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CHARACTER OF CARBON-DEPLETED REGIONS IN UNDERCOOLED AUSTENITE AND THERMODYANMICS OF BAINITIC TRANSFORMATION

YANG Quanmin KANG Mokuang Northwestern Polytechnical University , Xi'an , China YANG Quanmin , Dept.of Material Science and Engineering , Zhejiang University , Hangzhou 310027 , China

金属学报(英文版)

The chemical driving forces for the phase transformation from austenite in three different car- bon-depleted regions into ferrite with the identical composition have been derived respectively. The starting temperature of bainitic transformation,B_s,has also been calculated according to the shearing mechanism of bainitic transformation in carbon-depleted regions of austenite. The maximum driving forces for banitic transformation at B_s in both 3% Cr and the CrMo steels were obtained.It was shown that the proposed shearing mechanism of the bainitic trans- formation is thermodynamically possible.

关键词: bainitic , null , null

GEOMETRIC MODEL AND APPLIED METHOD FOR THE CALCULATION OF GRAIN SIZE DISTRIBUTIONS

ZHAO Xinbing Zhejiang University , Hangzhou , China LCKEK Institut fur Metallkunde und Metallphysik der RWTH Aachen , Germany Department of Materials Scicnce and Engineering , Zhejiang Univer sity , Hangzhou 310027 , China

金属学报(英文版)

Most of the available methods for the calculation of the three dimensional(3D)grain size dis- tribution functions(SDF)are based on the S model and lead a grave systematical error.The origin is the basic supposition of spherical grains in the S model,which does not correspond with the feature of real grains.A new model called A model is developed based on the hypothe- sis of polvhedral grains.The probability functions of the A model and the method to calculate the 3D SDFs using the A model are given in the present paper.The theoretical analyses and experimental tests have demonstrated that the A model reduces the systematical error radical- ly.It is nearly as simple as the so far used S model,but gives much better results in repro- ducing of 3D SDFs from the measured ID or 2D SDFs.

关键词: grain size , null , null , null

MECHANISM OF DEUTERIUM CRACKING IN PALLADIUM

SUN Dalin LEI Yongquan CHEN Yanglin WU Jing WANG Qidong Zhejiang University , Hangzhou , China Department of Materials Science and Engineering , Zhejiang University , Hangzhou 310027 , China

金属学报(英文版)

After 290 h electrochemical charging of deuterium,the density of dislocation in well-annealed Pd was increased from 10~8/cm~2 to over 10~12/cm~2 and a large amount of bubble-like voids or cracks was observed by optical and transmission electron microscopes.The mechanism of deuterium cracking is believed due to the formation of molecular De during the segregstion and combination of deuterium atoms around dislocations.XRD results showed that the lattice constant of Pd increased from 0.3890 nm to 0.4034 nm.

关键词: deuterium cracking , null

聚脲聚氨酯环氧涂料用於混凝土钢筋防腐蚀的研究

林薇薇

中国腐蚀与防护学报

聚脲聚氨酯环氧涂料用於混凝土钢筋防腐蚀的研究林薇薇(浙江大学高分子系杭州310027)钢筋混凝土建筑物耐久性下降的主要原因之一是增强钢筋的腐蚀。因为混凝土是多孔性凝胶体,空气中的氧、湿气和其它腐蚀介质能通过孔隙和细裂缝侵蚀钢筋,而钢筋变成铁锈时体积要增大2~4倍,结果产生内应力,使混凝土开裂,又进一步加剧腐蚀,造成钢筋混凝土构件破损失效。为此,目前已采用一些方法来减缓钢筋的腐蚀速度[1]。钢?...

关键词: null , Epoxy;Polyurea , Polyurethane , Concrete

Ni-13Cr-0.5Ce合金在575℃ Cl_2-H_2O混合气氛中的腐蚀行为

涂江平 , 李志章 , 毛志远

中国腐蚀与防护学报

Ni-13Cr-0.5Ce合金在575℃Cl_2-H_2O混合气氛中的腐蚀行为涂江平,李志章,毛志远(浙江大学杭州310027)1引言关于合金在干氯气或含氯的氯化气氛中的腐蚀行为已有报导[1~3],而在实际生产中,液氯经雾化后往往存在少量水份,使腐蚀环境变得复杂,尤其在高温下腐蚀条件进一步恶化[4].高温氯气环境中少量水蒸气的存在对合金腐蚀行为的影响是复杂的.在550℃以下时水蒸气会加速镍基合?...

关键词: null , Internal chlorination , Ni-Cr alloy

Ni-Cr-Ce合金经700℃空气预氧化后在高温氯气中的腐蚀行为

涂江平 , 毛志远 , 李志章

中国腐蚀与防护学报

Ni-Cr-Ce合金经700℃空气预氧化后在高温氯气中的腐蚀行为涂江平,毛志远,李志章(浙江大学杭州310027)改善合金在高温含卤素气氛中的抗腐蚀性能,可以由形成和维持化学性质稳定、结合强度高和完整性好的表面膜来实现[1].然而在较高氯分压的高温环境中Ni-Cr合金表面所形成的腐蚀膜难以具有保护作用,不能有效地阻碍C12的继续侵蚀,因而使合金表现出很高的腐蚀速度.采用预氧化工艺使合金表面形?...

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