry and Applications , Peking University , Beijing 100871 , China2) Schoolof Materials Science and Engineering , Beijing Polytechnic University , Beijing 100022 , China

金属学报(英文版)

The valenceofelementyttrium of Y2 O3 Mocathode materialhasbeenstudied by usingther mal weight analysis, X ray diffraction analysis, Scanning electron microscopy and X rayphotoelectronspectrum . It hasbeen provedthatyttrium oxidecan bereduced by molybdenum carbide. Thereaction between powdered Y2 O3 and Mo2 Ccan happen at 1173 , and Y2 O3may bereduced to metallicyttrium . Afterthepowder mixtureof Y2 O3 and Mo2 Cwasheat treated at1873 K, Yttrium existsin two kinds of chemicalstate- yttrium of zero valence and yttrium ofthreevalences.

关键词: valence , null , null , null

J(τ_0γ_0/(x_1x_2))行列式与弹塑性J积分不守恒的理论与实验证明

刘叔仪

金属学报

<正> 作为固体脆性断裂判据的J积分,其数值与其积分路径无关,这在文献中叫“守恒性”。这个守恒性已被推广到塑性断裂,这到底有否根据?本文目的是作这个问题的证明。未用原作者的方法,但由两个旋度判据得到应力应变函数行列式给出的一些否定结论,希望这对J积分应用条件的了解有所助益。1.弹塑性J积分守恒的条件 J积分

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温度对J55油管CO2腐蚀行为的影响

朱世东 , 李金灵 , 杨志刚 , 张世君 , 李辉 , 王珂 , 马海霞

机械工程材料

采用高温高压釜于25～65℃模拟了J55油管在延长油田井下环境中的CO2腐蚀行为,并用扫描电镜和X射线衍射仪研究了温度对J55油管CO2腐蚀行为的影响.结果表明:J55油管的平均腐蚀速率随着温度的升高而急剧增大,拟合函数较好地预测了腐蚀速率随温度的变化关系;温度的升高加快了Ca2中和Mg2+在膜中的沉积,导致复盐Fe(Ca,Mg)(CO3)2在高温下出现,改变了腐蚀产物膜的结构,使垢下腐蚀加剧.

关键词: J55油管 , CO2腐蚀 , 垢下腐蚀

X70管线钢J1d和K1a与V型缺口Ak关系研究

朱杰武 , 柳永宁 , 许雁 , 冯耀荣

机械工程材料 doi:10.3969/j.issn.1000-3738.2005.06.007

在不同温度下测试了X70管线钢动态断裂韧度K1d、J1d和止裂韧度K1a以及夏氏V型缺口冲击韧度Ak,对三者的关系进行了分析.结果表明:温度和加载速率都对断裂韧度产生影响;加载速率变化引起的韧-脆断裂转变具有热激活特征,在热激活分析基础上,在应力强度因子速率K=15 MPa·m1/2s-1条件下,得出断裂韧度、止裂韧度和冲击韧度三者的关系:Ak=4.84×106T-2.8K1d(或K1a).可以用小试样Ak数据计算得到K1d和K1a.

关键词: 管线钢 , 断裂韧度 , 止裂韧度 , 韧-脆断裂转变

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

ECAP变形2J4合金回火后的磁性能研究

杜忠泽 , 伍来智 , 符寒光 , 王庆娟 , 王经涛

航空材料学报 doi:10.3969/j.issn.1005-5053.2009.03.002

研究了磁性材料2J4合金经等径弯曲通道变形(Equal Channel Angular Pressing,简称ECAP)和不同温度回火后的磁性能,并与冷轧变形合金的磁性能进行了对比分析.结果表明,2J4合金随着ECAP变形道次的增加,磁导率增加,4道次ECAP变形的饱和磁感应强度最高.另外,2J4合金的磁性能对回火温度的变化非常敏感,呈波浪式变化.4道次ECAP变形2J4合金沿挤压面(S面)进行85%冷轧变形,在610℃回火后获得的磁性能最好,矫顽力达到3.8364 kA/m.ECAP变形2J4合金沿挤压面的磁性能远优于传统冷轧合金.试验结果证实了采用ECAP变形方式制备高性能磁性材料是可行的.

关键词: 等径弯曲通道变形 , 2J4合金 , 回火 , 磁性能 , 冷轧

ECAP制备半硬磁2J4合金的磁性能研究

杜忠泽 , 伍来智 , 王庆娟 , 王经涛

材料工程 doi:10.3969/j.issn.1001-4381.2006.10.003

开发了用等径弯曲通道变形(ECAP)制备半硬磁2J4合金.研究结果表明:2J4合金的磁性能随着ECAP变形道次的增加而逐渐增大,在第3道次变形时,其磁性能增加速度最快.ECAP变形与冷轧类似,都形成极其相似的带状织构,提高了合金的各向异性常数.由于ECAP方式使晶粒细化,达到或接近单畴结构,使得2J4合金的磁性能优于冷轧条件下的磁性能.

关键词: 等径弯曲通道变形 , 半硬磁 , 2J4合金

First-principle study of electronic properties of Ti3Si1-xAlxC2 solid solutions

Journal of Physics and Chemistry of Solids

The layered ternary ceramics Ti3SiC2 and Ti3AlC2 are isostructural and can form Ti3Si1-xAlxC2 solid solutions combining the advanced properties of both compounds [H.B. Zhang, Y.C. Zhou, Y.W. Bao, M.S. Li, Improving the oxidation resistance of Ti3SiC2 by forming a Ti3Si0.90Al0.1C2 solid solution, Acta Mater. 52 (2004) 3631-3637; E.D. Wu, J.Y. Wang, H.B. Zhang, Y.C. Zhou, K. Sun, Y.J. Xue, Neutron diffraction studies of Ti3Si0.9Al0.1C2 compound, Mater. Lett. 59 (2005) 2715-2719; J.Y. Wang, Y.C. Zhou, First-principles study of equilibrium properties and electronic structure of Ti3Si0.75Al0.25C2 solid solution, J. Phys.: Condens. Matter 15 (2003) 5959-5968; Y.C. Zhou, J.X. Chen, J.Y. Wang, Strengthening of Ti3AlC2 by incorporation of Si to form Ti3Al1-xSixC2 solid solutions, Acta. Mater. 54 (2006) 1317-1322]. In the present work, the solid solutions of Ti3Si1-xAlxC2 (x = 0, 0.25, 0.33, 0.5, 0.67, 0.75, 1) are investigated by first-principle calculations based on pseudo-potential plan-wave method within the density functional theory framework. The results show that as Al content increases in the solid solution, all the bonds have weakened to certain extents, which lead to an unstable structure both energetically and geometrically. The calculated results are compared and discussed with the reported data for the Ti3Si1-xAlxC2 solid solutions. (c) 2007 Elsevier Ltd. All rights reserved.

关键词: ceramics;ab initio calculations;electronic structure;electrical;conductivity;oxidation behavior;mechanical-properties;ti3sic2;temperature;ti3alc2;air;si

S355J2W耐候钢的耐腐蚀性能

鲁二敬 , 卢峰华 , 许鸿吉 , 谢明 , 钮旭晶

机械工程材料

通过周期浸润腐蚀试验，对比研究了S355．12W耐候钢和Q345R低合金钢在NariSOs溶液中的耐腐蚀性能，并用扫描电镜对腐蚀产物进行了观察和分析。结果表明：在相同试验条件下，S355J2W耐候钢的腐蚀速率低于Q345R钢的；S355J2W耐候钢会在表面形成黑褐色锈层，而Q345R钢表面形成橘红色易剥落的疏松锈层；S355J2W耐候钢腐蚀产物微观形貌为沿放射性方向生长的针状晶体，Q345R钢为颗粒状聚合物堆积而成，形状无规则，颗粒之间有较大的空隙。

关键词: S355J2W耐候钢 , 周期浸润腐蚀试验 , 耐腐蚀性能

ECAP变形2J4合金的显微组织演变

杜忠泽 , 伍来智 , 符寒光 , 王庆娟 , 王经涛

航空材料学报 doi:10.3969/j.issn.1005-5053.2008.01.006

借助光学显微镜和透射电镜对2J4合金等径弯曲通道变形(ECAP)组织进行了研究.结果表明,常温下2J4合金ECAP变形的最大累积真应变达到3.0,相当于压下量达到90%.ECAP变形1道次后,晶粒由30μm转变为具有一定方向性、相互平行的宽约0.35μm、长约为2.5μm的马氏体板条组织.随着变形道次增加,马氏体进一步细化,且出现晶粒从大板条向小的板条及等轴晶转化的趋势.另外,α相转变量随着变形量的增大而增加.

关键词: 等径弯曲通道变形 , 2J4合金 , 超细晶 , 马氏体