LI Donggui J.P.Simpson R.Schenk Dalian Acid Proof Pump Plant
,
China. Sulzer Bros.Ltd
,
Winterthur
,
Switzerland.
材料科学技术(英文)
The effect of temperature and chloride ion concentration on the electrochemical behaviour of austenitic-ferritic duplex stainless steel COR 25 in an aqueous solution of 60%H_3PO_4+4%H_2SO_4 is studied in this paper. The experiments show that the anodic active peak current on potentiodynamic polarization increases by an order of magnitude with an in- crease of temperature from 50℃ and with an increase of chloride ion from<1 mg/1 to 1500mg/1. Compared with the other materials tested, the austenitic-ferritic duplex stainless steel shows favourable corrosion characteristics in electrochemical tests,being comparable to the fully austenitic alloy Sanicro 28,which has a higher chromium and nickel content,and is much better than GX3CrNiMo2010.Corrosion of the duplex material is normally phase selec- tive,with phase boundary attack after unfavour- able heat treatments.
关键词:
temperature
,
null
,
null
,
null
LI Donggui J.P.Simpson R.Schenk Dalian Acid Proof Pump Plant
,
China. Sulzer Bros.Ltd
,
Winterthur
,
Switzerland.
材料科学技术(英文)
The effect of heat treatment on the corrosion performance of austenitic-ferritic duplex stain- less steel COR 25 in aqueous solution containing 60%H_3PO_4+4%H_2SO_4+1500 ppm Cl~- at 95℃ was in- vestigated.When the solution temperature was increased from 950℃ to 1230℃,the corrosion resistance increased by two orders of magnitude, as shown by electrochemical measurements,im- mersion tests and direct observation under the scanning electron microscope.The specimens heat treated at solution temperatures of 950℃ and 1030℃ were severely corroded along the phase boundaries;specimens treated at 113C℃ and 1230℃ tended to selective corrosion caused by the dissimilar chromium contents of the aus- tenite and ferrite phases after heat treatment.
关键词:
heat treatment
,
null
,
null
,
null
American Mineralogist
A natural high-pressure phase of titanium oxide with alpha-PbO2-structure has been found in omphacite from coesite-bearing eclogite at Shima in the Dabie Mountains, China. High-resolution transmission electron microscope observations have revealed an orthorhombic lattice, corresponding to alpha-PbO2-type TiO2, with cell parameters a = 0.461 nm, b = 0.540 nm, c = 0.497 nm and space group Pbcn. It occurs as nanometer-thick (< 2 nm) lamellae between multiple twinned rutile crystals, providing additional evidence of very high-pressure, metamorphism at 7 GPa, 900 degrees C. This implies subduction of continental material to a depth of more than 200 kilometers. alpha-PbO-type TiO2 could be an extremely useful index mineral for ultrahigh-pressure.
关键词:
high-pressure phase;ries crater;rutile;polymorph;titanium
Acta Geologica Sinica-English Edition
Transmission electron microscope (TEM) and high resolution transmission electron microscope (HRTEM) analyses have been performed on omphacite from ultra-high pressure (UHP) eclogites at the locality of Shima, Dabie Mountains, China. TEM reveals that the microstructures consist dominantly of dislocation substructures, including free dislocations, loops, tiltwalls, dislocation tangles and subboundaries. They were produced by high-temperature ductile deformation, of which the main mechanism was dislocation creep. Antiphase domain (APD) boundaries are common planar defects; an age of 470 +/- 6 Ma for UHP eclogite formation has been obtained from the equiaxial size of APDs in ordered omphacites from Shima, coincident with ages given by single-zircon U-Pb dating (471 +/- 2 Ma). HRTEM reveals C2/c and P2/n space groups in different parts of one single omphacite crystal, and no exsolution is observed in the studied samples, which is attributed to rapid cooling. It is suggested that the UHP eclogites underwent a long period of annealing at high temperatures, followed by relatively rapid cooling. These data provide valuable information for the formation and exhumation mechanism of UHP eclogites in the Dabie high-pressure (HP) and UHP metamorphic belt.
关键词:
UHP eclogite;omphacite;TEM and HRTEM;Dabie mountains;high-temperature deformation;naturally deformed omphacites;diopside;single-crystal;dislocation glide;transformation;consequences;mechanisms;rocks;shan
LIANG Yong LI Ruiguo Institute of Metal Research
,
Academia Sinica
,
Shenyang 110015
,
ChinaInstitute of Corrosion and Protection of Metals
,
Aademia Sinica
,
Shenyang
,
110015
,
China
材料科学技术(英文)
Recent advances in laser coating technology including laser cladding,laser surface alloying and laser vapour deposition in China are reviewed in this paper.
关键词:
laser
,
null
,
null
,
null
,
null