材料期刊网

STUDIES OF LOW CONCENTRATION CHROMATE PASSIVE FILM FOR ZINC BASED ALLOY COATED STEEL WIRES

Y.Li 1) , H.R Wang 2) , F.L.Feng 1) and X.J.Wei 1) 1) POB 118 , Northeastern University , Shenyang 110006 , China 2) Qingdao Branch of Luoyang Ship Material Research Institute , Qingdao 266071 , China

金属学报(英文版)

The corrosion resistance of a low concentration chromate passive film for zinc based alloy coated steel wires was assessed by salt spray and electrochemical corrosion tests. XPS and AES analyses showed that the composition of such chromate passive film was S 5 5, Na 3 4, C 11 8, Ti 7 9, O 41 6, Cr 13 7, Zn 16 0.

关键词: chromate passive film , null , null , null

RuCl2[P(C6H5)3]2-(R,R)-DPEN催化萘乙酮不对称加氢反应

陶明 , 熊伟 , 陈华 , 李贤均

催化学报

合成了(R,R)-1,2-二苯基乙二胺((R,R)-DPEN)、钌和三苯基膦的三元配合物RuCl2[P(C6H5)3]2-(R,R)-DPEN,并将其用于萘乙酮的不对称加氢反应.考察了碱/催化剂的摩尔比、反应温度和氢气压力等对催化活性和对映选择性的影响.结果表明,多种因素对反应的转化率和对映选择性均有影响.在萘乙酮:(CH3)3COK:催化剂摩尔比为50 000:450:1,氢气压力为4 MPa,反应温度为25℃的条件下,反应16 h时,萘乙酮生成α-萘乙醇的产率和对映选择性分别达到了100%和83%.

关键词: 钌膦配合物 , 手性二胺 , 萘乙酮 , 不对称催化加氢 , α-萘乙醇 , 对映选择性

离心力场下H2O和R12热驱动换热特性实验研究

杨敏 , 常海萍 , 毛军逵

工程热物理学报

本文实验研究了离心力场下细微封闭循环通道中,以H2O和氟利昂R12为热驱动介质的热驱动流动规律和换热特性,重点分析了热驱动换热技果随Ra数Ro数的变化规律以及冷却效果.实验结果表明:在热流密度和旋转速度相同的条件下,采用介质R12可以获得较高的半均换热系数,冷却效果也优于以H2O为介质的冷却效果.最后建立了两种介质条件下相应的准则关系式.

关键词: 热驱动 , 热驱动介质 , 细微通道 , 旋转 , 换热系数

INTRINSIC MAGNETIC-PROPERTIES OF R2FE17CYNXCOMPOUNDS - (R=Y, SM, ER, AND TM)

Journal of Applied Physics

Samples of R2Fe17C(y)N(x) (R = Y, Sm, Er, Tm) were prepared by arc melting appropriate amount of R, Fe, and C, vacuum annealing at 1373 K and finally annealing at 740 K in nitrogen for 10 h. The magnetic properties of these compounds were investigated by means of ac initial susceptibility, magnetization measurements, and x-ray diffraction. The thermal stability of the nitride phase was studied by differential scanning calorimetry. It was found that, when heated above 600 K, R2Fe17C(y)N(x) irreversibly decomposes N which is irrespective of the carbon concentration and rare-earth element. The Curie temperatures of R2Fe17C(y)N(x) are independent of the carbon concentration and are approximately 400 K higher than those of the corresponding pure R2Fe17 compounds. However, the Curie temperatures cannot be correlated to the composition x of the initial R2Fe17C(y)N(x) compounds at room temperature because some N was lost during the heating to T(c). In the Er and Tm compounds spin reorientation transitions were found, marking the change of the easy magnetization direction from the c axis to the basal plane with increasing temperature. The Tm compounds show an additional magnetic transition at low temperatures (below 40 K). A coexistence of the hexagonal and the rhombohedral structural modifications was found in Er2Fe17C(y)N(x) when y < 1.5, characterized by two different spin reorientation temperatures. The anisotropy fields of Sm2Fe17C(y)N(x) are higher than that of Sm2Fe17N(x). Indications of a magnetic phase transition were found also in Sm2Fe17C0.7N(x) and Sm2Fe17C0.9N(x).

关键词: magnetocrystalline anisotropy;carbides;alloys

Two-step magnetization in a spin-chain system on the triangular lattice: Wang-Landau simulation

Physical Review B

The Wang-Landau algorithm is used to study the thermodynamic and magnetic properties of triangular spin-chain system based on two-dimensional Ising model in order to understand the magnetic-order dynamics in Ca(3)Co(2)O(6) compound. The calculated results demonstrate that the equilibrium state of the rigid spins produces the two-step magnetization curve at low temperature even when the random-exchange term is considered. This work indicates that the four-step magnetization behavior observed experimentally must be due to the nonequilibrium magnetization.

关键词: calcium compounds;exchange interactions (electron);Ising model;magnetisation;thermodynamics;one-dimensional ca3co2o6;density-of-states;compound ca3co2o6;phase-diagram;proteins;crystal

MAGNETOCRYSTALLINE ANISOTROPY IN R2FE14-XCOXB1-YCY COMPOUNDS (R = ND, PR)

Journal of Magnetism and Magnetic Materials

The temperature dependence of the magnetocrystalline anisotropy field (mu-0H(a)) of R2Fe14B(1-y)C(y) and Nd2Fe12Co2B(1-y)C(y) (R = Nd, Pr; y = 0, 0.5) compounds has been determined by applying the SPD (singular point detection) technique in a high pulse magnetometer in the temperature range of 300-600 K. To determine the Curie temperature (T(c)) of the compounds, the ac initial susceptibility measurement was employed. It was found that the influences of carbon substituting for boron and cobalt substituting for iron on the Curie temperature are independent of each other and the latter has been understood as the case where all 2p electrons which transferred from carbon to 3d bands localize around Fe. The effect of crystal electric field acting on the rare earth site is dominant at temperatures below 400 K in R2Fe14B (R = Nd, Pr) compounds. The substitution of small amounts of cobalt for Fe does not affect the crystal electric field acting on the rare earth site very much.

关键词:

THE ANISOTROPY OF R2FE17CX (R = SM AND TM)

Journal of Applied Physics

The temperature dependence of the anisotropy field of Sm2Fe17C(x) and Tm2Fe17C(x) has been determined over the entire uniaxial ferro- or ferrimagnetic temperature range using the singularity point detection technique. The temperature dependence of the ac initial susceptibility was measured on these two systems from 4.2 to 300 K. The Curie temperature, lattice constants, spin-reorientation temperature (of Tm2Fe17C(x)) and the magnetic anisotropy field are increasing with increasing carbon concentration. A "magnetic-phase-like transition" is observed in Sm2Fe17C(x) for x < 0.7 at low temperatures, which is proved not to be a spin reorientation. Additionally, the transition temperature increases systematically with increasing carbon concentration. However, the nature of this transition is not yet well understood.

关键词: magnetic-properties;earth

ANOMALOUS 3D-ANISOTROPY OF R2FE14C AND R2FE14B COMPOUNDS

Journal of Magnetism and Magnetic Materials

The temperature dependence of the anisotropy field H(A) and the thermal expansion DELTA-l/l0 of R2Fe14X (R = Gd, Lu; X = B,C) were measured by applying the SPD technique for H(A)(T) and a membrane technique for DELTA-l(T)/l0. Comparing Lu2Fe14B and Lu2Fe14C the difference in the temperature dependence of H(A) is associated with the difference in the Invar-like thermal expansion between the two compounds.

关键词: 3d magnetism;anisotropy;gd2fe14b

NEUTRON DIFFRACTION STUDY ON R_2Fel_(17)N_x(R=Y,Dy,Nd)

YANG Jilian ZHANC Baisheng DINC Yongfan China Institute of Atomic Engergy , Beijing , ChinaYANG Yingchang ZHANG Xiaodong Peking University , Beijing , ChinaPAN Shuming General Research Institute for Non-Ferrous Metals , Beijing , China associate professor , P.O.Box 275 , Branch No.30 , Beijing 102413 , China

金属学报(英文版)

The N occupying sites and magnetic structures in R_2Fe_(17)N_x(R=Y,Dy,Nd)are de- termined by neutron diffraction.The effects of the site occupation of N on magnetic properties are discussed primarily.

关键词: neutron diffraction , null , null , null , null , null

SPIN REORIENTATION AND EXCHANGE INTERACTIONS IN (ND, R)2FE14B (R = Y, GD)

Journal of Magnetism and Magnetic Materials

Exchange fields in both (Nd, Y)2Fe14B and (Nd, Gd)2Fe14B series are determined by analyzing spin reorientation. Results calculated for the two systems suggest that the R-R exchange interactions between R ions are comparable with the crystal-field interaction and that their effect might be taken into account for reproducing the spin-reorientation temperature.

关键词: magnetization process;crystal;nd2fe14b;r2fe14b;transition