AO Ming
,
WANG Qidong Zhejiang University
,
Hangzhou China Dept.of Materials Science
,
Zhejiang University
,
Hangzhou 310013
,
China
金属学报(英文版)
The hydriding and dehydriding behaviors of tetrahydrofuran modified Mg,its electronic struc- ture,crystal structure,micro-morphology as well as its stability have been investigated.The modifield Mg absorbs 3.5 wt-% hydrogen at 643 K in 3.5 MPa H_2,its hydride gives off 3.2 wt-% hydrogen at 643 K in a vaccum of 1.3 Pa after 20 cycles of hydriding and dehydriding. Tetrahydrofuran alters the electronic structure of Mg but keeps its crystal strueture unchanged.In hydriding products,a new hydride phase is found in addition to the known MgH_2 phase.The hydride formed from Mg is polv-erystalline.The wide-spreading slip bands and twins within crystals indicate that the transformation during absorption of hydrogen causes serious lattice distortions.
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