NIU Yan
,
F.GESMUNDO
,
WU Weitao
,
ZENG Chaoliu
,
F.VIANI
,
(State Key Laboratory for Corrosion and Protection
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang.110015
,
China)(Istituto di Chimica
,
Facolta'di Ingegneria
,
Universita'di Genova
,
Fiera del Mare
,
Pad.D
,
16129 Genova
,
Italy)Manuscript received 3 July 1995
金属学报(英文版)
The corrosion properties of a Co-15wt% Y alloy were studied in H_2-H_2S mixtures under a sulfur pressure of 10-3 Pa at 600-800℃ and of 10-2 Pa at 800℃ to examine the effect of Y on the resistance of pure cobalt to sulfur attack at high temperatures.The alloy is nearly single-phase.containing mostly the intermetallic compound Co17Y2 plus a little amount of the solid solution of Y in cobalt.At 600-700℃ and at 800℃ under 10-2 Pa of S2 the alloy forms multi-layered scales consisting of an outer region of pure cobalt sulfide,an intermediate region of a mixture of the sulfides of the two metals and finally an innermost layer of a mixture of yttrium sulfide with metal cobalt.At 800℃ under 10-3Pa of S2,below the dissociation pressure of cobalt sulfide, the alloy forms only a single layer composed of a mixture of metallic cobalt with yttrium sulfide.Pure Y produces only the oxysulfide Y2O2S, as a result of the good stability of this compound and of the presence of some impurities in the gas mixtures used The corrosion kinetics is generally rather complex and irregular except al 800℃under 10-3 Pa of S2.The addition of yttrium always reduces the sulfidation rate of cobalt, even though the formation of a continuous protective external layer of yttrium sulfide is never achieved.The internal sulfidation of Y in Co-15% Y is not associated with a depletion of Y in the alloy.This kind of diffusionless internal attack is typical of alloys with a very small solubility of the most reactive component Y in the base metal A.which restricts severely the Y flux from the alloy towards the alloy-scale interface.
关键词:
:cobalt-yttrium alloy
,
null
,
null
M. H. Guo
,
D. C. Shao
,
Z. G Dong and J. C Yang National Key Laboratory Advanced Welding Production Technology
,
Harbin institute of Technology
,
Harbin 150001
,
China
金属学报(英文版)
Manuscript received 30 July 1999 Abstract The shielded metal arc welding (SMAW) of a manganese steel part as a crossing of railway track to a carbon steel part as the rails of the railroad is the welding of dissimilar steel. It are was known that it is not possible to the the rail of railroad directly to the cross- ing of railway track made from a steel containing about 14% of manganese (wt. ) because of so many differences between the two kinds of steels such as composition, microstructure,mechanical properties and weldability.A method was used to solve the problem by presetting an intermediate layer on each side of the joint and other special procedures were used.The result of test indicated that a good weld joint was obtained.
关键词:
high manganese steel
,
null
,
null
,
null
L.L.Wang
,
L.H.Zhao
,
W.Y.Hu
,
X.L.Shu
,
X.J.Yuan
,
B.W.Zhang and X.Sheng Department of Applied Physics
,
Hunan University
,
Changsha 410082
,
China
金属学报(英文版)
Manuscript received 24 June 1999 The Fe Al P alloy deposits were plated on copper sheets by electroless plating. The change law of the deposition rate, composition, surface appearance and structure for the deposits was studied by changing the metallic salt ratios (AlCl 3/AlCl 3+FeSO 4), the concentration of metallic salt AlCl 3 and reductant NaH 2PO 2. The optimum plating bath was obtained. It was found that the choices of ligand and reductant were the key of increasing Al content for the deposits.
关键词:
electroless Fe Al P plating
,
null
,
null
,
null
