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Correlation of the Mechanical Properties of Polycrystalline Ni_3Al Alloys with Their Electronic Structure

Wen DENG Liangyue XIONG Chiwei LUNG International Centre for Materials Physics , Institute of Metal Research , Academia Sinica , Shenyang , 110015 , ChinaShuhe WANG Jianting GUO Institute of Metal Research , Academia Sinica , Shenyang , 110015 , China

材料科学技术(英文)

The electronic structure of Ni_3Al alloys with different B contents has been investigated by measuring the positron lifetime spectra.The segregation of B atoms to defects could form strong covalent bondings with Ni and Al atoms and make the electronic structure in those locations similar to that in bulk,thus strengthen their cohesion.The interaction of B atoms,which were solid-solutioned in the crystal lattice of Ni_3Al in a manner of occupying interstitial sites,with Ni and Al atoms resulted in the increase of the density of valent electrons,thus increased the bonding cohesion in bulk.The im- provement of the mechanical properties of Ni_3Al alloys by B doping was due to both“grain bounda- ry effect”and“bulk effect”of B,which correlated with their electronic structure.

关键词: electronic structure , null , null , null

MICROSTRUCTURE AND PROPERTIES OF SiC_w/6061Al COMPOSITE The Author is now with Institute of Metal Research,Academia Sinica,China

MA Zongyi YAO Zhongkai Harbin Institute of Technology , Harbin , China

金属学报(英文版)

The SiC_w/Al composite prepared by squeeze casting has a combination of superior room temperature specific strength and modulus together with excellent thermal properties.The extrusion can make an improvement on the strength and ductility of the composite from 582 MPa as squeeze casted up to 639 MPa,and on the transformation from isotropic to the anisotropic structure.This seems to be explained by the orientation of whiskers and the densification of dislocations in matrix.TEM observation indicates that the stacking fault is the usual planar defect on the SiC_w surface. composite;;SiC whisker;;Al alloy;;microstructure

关键词: composite , null , null , null

Technical note: Research and development of localized corrosion rate monitoring instrument for nonpassivable metal in corrosive media

Corrosion

This paper introduces the design of a localized corrosion rate monitoring instrument that can monitor and evaluate the maximum and stable localized corrosion rate of a nonpassivable metal in a corrosive environment by measuring the current density in a corrosion sensor with an occluded anode.

关键词: instrument;localized corrosion rate;monitor

Two-step magnetization in a spin-chain system on the triangular lattice: Wang-Landau simulation

Physical Review B

The Wang-Landau algorithm is used to study the thermodynamic and magnetic properties of triangular spin-chain system based on two-dimensional Ising model in order to understand the magnetic-order dynamics in Ca(3)Co(2)O(6) compound. The calculated results demonstrate that the equilibrium state of the rigid spins produces the two-step magnetization curve at low temperature even when the random-exchange term is considered. This work indicates that the four-step magnetization behavior observed experimentally must be due to the nonequilibrium magnetization.

关键词: calcium compounds;exchange interactions (electron);Ising model;magnetisation;thermodynamics;one-dimensional ca3co2o6;density-of-states;compound ca3co2o6;phase-diagram;proteins;crystal

Study on Process Parameters Optimization of Sheet Metal Forming Based on PFEA/ANN/GA

Juhua HUANG , Jinjun RAO , Xuefeng LI

材料科学技术(英文)

Sheet metal forming is widely applied to automobile, aviation, space flight, ship, instrument, and appliance industries. In this paper, based on analyzing the shortcoming of general finite element analysis (FEA), the conception of parametric finite element analysis (PFEA) is presented. The parametric finite element analysis, artificial neural networks (ANN) and genetic algorithm (GA) are combined to research thoroughly on the problems of process parameters optimization of sheet metal forming. The author programs the optimization scheme and applies it in a research of optimization problem of inside square hole flanging technological parameters. The optimization result coincides well with the result of experiment. The research shows that the optimization scheme offers a good new way in die design and sheet metal forming field.

关键词: Sheet metal forming , null , null , null

Metal Dusting-Mechanisms and Preventions

J.Q.ZHANGD.J.YOUNG

中国腐蚀与防护学报

Metaldusting attacks iron, low and high alloy steels and nickel-or cobalt-base alloys by disintegrating bulk metals and alloys into metal particles in a coke deposit. It occurs in strongly carburising gas atmospheres (carbon activity aC>1) at elevated temperatures (400 ℃~1000 ℃). This phenomenon has been studied for decades, but the detailed mechanism is still not well understood. Current methods of protection against metal dusting are either directed to the process conditions-temperature and gas composition-or to the development of a dense adherent oxide layer on the surface of the alloy by selective oxidation. However, metal dusting still occurs by carbon dissolving in the base metal via defects in the oxide scale. The research work at UNSW is aimed at determining the detailed mechanism of metal dusting of both ferritic and austenitic alloys, in particular the microprocesses of graphite deposition, nanoparticle formation and underlying metal destruction. This work was carried out using surface observation, cross-section analysis by focused ion beam and electron microscopic examination of coke deposits at different stages of the reaction. It was found that surface orientation affected carbon deposition and metal dusting at the initial stage of the reaction. Metal dusting occurred only when graphite grew into the metal interior where the volume expansion is responsible for metal disintegration and dusting. It was also found that the metal dusting process could be significantly changed by alterations in alloy chemistry. Germanium was found to affect the iron dusting process by destabilising Fe3C but increasing the rate of carbon deposition and dusting, which questions the role of cementite in ferritic alloy dusting. Whilst adding copper to iron did not change the carburisation kinetics, cementite formation and coke morphology, copper alloying reduced nickel and nickel-base alloy dusting rates significantly. Application of these fundamental results to the dusting behaviour of engineering alloys is discussed.

关键词: metal dusting , null , null , null , null , null

Review On Research And Development Of Magnesium Alloys

Z. Yang , J.P. Li , J.X. Zhang , G.W.Lorimer , J. Robson , null , null , null , null

金属学报(英文版)

The current research and development of magnesium alloys is summarized. Several aspects of magnesium alloys are described: cast Mg alloy, wrought Mg alloy, and novel processing. The subjects are discussed individually and recommendations for further study are listed in the final section.

关键词: Magnesium alloys , null , null

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