材料期刊网

ELECTROCHEMICAL STUDY OF ACTIVITY OF Nb_2O_5 AND MnO IN Nb_(?)O_(?)-MnO-SiO_(?)SYSTEM

ZHANG Shengbi WEI Shoukun WANG Ruiyin LI Liman University of Science and Technology Beijing , Beijing , China ZHANG Shengbi Professor , Dept.of Metallurgical Physical Chemistry , University of Science and Technology Beijing , Beijing 100083 , China

金属学报(英文版)

Equilibrium between liquid iron containing Nb with Nb_2O5-MnO-SiO_2 slag was investigated at 1828 K,the solid electrolyte oxygen concentration cell being used to measure the activity of oxygen in the metal bath.The activity of Nb_O_5 and MnO in the slag was evaluated, accompanied with an iso-activity diagram of a_(Nb_2O_5) and a_(MoO) in Nb_2O_5-MnO-SiO_2 slay.

关键词: activity , null , null

用DEPT135测定Resol的组成及微细结构参数

杨金瑞 , 余尚先 , 顾江楠

高分子材料科学与工程

通过对resol(羟甲基酚化合物和低分子量羟甲基酚树脂)DEPT135图谱的分析讨论,得到一系列计算resol微细结构参数的经验公式.根据DEPT135图谱可判断是否发生缩聚反应,根据经验公式可计算酚单体各个活性点参与反应百分率或酚羟基导入率、不同类型缩聚所占百分率及低分子量羟甲基酚树脂的平均核体数.

关键词: 羟甲基酚化合物 , 羟甲基酚树脂 , DEPT135 , 结构参数

ELECTROCHEMICAL MEASUREMENTS OF COMPONENT ACTIVITIES IN METALLURGICAL SLAGS

O. Volkova , P.R.Scheller , D.Janke

金属学报(英文版)

The up-to-date status of FeO, CaO, SiO2, P2O05,Ti2O3 and Cr2O3 activity measurements in metallurgical slags using electrochemical sensors is outlined. A description of theoretical concepts and practical sensors is presented including their determining features.

关键词: electrochemical measurement , null , null

Thermo electrochemistry and its application to metallurgical research

Zheng FANG , Quanru ZHANG , Hengzhong ZHANG , Yuan FANG

材料科学技术（英文）

The thermoelectrochemistry (TEC), a novel cross discipline, is presented, including the basic equations for a cell and a half-cell reaction, the treatment of experimental data and its application to electro-generative leaching of mineral and to measuring thermodynamic and kinetic data of an electrode reaction. The TEC technology will play an important part in the research on the metallurgical process under various fields.

关键词:

Metal-Free Heterogeneous Catalysis for Sustainable Chemistry

Chemsuschem

The current established catalytic processes used in chemical industries use metals, in many cases precious metals, or metal oxides as catalysts. These are often energy-consuming and not highly selective, wasting resources and producing greenhouse gases. Metal-free heterogeneous catalysis using carbon or carbon nitride is an interesting alternative to some current industrialized chemical processes. Carbon and carbon nitride combine environmental acceptability with inexhaustible resources and allow a favorable management of energy with good thermal conductivity Owing to lower reaction temperatures and increased selectivity, these catalysts could be candidates for green chemistry with low emission and an efficient use of the chemical feedstock This Review highlights some recent promising activities and developments in heterogeneous catalysis using only carbon and carbon nitride as catalysts The state-of-the-art and future challenges of metal-free heterogeneous catalysis are also discussed.

关键词: carbon;catalyst;heterogeneous catalysis;selectivity;sustainable;chemistry;graphitic carbon nitride;modified activated carbon;nanofiber/graphite-felt composite;ordered mesoporous carbons;oxygen;reduction reaction;nitrogen-doped graphite;fuel cell cathode;onion-like carbon;oxidative dehydrogenation;hydrogen-production

Jet Behavior and Metallurgical Performance of Innovated DoubleParameter Oxygen Lance in BOF

YUAN Zhangfu , YANG Xiao , LU Zhixing , HUANG Jiangning , PAN Yifang , MA Enxiang

钢铁研究学报(英文版)

A doubleparameter oxygen lance used in a 300 t converter was designed to improve the metallurgical performance. A smallscale measurement of the jet behavior was done using a computer controlled scanning system. The experimental data on the velocity distribution at the jet centerline, the contour map of the jet velocity, the deviation of the jet centerline, and the velocity distribution of the axial section were compiled. According to the results of the smallscale measurement, the doubleparameter lance was also employed for a BOF experiment. The metallurgy indexes show that the metallurgical performance was highly promoted by use of the doubleparameter lance.

关键词: oxygen lance;jet behavior;BOF;metallurgical performance

SERS and Quantum Chemistry Studies of Adsorption of Thiourea and Ethylthiourea on Silver Electrode

Acta Physico-Chimica Sinica

Adsorption of thiourea (TU) and ethylthiourea( ETU) on roughened silver electrode was investigated using in situ surf. enhanced Raman spectroscopy(SERS) Using quantum chemistry and HSAB theories, the influences of electrode potential and the different substituent groups on SERS were disc i. TU is chemisorbed perpendicularly by Ag-S bond on silver at E = -0.3 V and adsorption of TU turns into a parallel orientation at E = -0.9 V. ETU is always chemisorbed at an angle from Ag. The adsorption of ETU is through and C=C and C=O groups at E = -0.3 V, and mainly through C=C at E = -0.9V.

关键词: Surface enhanced Raman spectroscopy;Adsorption;Quantum chemistry;Thiourea;Inhibitor

LOCAL CHEMISTRY AND THE COHESIVE STRENGTH OF GRAIN BOUNDARIES IN Ni_3Al

Shanthi Subramanian , David Muller , John Silcox and Stephen L.Sass (Department of Materials Science and Engineering and Department of Applied and Engineering Physics , Cornell University , Ithaca. NY 14853)

金属学报(英文版)

Local chemistry plays an important role in determining the cohesive strength of grain boundaries in Ni3Al. Doping with B increases the room temperature ductility and changes the fracture mode from intergranular to transgranular, while doping with Zr increases the ductility but leaves the fracture mode predominantly intergranular.Electron Energy Loss Spectroscopy (EELS) and Energy Dispersive X-ray Spectroscopy (EDS) were used to probe the changes in local bonding (and hence the cohesive strength) produced by changes in local chemistry at large angle boundaries in Ni3Al.In addition , small angle tilt boundaries were studied to correlate structure with Nienrichment at the interface. B segregation to Ni-rich grain boundaries was shown to make the bonding similar to that of the bulk, thereby increasing their fracture resistance. Ni-enrichment does not occur in the presence of Zr segregation to grain boundaries. Ni-enrichment to antiphase boundaries (APB) in small angle tilt boundaries lowers the APB energy by reducing the number of high energy Al-Al interactions across the interface. Ni-enrichment to large angle boundaries is expected to produce a similar effect on energy.

关键词: : grain boundary chemistry , null , null , null

MEASUREMENT AND APPLICATION OF PHYSICAL PARAMETERS IN UNSTEADY HEAT CONDUCTION

S. X. Wanng , D. S. Zheng , Y. L. Liu 1) Department of Material Engineering , Luoyang Institute of Technology , Luoyang 471039 , China 2) Luoyang Copper (Group) Co. , Ltd , Luoyang , China

金属学报(英文版)

As far as the accuracy of calculating unsteady temperature field is concerned, it is very important to find the accurate physical parameters such as specific heat, thermal conductivity, latent heat of phase transformation and surface heat flux. The model for calculating H and Q is established in this paper. The measurement methods and data processing for physical parameters such as volume specific heat C, thermal conductivity k, volume latent heat of phase transformation c1 and surface heat flux are introduced The physical parameters of 1Cr18Ni9Ti and 45 steels and the surface heat flux for 1 Cr18Ni9Ti probe cooled in water,10% NaCl water and oil with different temperatures are measured, respectively. These data show that the probability of absolute error less than 2* C between the calculated and measured values in temperature field calculation reaches above 80% if using the above physical parameters, which provides a reliable technology basis for precise calculation of temperature field.

关键词: unsteady temperature field , null

Effect of Hydrogen Addition on Low Temperature Metallurgical Property of Sinter

MU Lin , JIANG Xin , GAO Qiang-jian , WEI Guo , SHEN Feng-man

钢铁研究学报(英文版)

Abstract： Hydrogen-enrich iron making process is certainly to be an effective method to reduce greenhouse gases emission. However, the effect of hydrogen addition on the low temperature metallurgical property of sinter is still unclear. A detailed investigation was performed on the above topic. The results are as follows. When CO is partially replaced by H2, the RDI＜315 (RDI＜28) of sinter decreases with the increase of the H2 content; when the content of H2 increases, the CO, CO2 and N2 decrease proportionally, in this case, RDI＜315 (RDI＜28) of sinter increases with the increase of H2 content; the value of RDI＜315 (RDI＜28) basically depends on the reduction index (Ri).The experimental data of RDI＜28 based on Japanese industrial standard (JIS) are a little higher than the data of RDI＜315 based on Chinese industrial standard (CIS) in the same condition. In addition, for part of CO is replaced by H2: RDI＜28=338394+11585 RDI＜315; for other gases, except H2, are decreased proportionally: RDI＜28=1739678+042922 RDI＜315.

关键词: Key words: sinter , hydrogen , reduction disintegration index (RDI) , metallurgical property