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Development of Magnesium-Insertion Positive Electrode for Rechargeable Magnesium Batteries

Huatang YUAN , Lifang JIAO , Jiansheng CAO , Xiusheng LIU , Ming ZHAO , Yongmei WANG

材料科学技术(英文)

Magnesium-based rechargeable batteries might be an interesting future alternative to lithium-based batteries. It is so far well known that Mg2+ ion insertion into ion-transfer hosts proceeds slowly compared with Li+, so it is necessary to realize fast Mg2+ transport in the host in addition to other requirements as practical cathode materials for magnesium batteries. Positive electrode materials based on inorganic transition-metal oxides, sulfides, and borides are the only ones used up to now to insert magnesium ions. In this paper, the available results of research on materials suitable as possible, for secondary magnesium batteries, are reviewed.

关键词: Rechargeable magnesium battery , null , null

Intensified alkaline leaching pretreatment of refractory gold concentrates at common temperature and pressure

Transactions of Nonferrous Metals Society of China

A new process for the hydrometallurgy of refractory gold concentrates was presented. The process comprises grinding-leaching, intensified alkaline leaching (IAL), cyanidation and adsorption. In a stirring-type pulverizing-leaching tower mill, the concentrate is ground to <35. 6 μm of 95. 5 % while simultaneously leached by NaOH of 12 kg/t, then carried out intensified alkaline leaching for 48 h by NaOH of 108 kg/t in enhanced agitation tanks with the pulp concentration of 40% solids at the environmental temperature of 9. 5 &SIM; 13. 5 &DEG;C and the environmental pressure of 10(5) Pa. The oxidation rate of As is 94. 9%, and 47. 6% for S. The total consumption of NaOH is only 20% of that theoretically calculated under the conditions of full oxidation at the same oxidation rates of arsenic to arsenate and sulfur to sulfate. The gold leaching rate by NaCN in 24 h is increased from 9. 2% before pretreatment to 94. 2%. The consumption of NaCN is 7. 5 kg/t, which is one times less than that before pretreatment. The extraction cost of gold is about 422 Yuan/t.

关键词: refractory gold concentrates;grinding-leaching;intensified alkaline;leaching (IAL);pretreatment;common temperature and pressure

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