J.Q.ZHANGD.J.YOUNG
中国腐蚀与防护学报
Metaldusting attacks iron, low and high alloy steels and nickel-or cobalt-base alloys by disintegrating bulk metals and alloys into metal particles in a coke deposit. It occurs in strongly carburising gas atmospheres (carbon activity aC>1) at elevated temperatures (400 ℃~1000 ℃). This phenomenon has been studied for decades, but the detailed mechanism is still not well understood. Current methods of protection against metal dusting are either directed to the process conditions-temperature and gas composition-or to the development of a dense adherent oxide layer on the surface of the alloy by selective oxidation. However, metal dusting still occurs by carbon dissolving in the base metal via defects in the oxide scale. The research work at UNSW is aimed at determining the detailed mechanism of metal dusting of both ferritic and austenitic alloys, in particular the microprocesses of graphite deposition, nanoparticle formation and underlying metal destruction. This work was carried out using surface observation, cross-section analysis by focused ion beam and electron microscopic examination of coke deposits at different stages of the reaction. It was found that surface orientation affected carbon deposition and metal dusting at the initial stage of the reaction. Metal dusting occurred only when graphite grew into the metal interior where the volume expansion is responsible for metal disintegration and dusting. It was also found that the metal dusting process could be significantly changed by alterations in alloy chemistry. Germanium was found to affect the iron dusting process by destabilising Fe3C but increasing the rate of carbon deposition and dusting, which questions the role of cementite in ferritic alloy dusting. Whilst adding copper to iron did not change the carburisation kinetics, cementite formation and coke morphology, copper alloying reduced nickel and nickel-base alloy dusting rates significantly. Application of these fundamental results to the dusting behaviour of engineering alloys is discussed.
关键词:
metal dusting
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null
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null
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null
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null
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李亚宁
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董保胜
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赵新伟
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罗金恒
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周根树
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郑茂盛
钢铁研究
doi:10.3969/j.issn.1001-1447.2006.03.010
Q345是广泛使用的一种普通低合金钢,其断裂韧性是工程中进行裂纹检测的重要参数.应用J积分法测定了Q345的断裂韧性,并采用R6方法中的选择3曲线和通用曲线绘制了其失效评定曲线.研究发现:所有试样断口均有充分张开的大分层现象,它的存在阻碍了断口沿厚度方向的收缩,从而增加了材料的断裂韧性值.给出了适合Q345特性的失效评定曲线,以便为工程应用提供依据.
关键词:
Q345
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J积分
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断裂韧性
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失效评估曲线
Physical Review B
The Hamiltonian for a four-sublattice Heisenberg ferrimagnet or ferromagnet with different exchange constants (J(ab) = J(cd) not equal J(bc) = J(da)) was established. An extended Bogoliubov transformation was developed by solving an equation group, consisting of 20 equations and 20 unknowns. The procedure for solving the equation group was carried out by introducing a simple way of reducing the numbers of the equations and the unknowns. The spin-wave spectra in the present system have been determined by performing the standard Holstein-Primakoff transformation and the Bogoliubov one. It has been found that the spin-wave spectra of the present system depend on the exchange constants and that the degeneracy of the spin-wave spectra remains. The results for a special case (J(ab) = J(bc)) i.e., an antiferromagnet are discussed briefly. The spin-wave spectra of the four-sublattice Heisenberg antiferromagnet are found to be degenerative also and they are linear in k for small k.
关键词:
model
Y.G. Cao
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X.Y. Sun
金属学报(英文版)
J-integral and crack opening displacement δ(COD) were important parameters for characterization of fractures in engineering materials. The relationship between J-integral and COD has been investigated for a long time and was enerally represented as J = m σyδ, where σy is the yield strength and m is a function of specimen geometry and material properties. To determine the value of m, extensive studies and experiments have been performed. The method that used the fracture-surface topography analysis (FRASTA) for determining J-integral from fracture surfaces of materials was introduced. On the basis of the relationship between COD and fracture surface average profile, the relationship between J-integral and COD was deduced and compared with the generally used equation. The method was experimentally confirmed to be able to provide a new way to determine the relationship between J-integral and COD.
关键词:
FRASTA
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null
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null
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金属学报
在工程上,经常由于应力腐蚀开裂和氢脆引起中强度钢结构件发生滞后破坏。这类脆断往往从结构件中预先存在的疲劳或焊接裂纹处开始,因此,运用传统的光滑试样的检验方法不能反映这类破坏的特点。 本文将弹塑性断裂力学中的J积分概念用于滞后破坏的研究,提出用带预制疲劳裂纹的悬臂弯曲试样测定J积分的临界值J_(Ic)和应力腐蚀开裂阈值J_(Iscc)的方法。测定了40CrNiMo钢的J_(Ic)值及其在硫化氢水溶液中的J_(Iscc)值。通过和三点弯曲方法测定的J_(Ic)值的对比,以及和满足线弹性条件时直接测定的应力强度因子K_I值的对比,说明这种方法的可靠性。最后,对悬臂弯曲方法的特点进行了讨论。
关键词:
平荣刚
原子核物理评论
doi:10.3969/j.issn.1007-4627.2004.02.026
通过J/Ψ→pp-,pN-*,N*N-*衰变,研究了Roper共振态的混杂态结构对衰变角分布和分支比的影响.计算结果表明,如果Roper共振态为纯混杂态,那么J/Ψ→pN-*,N*N-*的角分布几乎相等,而J/Ψ衰变到混杂态的衰变宽度还不到J/Ψ→pp-的1%,给出了Γ(J/Ψ→ N*p-)/Γ(J/Ψ→pp-)和Γ(J/Ψ→ N*N-*)/Γ(J/Ψ→pp-)随混合参数的变化关系,并讨论了在J/Ψ衰变中研究Roper混杂态结构的可能性.
关键词:
Roper共振态结构
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混杂态
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J/Ψ
Journal of Physics-Condensed Matter
The temperature dependences of the magnetization, internal energy and specific heat in a three-sublattice ferrimagnet or ferromagnet with /J(ab)/ = /J(bc)/ not equal /J(ca)/ are calculated within the framework of the linear spin-wave approximation, by employing retarded Green's functions. For both the ferromagnet and the ferrimagnet, the internal energy and the specific heat decrease with increasing J ' /J and/or the value of the spins. For fixed values of S,, Sb, S, and J ' /J, the internal energy and the specific heat increase, whereas the sublattice magnetization decreases with increasing temperature theta. The three-sublattice ferrimagnet has some particular characteristics which are not shown by the systems with two sublattices. For ferrimagnets, the antiferromagnetism of the system becomes weaker with increasing J ' /J. The sublattice magnetization at low temperatures (also the magnetization M(0) at 0 K) of a ferrimagnet increases with increasing J ' /J for fixed values of S(a), S(b) and S(c). The effects of the spins S(a) (S,) and Sb On the magnetizations of other sublattices differ. The characteristics of the a-sublattice are the same as those of the c-sublattice, due to their similarity as well as the symmetry of the system. The behaviours of the b-sublattice are different from those of the a- and c-sublattices, due to the asymmetry of the three-sublattice system. The spin-value dependences of the spin deviation Deltam per spin land also the energy for the zero-point quantum fluctuation) of the system are different for different sublattices. These differences are ascribed to the asymmetry of the three-sublattice systems, which leads to the new intrinsic properties of the systems.
关键词:
layered heisenberg ferrimagnets;spin-wave theory;elementary;excitations;superlattices;systems;magnetoresistance;antiferromagnet;interfaces
Physical Review B
The quadratic Holstein-Primakoff spin-wave Hamiltonian for three-sublattice Heisenberg systems with different exchange constants (J(ab)=J(bc)not equal J(ca)) was diagonalized by a three-step procedure. The classical ground state was examined and the effects of quantum fluctuation on the ground state were discussed. The 0 K spin reorientation angles due to quantum fluctuations were found to originate from the asymmetry of the system. As an extended application of the spin-wave study of the multisublattice systems, the spin-wave spectra of a Heisenberg superlattice, which has four or three magnetic atoms or spins, in each magnetic unit cell in the x direction, were solved analytically in terms of creation and annihilation operators. It has been found that the spin-wave spectra of the present superlattice systems depend on the exchange constants J and J(1), and that the degeneracy of the spin-wave spectra remains for the superlattice of four atomic layers and is partially removed for the superlattice of three atomic layers mainly due to the asymmetry of the system. Another type of splitting of the energy level occurs which differs for those levels with different degeneracies. The mixing of the interface and the bulk modes were found for the spin-wave dispersion of the superlattices. It was predicted that even for different superlattices having the same exchange constants (either J or J'), i.e., without the oscillation of the exchange coupling, the asymmetry can lead to the oscillation of magnetic properties, such as magnetization and giant magnetoresistance.
关键词:
ferromagnetic superlattices;reorientation transitions;magnetic;superlattices;modes;temperatures;film
