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EQUILIBRIUM OF Mg-S IN Ni MELTS

WANG Conghua HAN Qiyong University of Science and Technology Beijing , Beijing , China WANG Conghua Faculty of Physical Chemistry of Metallurgy , University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The equilibrium of Mg-S in Ni melt was studied by the method of vapour equilibrium in a sealed chamber.At 1530℃ the equilibrium constant of the reaction MgS_(s)=Mg_(Ni)+S_(Ni)and the activity interaction coefficient were determined as K_(MgS)=6.76×10~(-5)and e_S~(Mg)=-9.1.

关键词: Equilibrium constant , null , null , null , null

Two-step magnetization in a spin-chain system on the triangular lattice: Wang-Landau simulation

Physical Review B

The Wang-Landau algorithm is used to study the thermodynamic and magnetic properties of triangular spin-chain system based on two-dimensional Ising model in order to understand the magnetic-order dynamics in Ca(3)Co(2)O(6) compound. The calculated results demonstrate that the equilibrium state of the rigid spins produces the two-step magnetization curve at low temperature even when the random-exchange term is considered. This work indicates that the four-step magnetization behavior observed experimentally must be due to the nonequilibrium magnetization.

关键词: calcium compounds;exchange interactions (electron);Ising model;magnetisation;thermodynamics;one-dimensional ca3co2o6;density-of-states;compound ca3co2o6;phase-diagram;proteins;crystal

Application of Microwave Radiation to Extractive Metallurgy

LIU Chunpeng XU Yousheng HUA Yixin Kunming Institute of Technology , Kunming , 650093 , China.

材料科学技术(英文)

In applying the microwave radiation to extractive me- tallurgy,it is essential first of all to find the extent of microwave energy absorbed by various minerals experi- mentally.In this paper,more than 25 kinds of common useful minerals have been individually irradiated by a 500 W,2450 MHz microwave source in an enclosed quartz crucible to ascertain their heating temperature in a definite time.In addition,the reduction and cbloridization tests were also carried out on the titanomagnetite concentrate and pentlandite with microwave heating,respectively. These experiments indicate potential applications of util- izing microwave energy in extractive metallurgy.

关键词: microwave radiation , null , null , null

OXIDE METALLURGY-ITS PURPOSES AND PRACTICAL APPROACHES

Z. T. Ma and D. Janke(Institute of Iron and Steel Technology , Freiberg University of Mining and Technology , Germany)

金属学报(英文版)

Useder certain conditions, nonmctallic inclusions such as oxides, sulfides, nitrides and carbides are no longer harmful to sted service properties. With the new concept of oxide metallurgy, these properties can be improved by generating fine oxide inclusions which serve as heterogeneous nuclei for sulfide and fine ferrite[1-4]. A novel continuous casting (CC) process is expected to be created with the utilization of oxide metallurgy. This is also useful for the forthcoming technologies of direct rolling and near-net-shape casting. The main idea of oxide metallurgy consists of an alternative oxidation technology. It is based on steels treated by complex metals such as Ti, Zr, Ti-Zr alloys and rare earth metals. The selected deoxidants should follow the required conditions which are concluded in this paper.

关键词: oxide , null , null , null

Metal-Free Heterogeneous Catalysis for Sustainable Chemistry

Chemsuschem

The current established catalytic processes used in chemical industries use metals, in many cases precious metals, or metal oxides as catalysts. These are often energy-consuming and not highly selective, wasting resources and producing greenhouse gases. Metal-free heterogeneous catalysis using carbon or carbon nitride is an interesting alternative to some current industrialized chemical processes. Carbon and carbon nitride combine environmental acceptability with inexhaustible resources and allow a favorable management of energy with good thermal conductivity Owing to lower reaction temperatures and increased selectivity, these catalysts could be candidates for green chemistry with low emission and an efficient use of the chemical feedstock This Review highlights some recent promising activities and developments in heterogeneous catalysis using only carbon and carbon nitride as catalysts The state-of-the-art and future challenges of metal-free heterogeneous catalysis are also discussed.

关键词: carbon;catalyst;heterogeneous catalysis;selectivity;sustainable;chemistry;graphitic carbon nitride;modified activated carbon;nanofiber/graphite-felt composite;ordered mesoporous carbons;oxygen;reduction reaction;nitrogen-doped graphite;fuel cell cathode;onion-like carbon;oxidative dehydrogenation;hydrogen-production

Introduction to atmospheric corrosion research in China

Science and Technology of Advanced Materials

In this paper, we introduce the research on atmospheric corrosion in China. We describe the climate characteristics and the classification of atmospheric corrosivity across the whole country. We also describe the rusting evolution under simulated wet/dry cyclic conditions. (C) 2007 NIMS and Elsevier Ltd. All rights reserved.

关键词: atmospheric corrosion;corrosivity;rusting evolution;weathering steels;rust;mechanism;so2;o-3;no2

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