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Treatment of Reused Comprehensive Wastewater in Iron and Steel Industry With Electrosorption Technology

ZHANG Yunhua , GAN Fuxing , LI Meng , WANG Dihua , HUANG Zhongmai , GAO Yunpeng

钢铁研究学报(英文版)

Electrosorption technology was used to treat the reused comprehensive wastewater from iron and steel industry. A problem of relatively high conductivity of wastewater which greatly affects the reuse was examined, and industrial test was conducted for the reused water advanced deionization and purification in a comprehensive wastewater treatment plant of WISCO [Wuhan Iron and Steel (Group) Corporation]. The results of the onsite industrial test showed a satisfactory treatment performance for the reused water even at a flow rate of 1000 L/h in a standard 500 L/h unit. The average conductivity decreased by about 70%, from 580-780 μS/cm to 100-350 μS/cm. The average removal efficiency of Cl- and Ca2+ was about 75% and 68%, respectively, and CODCr of the treated water was also reduced in some degree while the pH value was almost unchanged. The energy consumption was as low as 06 kWh/t, which was remarkably superior to the conventional technologies. Therefore, it is entirely feasible that the novel electrosorption technology can be used in enhanced desalination and purification treatment of reused comprehensive wastewater in iron and steel industry.

关键词: electrosorption , desalination , purification , conductivity , industrial reused water

改性曼尼希胺水性环氧固化剂的制备及性能

李楚新 , 段颖 , 丁嘉欣 , 夏新年

涂料工业 doi:10.3969/j.issn.0253-4312.2012.08.008

以聚醚胺(D - 230)和DMP - 30为原料,利用胺交换反应制得一种新型的改性曼尼希胺(MAI).然后以自制的端官能环氧聚合物( PEG - EP)与低相对分子质量液体环氧树脂(EP)为扩链剂对MAI进行扩链改性,并用苯基缩水甘油醚(PGE)封端,最后采用相反转法制得了一种新型的改性曼尼希水性环氧固化剂.讨论了PEG - EP的添加量、MAI与EP的加料比及封端剂的添加量对水性固化剂体系稳定性的影响.并采用物理化学方法对反应程度及涂膜的性能进能了表征分析.优化体系固化涂膜硬度229s,柔韧性1mm,附着力0级,适用期5h,耐水性优异.

关键词: 水性 , 环氧固化剂 , 改性 , 曼尼希胺

密相气力输送颗粒静电波动信号多尺度分析

许传龙 , 王式民

工程热物理学报

在加压密相气力输送实验装置上获得了不同操作条件下煤粉颗粒静电波动信号,并用Hilbert-Huang变换、功率谱进行分析.结果表明:随着表观速度的增加,静电波动信号主峰值的频率增大;静电波动信号希尔伯特-黄变换(Hilbert-Huang)揭示了气固两相流静电信号的非线性和非平稳特征,随气固两相流颗粒相浓度降低和颗粒及表观速度增加,静电波动信号特征尺度由高尺度(低频)向低尺度(高频)转移.多尺度分析有助于认识气固两相流动形态及其转变规律.

关键词: 颗粒静电 , 静电传感器 , 气-固两相流 , Hilbert-Huang变换

1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....

关键词:

Shock compression of monocrystalline copper: Experiments, characterization, and analysis

Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing

Monocrystalline copper samples with [001] and [221] orientations were subjected to shock/recovery experiments at 30 and 57 GPa and 90 K. The slip system activity and the microstructural evolution were investigated. Different defect structures, including dislocations, stacking faults, twins, microbands, and recrystallized grains were observed in the specimens. The residual microstructures were dependent on crystalline orientation and pressure. The differences with crystalline orientations are most likely due to different resolved shear stresses on specific crystalline planes. The geometric relationships between the shock propagation direction and crystalline orientation are presented under uniaxial strain. It is shown that the [2 2 11 orientation, by virtue of having fewer highly activated slip systems, exhibits greater concentration of deformation with more intense shear on the primary system. This, in turn leads to greater local temperature rise and full recrystallization, in spite of the thermodynamic residual temperature of similar to 500 K and rapid cooling (within 20 s) to ambient temperature. The profuse observation of microbands is interpreted in terms of the mechanism proposed by Huang and Gray [J.C. Huang, G.T. Gray III, Acta Metallurgica 37 (1989) 3335-3347]. (C) 2009 Elsevier B.V. All rights reserved.

关键词: Shock compression;Shock loading;Slip bands;Microtwins;Microbands;strain rate history;single-crystals;grain-size;constitutive;description;plastic-deformation;mechanical response;deformed metals;loaded nickel;substructure;recrystallization

退火温度对混合阳离子钙钛矿太阳能电池性能的影响

刘垚 , 张帆 , 牛芳芳 , 连加荣 , 宋军 , 曾鹏举

人工晶体学报

通过不断降低钙钛矿的带隙,拓宽光活性层的光吸收范围是提高钙钛矿太阳能电池光电转换效率的一个有效途径.本文通过在三碘亚铅酸甲脒(HC(NH2)2PbI3简称FAPbI3)前驱液中混入一定比例的碘化甲铵(CH3NH3I简称MAI)并将其退火温度从150 ℃降低到100 ℃,不仅能有效改善钙钛矿薄膜的表面形貌和结晶度,还能得到比三碘亚铅酸甲铵(CH3NH3PbI3简称MAPbI3)更窄带隙的薄膜,由此得到效率达14.8%钙钛矿太阳能电池器件.

关键词: 钙钛矿 , 三碘亚铅酸甲脒 , 退火温度 , 薄膜

Mean-field theory for ferroelectricity in Ca(3)CoMnO(6)

Physical Review B

An elastic Ising model for CoMnO(6) chain is proposed to explain the ferroelectricity induced by collinear magnetic order in Ca(3)CoMnO(6), and then a mean-field theory with interchain spin interactions based on this model is developed. With inclusion of the dynamics of polarization domains at finite temperature, we address the rationality of our theory by the good agreement of the calculated electric polarization and dielectric susceptibility with the reported data on Ca(3)Co(2-x)Mn(x)O(6) (x approximate to 0.96) [Y. J. Choi, H. T. Yi, S. Lee, Q. Huang, V. Kiryukhin, and S.-W. Cheong, Phys. Rev. Lett. 100, 047601 (2008)], a typical diatomic Ising spin chain system, while the predicted magnetic susceptibility shows some difference from experiment, the reason of which is discussed.

关键词: calcium compounds;cobalt compounds;dielectric polarisation;ferroelectricity;Ising model;magnetic susceptibility;multiferroics;optical susceptibility;one-dimensional oxides;magnetic-properties;multiferroics;ca3co1+xmn1-xo6

Lu-induced orthorhombic phase in polycrystalline La0.7Sr0.3MnO3

Physica B-Condensed Matter

Polycrystalline La0.5Lu0.2Sr0.3MnO3 samples prepared by thermal decomposition are investigated by means of electron diffraction and high-resolution transmission electron microscopy. Besides rhombohedral La0.7Sr0.3MnO3 phase (R-phase) and hexagonal LuMnO3 phase (H-phase) reported by Huang, unexpectedly, an orthorhombic lattice (O-phase) with space group Pnma is observed in the interior of R-phase grain. The lattice parameters of the orthorhombic unit cell are a(o) = 5.44 angstrom, b(o) = 7.65 angstrom and c(o) = 5.48 angstrom The formation of O-phase results from a(-)b(+)a(-) type orthorhombic distortion of MnO6 octahedra induced by partial substitution of Lu3+ for La3+. Meanwhile, based on image simulation of the interface between R and O-phases, the atomic bonding on the interface is particularly discussed. (c) 2005 Elsevier B.V. All rights reserved.

关键词: orthorhombic lattice;octahedral;substitution;atomic bonding;la0.7-xluxsr0.3mno3 perovskites;transport-properties;magnetoresistance;films

Effects of A-site doping on microstructure and phase separation of La0.5RE0.2Sr0.3MnO3 (RE=Eu, Ho, Yb, Lu)

Materials Letters

Phase separation and microstructure of La0.7Sr0.3MnO3 doped with rare earth elements (Eu, Ho, Yb and Lu) are studied using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Composition and diffraction analyses demonstrate that the ionic radius of doping element plays an important role in the crystalline structure and the lattice constants of the secondary phase. When La 3 is replaced partly by Eu3+ or Ho3+, orthorhombic perovskite structure with space group Pnma is formed due to the distortion Of MnO6 octahedra. Different from the phenomenon observed by Huang et al., however, the hexagonal non-perovskite structure (YbMnO3 and LuMnO3) has appeared when La3+ and Sr2+ are substituted completely by Lu or Yb (c) 2005 Elsevier B.V. All rights reserved.

关键词: ionic radius;crystalline structure;lattice constants;orthorhombic;perovskite;hexagonal non-perovskite;magnetoresistance;perovskites;films

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