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CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,University of Science and Technology Beijing,Beijing 100083,China

QIAO Lijie LIU Rui XIAO Jimei University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词: stress corrosion cracking , null , null , null

Atmospheric corrosion of carbon steels pre-corroded by different pollutants

Materials and Corrosion-Werkstoffe Und Korrosion

Carbon steels were pre-corroded in atmospheres containing certain pollutants such as sulfur dioxide or hydrogen sulfide or nitrogen dioxide for certain period of time. Then the pre-corroded samples were further exposed at two central test stations in the country to evaluate the influence of pre-corrosion on the behavior of long-term atmospheric corrosion of carbon steel by gravimetric measurement and rust examinations with FT-IR and XRD. The results showed that the corrosion rates of every kind of carbon steel at Jiangjin station were two times higher than that at Beijing station. The influence of different pre-corrosion conditions on the long-term atmospheric corrosion of carbon steel was analyzed. It followed that the pre-corrosion conditions made the long-term atmospheric corrosion performance of three kinds of carbon steels different, but the differences were small. Among the three pollutants, NO2 showed the strongest influence to the process. As the exposure time was going on, all the samples corroded slowly at Beijing and Jiangjin stations.

关键词: pollution parameters;prediction;outdoor;rust

GALVANIC CORROSION AND PROTECTION OF GECM/LY12CZ COUPLES UNDER DIFFERENT ATMOSPHERIC EXPOSURE CONDITIONS

F.Lu , Q.P.Zhong

金属学报(英文版)

Galvanic compatibility between graphite epoxy composite materials (GECM) and LY12CZ aluminum alloy was evaluated in different atmospheric corrosion environ-ments and by laboratory electrochemical measurements.Open circuit potential elec-trochemical measurements showed a relatively large potemtial difference about 1 volt between the GECM and LY12CZ aluminum alloy,and this difference provided the driving force for galvanic corrosion of the LY12CZ aluminum alloy as an anode. Having been exposed for 1,3or 5years in Beijing,Tuandao and Wanning station,GECM/LY12CZ couples showed significant losses of strength and elongation.Protec-tive coatings and non-conductive barriers breaking the galvanic corrosion circuit were evaluated under the same atmospheric corrosive conditions.Epoxy primer paint,glass cloth barriers and LY12CZ anodizing were effective in glvanic corrosion control for GECM/LY12CZ couples.

关键词: galvanic corrosion , null , null

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