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Antibacterial Property of Cu Modified Stainless Steel by Plasma Surface Alloying

ZHANG Xiang-yu , HUANG Xiao-bo , JIANG Li , MA Yong , FAN Ai-lan , TANG Bin

钢铁研究学报(英文版)

Abstract: Stainless steel (SS) is not recommended to be used in hospital environments for work surfaces and door furniture due to the lack of antibacterial properties. To this end, a novel SS surface modified layer with both a quick bacterial killing rate and relatively thick has been obtained by plasma surface alloying with Cu. The microstructure, elements distribution and phase identification were analyzed by SEM, GDS, XRD and XPS. A spread plate method was adopted for evaluation of antibacterial property of specimens against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). The experimental results demonstrate that the surface modified layer with the thickness of about 26 μm is uniform and dense. The layer is mainly composed of a mixture of pure Cu, expanded austenite phase and a few Fe3O4 phase. The Cu modified layer exhibits excellent antibacterial effects against E. coli and S. aureus within 1 h. No viable E. coli and S. aureus was found after 3 h (100% killed). The modified layer is relatively thick, hence it is expected that the Cu modified SS will have a durable antibacterial function.

关键词: Key words: plasma alloying , Cu , antimicrobial , AISI 304 stainless steel

The crossover from parallel shift to fan-shape broadening of the superconducting transition of La(1.44)Nd(0.4)Sr(0.16)CuO(4) films in magnetic fields

Superconductor Science & Technology

In this paper we report the transport properties of c-axis-oriented superconducting La(1.44)Nd(0.4)Sr(0.16)CuO(4) films on LaSrAlO(4) substrates with different thicknesses in various magnetic fields parallel and perpendicular to the c axis of the films. It is found that with decreasing film thickness there is a crossover from the parallel shift to fan-shape broadening in the resistive transitions. Moreover, for both field configurations, the flux pinning potential U(0)(H) of the film shifts upward with an order of magnitude with increasing in-plane compressive strain. These results indicate that the compressive epitaxial strain and strain-induced destabilization of the static charge stripes are important aspects for the promotion of superconducting transition temperature as well as the flux pinning potential.

关键词: high-temperature superconductors;crystal thin-films;flux motion;la2-xsrxcuo4;strain;insulator;dependence;behavior

Formation of PFZ and Its Effect in a RSP AI-Li Alloy

Liang ZHEN Yuexian CUI Dezhuang YANG Department of Materials Science , Harbin Institute of Technology , Harbin , 150006 , ChinaShenglong DAI Guifu YU Beijing Institute of Aeronautical Materials , Beijing 100095 , China

材料科学技术(英文)

The formation of precipitation free zone (PFZ) and its effect in a RSP AI-Li alloy has been studied. The results show that PFZ is easy to form when aged at 190℃,but there is no equilibrium phase on grain boundaries.The growth of PFZ in the alloy is different from that in conventional AI-Li alloys, The effect of PFZ is of great importance because of its large volume fraction in the alloy.It offsets the beneficial effect of RSP,and is thought to be an important factor that leads to the poor toughness and low ductility of RSP AI-Li alloy sheet.

关键词: precipitation free zone , null , null , null

DETERMINATION OF ACTIVITY OF AI IN SOLID Cu-Al ALLOYS

ZHANG Qianxiang , University of Science and Technologys Beijing , Beijing , China

金属学报(英文版)

Activities and activity coefficients of Al in solid Cu-AI alloys have been determined by meansof solid electorlyte galvanic cells Al(a_1 , in alloy), Al_2O_3 ZrO_2·Y_2O_3 Ni, NiOand Al(a_1, in alloy), Al_2O_3 Na, βAl_2O_3 Al(a_2 , in alloy), Al_2O_3

关键词: Cu-Al alloy , null , null , null , null

EFFECTS OF DIFFUSION WELDING PARAMETERS ON JOINT STRENGTH OF SiCw/6061AI COMPOSITE

L.M. Liu , J.T. Niu , Z.H. Lai , Y.L. Guo and J.P. Zhai (National Key Laboratory of Advanced Welding Production Technologyt HIT , Harbin 150001 , China)

金属学报(英文版)

Diffusion welding was used to join SiCw/6061AI composites. The effects of welding pammeters on strength Of welded joint were investigated. JOint Of high quality for SiCw/6061Al composites can be obtained with aPPropriate diffesion welding parameters.

关键词: diffusion welding , null

低伤害高温酸化缓蚀剂AI-811的开发及机理

王宝峰 , 胡恩安

腐蚀学报(英文)

低伤害、耐高温缓蚀剂AI-811是以咪唑啉季铵盐为主 体,并复合含S、含酮、含酰胺的混合成分,适用于HCl、盐酸/氢氟酸(HCl/HF)及醋酸等 有机混合酸液体系.其主要特点是高温缓蚀效果好,可预防或大大降低酸液对低渗储层的伤 害,使用浓度低,气味极小,与酸液中的其他添加剂配伍性好,适用性强,与缓蚀增效剂AI -800协同使用可在高达190℃下显示独特的优良缓蚀性能. 用CC-10-S高温高压动态腐蚀实验仪对AI-811的高温缓蚀性能进行了评价.结果表明:AI-811 及其AI-800在高温、高压、动态条件下对各种酸溶液具有很好的缓蚀效果,可使N-80油管 钢在高达190℃的储层温度下腐蚀速度大幅度降低,平均腐蚀速度<100 g/m2·h.

关键词: 酸化缓蚀剂 , high temperature , corrosion

低伤害高温酸化缓蚀剂AI-811的开发及机理

王宝峰 , 胡恩安

腐蚀学报(英文) doi:10.3969/j.issn.1002-6495.2001.05.011

低伤害、耐高温缓蚀剂AI-811是以咪唑啉季铵盐为主体,并复合含S、含酮、含酰胺的混合成分,适用于HCl、盐酸/氢氟酸(HCI/HF)及醋酸等有机混合酸液体系.其主要特点是高温缓蚀效果好,可预防或大大降低酸液对低渗储层的伤害,使用浓度低,气味极小,与酸液中的其他添加剂配伍性好,适用性强,与缓蚀增效剂AI-800协同使用可在高达190℃下显示独特的优良缓蚀性能.用CC-10-S高温高压动态腐蚀实验仪对AI-811的高温缓蚀性能进行了评价.结果表明:AI-811及其AI-800在高温、高压、动态条件下对各种酸溶液具有很好的缓蚀效果,可使N-80油管钢在高达190℃的储层温度下腐蚀速度大幅度降低,平均腐蚀速度<100 g/m2@h.

关键词: 酸化缓蚀剂 , 腐蚀 , 高温

Electromagnetic filteration of primary Fe-rich phases from AI-Si alloy melt

Zhenming XU , Tianxiao LI , Da SHU , Yaohe ZHOU

材料科学技术(英文)

Electromagnetic filtration primary Fe-rich phases (complex compound of AlFeSiMn) from Al-Si alloy melt containing 1.2 wt pet Fe have been studied by theoretical analysis and on a self-designed electromagnetic filtration equipment. The principle of the electromagnetic filtration is that the EMF (electromagnetic force) scarcely acts on the primary Fe-rich phases having low electric conductivity, which are then moved in the direction opposite to that of the EMF. Experimental results show that the primary Fe-rich phases are separated from AI-Si alloy melt and are collected in the filter while the melt is in horizontal flow. The removal efficiency of the primary iron-phases (eta) calculated is less as the greatest flow velocity of the melt (u(M)) and the height of the filter (2h) are larger, while it becomes larger as EMF, operating distance of electromagnetic force (x) and particle size (d(p)) become larger. It has been confirmed that the primary iron-phases larger than 20 mum can be removed efficiently by theoretical analysis and experiments. This new technique is high efficient and available for continuously flowing melts as compared with natural settling and filtration methods, which offer a Possibility for recycling high quality aluminum alloys.

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