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In Vivo and In Vitro Degradation Behavior of Magnesium Alloys as Biomaterials

Dingchuan Xue

材料科学技术(英)

The corrosion behavior of pure Mg, AZ31, and AZ91D were evaluated in various in vitro and in vivo environments to investigate the potential application of these metals as biodegradable implant materials. DC polarization tests and immersion tests were performed in different simulated body solutions, such as distilled (DI) water, simulated body fluid (SBF) and phosphate buffered solution (PBS). Mg/Mg alloys were also implanted in different places in a mouse for in vivo weight loss and biocompatibility investigations. The in vivo subcutis bio-corrosion rate was lower than the corrosion rate for all of the in vitro simulated corrosive environments. The Mg/Mg alloys were biocompatible based on histology results for the liver, heart, kidney, skin and lung of the mouse during the two months implantation. Optical microscopy and scanning electron microscopy were carried out to investigate the morphology and topography of Mg/Mg alloys after immersion testing and implantation to understand the corrosion mechanisms.

关键词: Mg/Mg alloys

Numerical Simulation and Shrinkage Defects Prediction of a Turbine Blade Investment Casting

Jing TIAN , Xiang XUE , Yuebing ZHANG , Yalong GAO , Luzhi LIU , Qin SUN , Shiyou YUAN

材料科学技术(英)

By adopting the solid modeling software SoldEdge and the enmeshment software SRIFCast as the pre-processing platform, a Ni based alloy turbine blade was three-dimensionally modeled and automatically enmeshed. A software code for numerical simulation of fluid flow and heat transfer was developed. The Xue criterion and Niyama criterion were used to predict the position of the shrinkage defects occurring in the solidification processes of the turbine blade. The results showed that both Xue and Niyama criteria could precisely predict the shrinkage defects in the Ni based alloy turbine blade. This indicates that numerical simulation is a significant tool in improving casting quality.

关键词:

First-principle study of electronic properties of Ti3Si1-xAlxC2 solid solutions

Journal of Physics and Chemistry of Solids

The layered ternary ceramics Ti3SiC2 and Ti3AlC2 are isostructural and can form Ti3Si1-xAlxC2 solid solutions combining the advanced properties of both compounds [H.B. Zhang, Y.C. Zhou, Y.W. Bao, M.S. Li, Improving the oxidation resistance of Ti3SiC2 by forming a Ti3Si0.90Al0.1C2 solid solution, Acta Mater. 52 (2004) 3631-3637; E.D. Wu, J.Y. Wang, H.B. Zhang, Y.C. Zhou, K. Sun, Y.J. Xue, Neutron diffraction studies of Ti3Si0.9Al0.1C2 compound, Mater. Lett. 59 (2005) 2715-2719; J.Y. Wang, Y.C. Zhou, First-principles study of equilibrium properties and electronic structure of Ti3Si0.75Al0.25C2 solid solution, J. Phys.: Condens. Matter 15 (2003) 5959-5968; Y.C. Zhou, J.X. Chen, J.Y. Wang, Strengthening of Ti3AlC2 by incorporation of Si to form Ti3Al1-xSixC2 solid solutions, Acta. Mater. 54 (2006) 1317-1322]. In the present work, the solid solutions of Ti3Si1-xAlxC2 (x = 0, 0.25, 0.33, 0.5, 0.67, 0.75, 1) are investigated by first-principle calculations based on pseudo-potential plan-wave method within the density functional theory framework. The results show that as Al content increases in the solid solution, all the bonds have weakened to certain extents, which lead to an unstable structure both energetically and geometrically. The calculated results are compared and discussed with the reported data for the Ti3Si1-xAlxC2 solid solutions. (c) 2007 Elsevier Ltd. All rights reserved.

关键词: ceramics;ab initio calculations;electronic structure;electrical;conductivity;oxidation behavior;mechanical-properties;ti3sic2;temperature;ti3alc2;air;si

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