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CORROSION FATIGUE OF HSLA STEELS IN SALT SPRAY

HAO Hongqi SONG Yujiu Xi'an Jiaotong University , Xi'an , China Institute of Metallic Materials and Strength , Xi'an Jiaotong University , Xi'an , China

金属学报(英文版)

The corrosion fatigue propagation behaviour of high strength low alloy Cr-Ni and Si-Mn steels has been investigated in 3.5 %NaCl solution spryly at the frequencies of 0.1 and 5.5 Hz. It was shown that the fatigue crack initiation resistances of the two steels are significantly re- duced in salt spray;the fatigue crack growth rates of steels increase with the decrease of fre- quency and are much higher in salt spray than in air within low ΔK range.A critical stress in- tensity factor was observed for each steel and the crack growth stoppage will occur if the ΔK values are lower than it.It was found that the active dissolution makes great contribution to the fatigue crack growth within low ΔK range.

关键词: salt spray , null , null , null

Dependence of strength, elongation, and toughness on grain size in metallic structural materials

Journal of Applied Physics

The dependence of yield strength, uniform elongation, and toughness on grain size in metallic structural materials was discussed. The toughness is defined as the product of yield strength and uniform elongation. The yield strength versus grain size can be well described by the Hall-Petch relation; however, the uniform elongation versus grain size is not well understood yet. A simple model involving the densities of geometrically necessary dislocations and statistically stored dislocations was proposed to estimate the uniform elongation versus grain size. Existing data for low carbon steels and aluminum indicate that, in the grain size less than 1 mu m, the materials usually exhibit high strength and low uniform elongation and, in the grain size greater than 10 mu m, the materials usually exhibit low strength and high elongation; in either case the toughness is low. However, in the grain size of several micrometers, the toughness is the highest. It is suggested that we should pay more attention to develop the metallic materials with grain size of several micrometers for structural applications. (c) 2007 American Institute of Physics.

关键词: nanocrystalline copper;nanostructured metal;steels;deformation;ductility;law

High tensile strength reliability in a bulk metallic glass

Applied Physics Letters

We report high strength reliability under tension of a bulk metallic glass (BMG), demonstrated by its high uniformity in strength found over a statistically significant number of specimens, despite the fact that the samples all showed no macroscopic plasticity. Weibull statistical analysis showed that the Weibull modulus of the material is 36.5, which is much higher than the values of more typical brittle materials, further confirming BMGs' high reliability [Appl. Mech. Rev. 5, 449 (1952)]. (c) 2008 American Institute of Physics.

关键词: plasticity;alloys;temperature;brittleness;estimators;fracture;stress

Fracture mechanisms in bulk metallic glassy materials

Physical Review Letters

We find that the failure of bulk metallic glassy (BMG) materials follows three modes, i.e., shear fracture with a fracture plane significantly deviating from 45degrees to the loading direction, normal tensile fracture with a fracture plane perpendicular to the loading direction, or distensile fracture in a break or splitting mode with a fracture plane parallel to the loading direction. The actually occurring type of failure strongly depends on the applied loading mode and the microstructure of the material. Extensive evidence indicates that the Tresca fracture criterion is invalid, and for the first time, three fracture criteria are developed for isotropic materials with high strength, such as advanced BMGs or the newly developed bulk nanostructural materials.

关键词: amorphous-alloys;enhanced plasticity;zr-ti;flow;deformation;composite;strength;microstructure;ribbons;failure

Development of rapidly quenched soft magnetic materials in China

Shaoxiong ZHOU

材料科学技术(英)

The discovery of the first Fe-based ferromagnetic amorphous alloy in 1966 had made an impact on conventional magnetic materials because of its unique properties. Since then, a number of amorphous magnetic materials have been successfully developed and used in a wide variety of applications. A brief review of R & D activities on amorphous soft magnetic materials in China is given from the beginning to the present in a somewhat chronological order, followed by a brief introduction to their applications on electric and electronic industries. An analysis and a prospect of Chinese market of such amorphous materials are also presented.

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Metallic glasses: Notch-insensitive materials

Scripta Materialia

The notch tensile behavior of Zr-based bulk metallic glasses (BMGs) is investigated and compared with that of crystalline metals and ceramics. It is found that the tensile strength of the studied BMGs is insensitive to notches, and much better than that of conventional brittle materials. Moreover, notched BMGs exhibit enhanced plastic deformation ability with the formation of shear band zones, which is distinctively different from traditional metals and ceramics, while it is consistent with the nearly zero tensile plastic elongation but high toughness of BMGs. (C) 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

关键词: Metallic glass;Tension test;Plasticity;Strength;Toughness;fracture mechanisms;tensile fracture;amorphous-alloys;shear bands;toughness;plasticity;ductility;behavior;damage

Ductile Fe-Nb-B bulk metallic glass with ultrahigh strength

Applied Physics Letters

The authors report a simple Fe-based Fe(71)Nb(6)B(23) ternary bulk metallic glass with a record high strength of 4.85 GPa as well as an appreciable compressive plastic strain of 1.6%. This finding is associated with the unique attribute of the alloying element Nb, which favors the formation of a networklike structure and holds high Poisson's ratio. A fracture feature with a combination of vein pattern and nanoscale corrugations under compression is clearly characterized in this glass. The fractographic observations correlate well with the observed improvements in plasticity. (c) 2008 American Institute of Physics.

关键词: mechanical-properties;supercooled liquid;alloy;plasticity

Mg-based bulk metallic glass composites with plasticity and high strength

Applied Physics Letters

Composite alloys of (Mg0.65Cu0.075Ni0.075Zn0.05Ag0.05Y0.1)(100-x)Fe-x(x=9 and 13) have been produced through copper mold casting, based on a good bulk metallic glass former. Upon cooling the melt, an alpha-Fe solid solution precipitates uniformly with sizes in the 1-10 mum range while the remaining melt undergoes a glass transition. The in situ composite has a compressive strength as high as similar to1 GPa, a factor of 1.6 higher than the single-phase metallic glass. In contrast to all the previous Mg-based monolithic glasses that always fail in the elastic regime, a plastic strain to failure of the order of 1% was obtained for the Fe-toughened composite. (C) 2003 American Institute of Physics.

关键词: matrix composites;mechanical-properties;amorphous-alloys;behavior;ag

High strength ductile Cu-base metallic glass

Intermetallics

Usually, bulk metallic glasses exhibit strength values superior to conventional crystalline alloys, often combined with a large elastic limit and rather low Young's modulus. This combination of properties renders such alloys quite unique when compared to commercial materials. However, the major drawback for engineering applications is their limited room temperature ductility and toughness due to the localized deformation processes linked to shear banding, where high plastic deformation is accumulated in a very narrow region without contributing to macroscopic deformation, work hardening or yielding. In this work we report on a new class of metallic glass in a simple Cu-base alloy. Addition of 5 at.% Al increases the glass-forming ability of binary Cu50Zr50. The resulting Cu47.5Zr47.5Al5 glass exhibits high strength (2265 MPa) together with large room temperature ductility up to 18%. After yielding a strong increase in the flow stress is observed during deformation. The structure of the metallic glass exhibits atomic-scale heterogeneities that enable easy nucleation and continuous multiplication of shear bands. The interaction and intersection of shear bands increases the flow stress of the material with further deformation, leading to a 'work hardening'-like behavior and yields a continuous rotation of the shear angle up to fracture resulting in a high compressive ductility. (c) 2006 Elsevier Ltd. All rights reserved.

关键词: glasses;metallic;mechanical properties at ambient temperature;work-hardening;microstructure;nanostructure-dendrite composite;mechanical-properties;matrix;composites;enhanced plasticity;thermal-stability;amorphous-alloys;zr-ti;bulk;microstructure;particles

Enhanced strength and plasticity of a Ti-based metallic glass at cryogenic temperatures

Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing

Conventional crystalline materials usually exhibit a ductile to brittle transition behaviour at low temperatures. An increase in the strength is always accompanied by a decrease in the plasticity. Here the authors report on a significant enhancement in both compressive strength and plasticity of a Ti-based bulk metallic glass (BMG) deformed at low temperatures. The ductilization of the BMG system can be evidently attributed to the formation of dense shear bands and the rotation mechanism of shear bands. The cryogenic Surroundings can effectively slow down the mobility and diffusion of the atoms and consequently, suppress the nucleation and growth of nanocrystals during the deformation process, allowing the simultaneous improvement in the mechanical responses of the glassy alloy to compressive loading far below the ambient temperature. (C) 2008 Elsevier B.V. All rights reserved.

关键词: Metallic glasses;Mechanical properties;Cryogenic temperatures;Shear;bands;Plasticity;bulk amorphous-alloys;shear bands;mechanical-properties;matrix;composites;room-temperature;deformation;tensile;ductility;nanocrystallization;behavior

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