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Influence of Pre-oxidation on the Hot Corrosion of DZ68 Superalloy in the Mixture of Na2SO4-NaCl

Enze Liuy Zhi Zheng Xiurong Guan Jian Tong Likui Ning Yongsi Yu

材料科学技术(英文)

DZ68 alloy is a new Ni-base directionally solidified superalloy for the blade of advanced turbine engine with high ratio of thrust-mass. In order to investigate the influence of pre-oxidation on the hot corrosion resistance of DZ68 alloy, pre-oxidation treatment was conducted at 950°C in air for 20 h. A mixture of 75% Na2SO4+25% NaCl (in mass fraction) was used for hot corrosion study at 900°C. The microstructure of specimens was investigated by using a scanning electron microscope (SEM) equipped with an energy dispersive spectroscopy (EDS). The compositions of the corroded specimens were determined by X-ray diffraction (XRD). After preoxidation at 950°C in air for 20 h, a protective scale consisting of Cr2O3, Al2O3, NiO, NiCr2O4, and Ni2Ti4O formed on the DZ68 superalloy surface. The pre-oxidation treatment improved the initial incubation stage of the alloy in the mixture of 75% Na2SO4+25% NaCl melts at 900°C. The oxide layer degraded gradually with increasing the time of hot corrosion. Once the oxide layer was damaged, the corrosion rate would increase rapidly, accompanied by obvious spallation of the corrosion products. At 900 °C, the pre-oxidation treatment could not inhibit the accelerated hot corrosion of DZ68 in the mixture of 75% Na2SO4+25% NaCl melts, with a high corrosion rate.

关键词: DZ68 superalloy , null , null

1998 COMPREHENSIVE TABLE OF CONTENTS

中国腐蚀与防护学报

N。1Atmospheric Corrosivlty for Steels………………………………………………… .LIANG Caideng HO[I i。-tat(6)Caustic Stress Corrosion Cr。king of Alloy 800 Part 2.The Effect of Thiosul执e……………………………………… KONG De-sheng YANG Wu ZHAO Guo-zheng HUANG De.ltL。ZHANG Yu。。he CHEN She。g-bac(13)SERS slid E16CttOCh6iniC81 Stlldy Of Illhibit1Oli M6ch&tllsth Of ThlollY68 Oil ITOll ID H....

关键词:

Improving the electrochemical properties of natural graphite spheres by coating with a pyrolytic carbon shell

新型炭材料

Two kinds of modified natural graphite (MNG) spheres with a pyrolytic carbon shell on smooth or granular surface were obtained using fluidized bed chemical vapor deposition of acetylene by adjusting the reaction parameters. The core of the NING has a highly ordered graphite structure and the shell has a disordered structure. Compared with natural graphite (NG) spheres, MNG with a core-shell structure shows improved first cycling efficiency and cyclability. Especially, the NING spheres with a granular surface possess 84% retention of the first discharge capacity after 41 cycles, owing to effective decrease of the contact resistance and increase of contact area between the NING spheres.

关键词: fluidized bed chemical vapor deposition;core-shell structure;pyrolytic;carbon;modified natural graphite;lithium ion secondary battery;lithium-ion batteries;chemical-vapor-deposition;1st-cycle charge loss;anode material;encapsulated graphite;surface-area;infiltration;performance;improvement;pyrocarbon

3 0CrMnSi 2A钢飞机主梁疲劳断裂分析

马康民 , 宣建光 , 康进兴

材料工程 doi:10.3969/j.issn.1001-4381.2001.10.012

用扫描电镜观察了某型飞机机翼主梁的疲劳断口,用疲劳条带估算了裂纹扩展寿命,并用Zheng-Hirt公式估算出裂纹尖端应力强度因子范围,估算结果与实验测定值十分接近,从而为研究老龄飞机的使用寿命,进行了有益的探索.

关键词: 机翼主梁 , 30crMnSiNi2A , 疲劳裂纹扩展寿命

Monte Carlo simulation of angular distribution and fractionation in the zero-fluence isotope sputtering

Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms

A static Monte Carlo simulation program has been used to study the influence of primary and secondary knock-on atoms on the angular distribution and the fractionation, for zero-fluence sputtering of Mo-92-Mo-100. At 10 keV Xe ion energy, calculations show that significant depth-dependent momentum asymmetry exists in the near-surface region, as in Refs. (L.P. Zheng, R.S. Li, M.Y.LI, Nucl. Instr, and Meth. B 100 (1995) 490; L.P. Zheng, M.Y. Li, Nucl. Instr. and Meth. B 114(1996) 28). The calculations also show that at the polar emission angle range between 0 degrees and 90 degrees the probabilities of the sputtered primary knock-on atoms for Mo-92 and Mo-100 are small (6.1% for Mo-92 and 6.6% for Mo-100), especially, between 0 degrees and 30 degrees they are very small (2.5% for Mo-92 and 2.8% for Mo-100). At 0.1 keV Ar ion energy, the calculations show that partial momentum flux ratios, for the primary and the secondary knock-on atoms, deviate far from one, through marker plane 1 (about an atomic layer distance from the surface). (C) 1998 Elsevier Science B.V. All rights reserved.

关键词: mo-92-mo-100;targets

LC4铝合金稀土转化膜耐蚀性及影响因素

张巍 , 李久青 , 许江涛 , 陈昆

腐蚀学报(英文) doi:10.3969/j.issn.1002-6495.1999.06.004

开发了IC4铝合金稀土转化膜碱性两步成膜工艺ZH1,利用正交优化设计方法确定了最佳工艺参数.采用多种实验方法研究了经ZH1处理的LC4铝合金在氯化物环境中的耐蚀性及其影响因素,结果表明:经ZHI工艺处理过的LC4铝合金耐全面腐蚀和点蚀性能均有明显提高,稀土转化膜既抑制了腐蚀的阴极过程,也抑制了阳极过程.具有ZH1转化膜的LC4铝合金对氯离子浓度和pH值的变化不甚敏感.

关键词: 高强铝合金 , 稀土转化膜 , 耐蚀性学科

DL-EPR法评价2205双相不锈钢晶间腐蚀敏感性

徐菊良 , 邓博 , 孙涛 , 李劲 , 蒋益明

金属学报 doi:10.3724/SP.J.1037.2009.00598

利用Thermo-Calc软件并结合金相显微镜,定性研究了2205双相不锈钢在800℃下敏化不同时间后的微观组织演变过程.通过研究扫描速率、介质成分、介质温度和试样表面状态优化了双环电化学动电位再活化法(DL-EPR),并用该优化方法研究了2205双相不锈钢晶间腐蚀敏感性.结果表明:DL-EPR法能定量评价σ相对2205双相不锈钢晶间腐蚀敏感性的影响,随敏化时间延长,σ相含量增多,晶jian 腐蚀敏感性也随之增加.腐蚀形貌的观测验证了这一规律,

关键词: 2205双相不锈钢 , DL-EPR , 晶间腐蚀敏感性 , σ相

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