ZENG Xianghua
,
SHA Jiande
,
SU Ge Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
ChinaYUAN Jigang LIU Fumei ZHONG Huiwen Southwest Aluminium Mill
,
China National Nonferrous Metals Industry Corporation
,
Chongqing
,
China SHA Jiande
,
Engineer
,
Institute of Metal Research
,
Academia Sinica
,
Shenyang
,
China
金属学报(英文版)
The end grain attack of LDIOCS aluminium alloy plates during chemical milling in hot aqueous solution of sodium hydroxide has been studied.The results show that the microsegregation of some components,i.e.Cu,Si etc.,is the main reason of the end grain at- tack,and it is affected by the conditions of heat treatment as well.The end grain attack significantly diminishes while some technical measures which are beneficial to the reduce of segregation were taken during melting and casting.
关键词:
aluminium alloy
,
null
,
null
,
null
史小慧
,
王蕊欣
,
高保娇
,
雷彩萍
,
李艳华
高分子材料科学与工程
首先采用氯甲基化试剂1,4-二氯甲氧基丁烷对水杨羟肟酸(SHA)实施氯甲基化反应,制得氯甲基化水杨羟肟酸(CMSHA);然后以聚甲基丙烯酸羟乙酯(PHEMA)改性的硅胶微粒PHEMA/SiO2为载体,使其表面的醇羟基与CMSHA上的氯甲基基团发生亲向取代反应,制得水杨羟肟酸功能化的复合螯合吸附材料(SHA-PHEMA/SiO2).考察了取代反应的主要影响因素;并研究了SHA-PHEMA/SiO2对重金属离子的螯合性能.结果表明,CMSHA与PHEMA/SiO2之间的取代反应遵循单分子取代反应(SNl)的机理;较高温度下,强极性溶剂有利于反应的进行.SHA-PHEMA/SiO2对不同重金属离子表现出不同的螯合吸附能力,摩尔吸附容量的顺序为Cu2+> Zn2+ >Cd2+> Pb2+;SHA-PHEMA/SiO2对Cu2+离子的吸附动力学符合伪二级速率方程;其吸附行为同时遵循Freundlich和Langmuir模式.
关键词:
水杨羟肟酸
,
聚甲基丙烯酸羟乙酯
,
硅胶
,
亲核取代反应
,
螯合吸附
LIANG Yong LI Ruiguo Institute of Metal Research
,
Academia Sinica
,
Shenyang 110015
,
ChinaInstitute of Corrosion and Protection of Metals
,
Aademia Sinica
,
Shenyang
,
110015
,
China
材料科学技术(英文)
Recent advances in laser coating technology including laser cladding,laser surface alloying and laser vapour deposition in China are reviewed in this paper.
关键词:
laser
,
null
,
null
,
null
,
null
Yang LUO
材料科学技术(英文)
Due to continued growth in key markets, a broadening of application base and performance improvements, the market demands of NdFeB magnet increased steadily in 1998, and the global output of sintered NdFeB magnet exceeded 10,000 t, in spite of the economic recession in Asia. In 1998 China produced 3,850 t sintered NdFeB block magnet, with an annual growth rate of +22% over the output in 1997.
关键词:
Shaoxiong ZHOU
材料科学技术(英文)
The discovery of the first Fe-based ferromagnetic amorphous alloy in 1966 had made an impact on conventional magnetic materials because of its unique properties. Since then, a number of amorphous magnetic materials have been successfully developed and used in a wide variety of applications. A brief review of R & D activities on amorphous soft magnetic materials in China is given from the beginning to the present in a somewhat chronological order, followed by a brief introduction to their applications on electric and electronic industries. An analysis and a prospect of Chinese market of such amorphous materials are also presented.
关键词: