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Effect of Doping and High-Temperature Annealing on the Structural and Electrical Properties of Zn1-XNiXO(0≤X≤0.15) Powders

Hakan Colak

材料科学技术(英文)

This paper reported the synthesis, crystal structure and electrical conductivity properties of Ni-doped ZnO powders (i.e. Zn1-XNiXObinary system, X=0, 0.0025, 0.005, 0.0075 and in the range 0.01≤X≤0.15). I-phase samples, which were indexed as single phase with a hexagonal (wurtzite) structure in the Zn1-XNiXObinary system, were determined by X-ray diffraction (XRD). The widest range of the I-phase was determined as 0≤X≤0.03 at 1200°C; above this range the mixed phase was observed. The impurity phase was determined as NiO when compared with standard XRD data, using the PDF program. We focused on single I-phase ZnO samples which were synthesized at 1200°C because of the widest range of solubility limit at this temperature. It was observed that the lattice parameters a and c of the I-phase decreased with Ni doping concentration. The morphology of the I-phase samples was analyzed with a scanning electron microscope. The electrical conductivity of the pure ZnO and single I-phase samples were studied by using the four-probe dc method at temperatures between 100 and 950°C in air atmosphere. The electrical conductivity values of pure ZnO and 3 mol% Ni-doped ZnO samples at 100°C were 2×10-6 and 4.8×10-6Ω-1?cm-1, and at 950°C they were 1.8 and 3.6Ω-1?cm-1, respectively. In other words, electrical conductivity increased with Ni doping concentration.

关键词: II-VI semiconductors

Acoustic emission inspection of Portevin-Le Chatelier effect and deformation mechanisms of two Mg-Li-Al alloys

Journal of Materials Science

In this paper, Portevin-Le Chatelier (PLC) effect of LA41 magnesium alloy is reported. With increasing strain rate, both ultimate tensile stresses (sigma(b)) and 0.2% proof (sigma(0.2)) stresses increase, while serrations become less severe. Major acoustic emission (AE) peaks appear at the end of elastic region, and transform to burst type signals in the plastic range. In another alloy containing less Li (LA11), serrations are absent and major AE peak values are considerably lowered. Additionally, PLC effect disappears in LA41 after annealing. The role of twins is discussed in details. Actual causes for AE activity during deformation are also proposed.

关键词: tensile deformation;magnesium alloys;bands;az31

The crossover from parallel shift to fan-shape broadening of the superconducting transition of La(1.44)Nd(0.4)Sr(0.16)CuO(4) films in magnetic fields

Superconductor Science & Technology

In this paper we report the transport properties of c-axis-oriented superconducting La(1.44)Nd(0.4)Sr(0.16)CuO(4) films on LaSrAlO(4) substrates with different thicknesses in various magnetic fields parallel and perpendicular to the c axis of the films. It is found that with decreasing film thickness there is a crossover from the parallel shift to fan-shape broadening in the resistive transitions. Moreover, for both field configurations, the flux pinning potential U(0)(H) of the film shifts upward with an order of magnitude with increasing in-plane compressive strain. These results indicate that the compressive epitaxial strain and strain-induced destabilization of the static charge stripes are important aspects for the promotion of superconducting transition temperature as well as the flux pinning potential.

关键词: high-temperature superconductors;crystal thin-films;flux motion;la2-xsrxcuo4;strain;insulator;dependence;behavior

Mathematical Analysis on the Uniqueness of Reverse Algorithm for Measuring Elastic-plastic Properties by Sharp Indentation

Yongli Huang

材料科学技术(英文)

The reverse analysis provides a convenient method to determine four elastic-plastic parameters through an indentation curve such as Young's modulus E, hardness H, yield strength σy and strain hardening exponent n. In this paper, mathematical analysis on a reverse algorithm from Dao model (Dao et al., Acta Mater., 2001, 49, 3899) was carried out, which thought that only when 20&le;E*0:033&le;26and 0.3<n&le;0.5, the reverse algorithm would yield two solutions of n by dimensionless function Π2. It is shown that, however, there are also two solutions of n when 20&le;E*0:033&le;26 and 0&le;n<0.1. A unique n can be obtained by dimensionless function Π3 instead of Π2 in these two ranges. E and H can be uniquely determined by a full indentation curve, and σy can be determined if n is unique. Furthermore, sensitivity analysis on obtaining n from dimensionless function Π3 or Π22 has been made.

关键词: Elastic-plastic properties , null , null , null , null

Mathematical Analysis on the Uniqueness of Reverse Algorithm for Measuring Elastic-plastic Properties by Sharp Indentation

Yongli Huang

材料科学技术(英文)

The reverse analysis provides a convenient method to determine four elastic-plastic parameters through an indentation curve such as Young's modulus E, hardness H, yield strength σy and strain hardening exponent n. In this paper, mathematical analysis on a reverse algorithm from Dao model (Dao et al., Acta Mater., 2001, 49, 3899) was carried out, which thought that only when 20&le;E*0:033&le;26and 0.3<n&le;0.5, the reverse algorithm would yield two solutions of n by dimensionless function Π2. It is shown that, however, there are also two solutions of n when 20&le;E*0:033&le;26 and 0&le;n<0.1. A unique n can be obtained by dimensionless function Π3 instead of Π2 in these two ranges. E and H can be uniquely determined by a full indentation curve, and σy can be determined if n is unique. Furthermore, sensitivity analysis on obtaining n from dimensionless function Π3 or Π22 has been made.

关键词: Elastic-plastic properties , null , null , null , null

BEHAVIOUR OF Ti IN AS-CAST MEDIUM MANGANESE AUSTENITIC STEEL

JIANG Qichuan LI Zhang WANG Shoushi HE Zhenming Jilin University of Technology , Changchun , China

金属学报(英文版)

The majority of Ti is found to be preferentially precipitated in the form of TiC from medium manganese steel melt.The TiC may contribute to the heterogeneous nuclei of fine austenite crystallization,to the retardation of dislocation movement as well as to pile-up and proliferate the dislocations,thus,the matrix of the as-cast steel will be effectively strength- ened.It was also found that the TiC can be acted as the heterogeneous nuclei of the nodular eutectic carbide formation and caused the dispersion o fan abundance of the carbide in the interstices between austenite dendrite arms.

关键词: TiC , null , null

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