J.L. Li
,
K.F. Wang
,
J. Li
,
Z.M. Yao and W. Ke(Fushun Petroleum Institute
,
Fushun 113001
,
China)(Department of Chemical Engineering
,
Zhejiang University
,
Hangzhou 310027
,
China)(Institute of Corrosion and Protection of Metals
,
The Chinese Academy of Sciences
,
Shengyang 110015
,
China)
金属学报(英文版)
Influence of hydrogen attack on mechanical and fatigue properties of 1020, 15CrMo and 2.25Cr-1Mo steels has been studied, which were exposed to gaseous hydrogen at pressure of 18MPa and 300-480℃ for up to 480h. The results of fatigue test showed that hydrogen attack (HA) resulted in an obvious change in fatigue properties of 1020 and 15CrMo steels, however, 2.25Cr-1Mo steel showed a lower susceptibility to hydrogen attack due to the addition of Cr and Mo. Fatigue crack behaviour for 1020 steel is attributed to hydrogen attack damage and the crack closure induced by the rough cracking surface, which lead to a valley on △Kth～HA% plot. The change in the fatigue behaviour of 15CrMo steel is possibly caused by severe surface decarburization.
关键词:
hydrogen attack
,
null
,
null
,
null
LI Hiaogang
,
MENG Qinghai
,
CHEN Hua
,
CHEN Jinwei
,
YAO Zhiming
,
KE Wei(State Key Laboratory of Corrosion Science
,
Institute of Corrosion and Protection of Metals
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)(Fushun Petroleum Institute
,
Fushun 113001
,
China)
金属学报(英文版)
Hydrogen attack occurred in low carbon steel and steel 25CrMo which had been exposed in hydrogen under 18MPa at 450 and 500℃ for 240,480 and 720 h.The methane bubbles and microcracks grow along grain boundaries.The degree of hydrogen attack increases with increasing exposure time and temperature.Magnetic acoustic emission(MAE) was used to detect the degree of hydrogen attack.The results show that the characteristics of MAE for samples of low carbon steel and steel 15CrMo with hydrogen attack have changed obviously comparing to the samples without hydrogen attack,and the MAE signals was sensitive to the degree of hydrogen attack at the last stage of hydrogen attack.The magnetic detection way,as a new method of nonrestrictive testing of hydrogen attack,can be used to detect the hydrogen attack in practice.
关键词:
:magnetic acoustic emission
,
null
,
null
,
null
WU Lijun
,
ZHAO Lihua
,
YANG Qiaoqin
,
LI Shaolu
,
LI Xieqian(Materials Research and Test Centre
,
Hunan University
,
Changsha 410082
,
China)(Laboratory of Atomic Imaging of Solids
,
Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)
金属学报(英文版)
The structure of Al-Mn-Zn-Mg alloy powder annealed at 800℃ has been studied by transmisston electron microscopy(TEM).An approximant phase(named as C-phase) to the decagonal phase was found and its crystal structure was determined It belongs to c-center orthorhombic lattice with a=2.35 nm,b=3.27 nm and c=1.22 nm.We stillfound a hexagonal phase with a=0.7) nm and c=0.79 nm,(named as phase) in the annealed alloy powder.The annealed alloy powder is composed of the C-phase,the phase,the decagonal phase and Al solid solution.
关键词:
:quasicrystal
,
null
,
null
W.J. Li
,
Z.M. Wu
,
J.F. Zhao
,
Z.H. Wu
,
X.L.Zhao and B.C. Cai ( Information Storage Research Center
,
Shanghai Jiaotong University
,
Shanghai 200030
,
China
,
College of Chemical Engineering & Technology
,
Taiyuan University of Technology
,
Taiyuan 030024
,
China)
金属学报(英文版)
Titanium dioxide thin films were prepared by low pressure metal organic chemical vapor deposition (LP-MOCVD) from titanium IV isopropoxide. Nitrogen was used as a carrier gas for the titanium precursor,and oxygen as a reactant gas. The deposition rates of the films have been studied as functions of process parameters such as sabstrate temperature and oxygen flow rote. Structural evolution of the films has been studied as functions of substrate temperature (110 to 700℃) and annealing temperature. The films have been characterized by X-ray dissection and by Raman scattering. Films deposited onto Si(100) substrates were amorphous at 110-250℃, anatase at 350- 550℃ and rutile above 650℃. The films deposited at substrate temperatures less than 550℃ and annealed at 600℃ for two hours were annealed, annealed at 700℃ for two hours were mixtures of anatase and rutile, and annealed at 850℃ for two hours were rutile.
关键词:
MOCVD
,
null
,
null
,
null
,
null
JIN Man
,
JIANG Zhonghao
,
NAN Shenghui
,
HU Jiandong
,
LIAN jianshe(Jilin University of Technology
,
Changchun
,
China)(Manuscript received 8 February 1995)Correspondent:LI Geping
,
(Institute of Metal Research
,
Chinese Academy of Sciences
,
Shenyang 110015
,
China)
金属学报(英文版)
The low carbon dual phase structure was cold de formed first,then was tempered at 200 to 600℃.The variation in strength and ductility during tempering of the steel was investigated.It was found that a fter the de formed dual phase structure was tempered at 200 to 600℃, with the increase in the tempering temperature the tensile strength decreases rapidly;the lotal elongation remains constant at 200 to 500℃ but began to rise dramatically at a critical temperature between 500 and 600℃.However,when the non-deformed dual phase structure was tempered at the same temperature range,the tensile strength decreases and the total elongation increases continuously with the increase of temperature.It was demonstrated from TEM analysis that precipitating carbides density along the boundaries ofmartensite lath and the recrystallized grains are responsible for the tempering response ofthe de formed dual phase structure.
关键词:
:de formed dual phase structure
,
null
,
null
L. P. Xu
,
M. H. Xu
,
L. Li
,
Y.A. Min
,
X.Z Xuand R.H .Liu (Department of Materials Science and Engineering
,
Shanghai University
,
Shanghai 200072
,
China) (Shanghai No.5 Iron and Steel Factory
,
Shanghai 200940
,
China)
金属学报(英文版)
The composition of a bearing steel was designed for limited hardenability by use of Grossmann's method. A medium frequency induction Process was applied to heat bearings to ensure penetrant heating and suitable solving of carbon and other elements in the matrix. The hardened depth measured from the end quenching test samples and actual bearings matches well with the designed one.
关键词:
: bearing steel
,
null
,
null
SUN Baode
,
CHE Xiaozhou
,
LIN Dongliang
,
ZHOU Yaohe(Department of Materials Engineering
,
Shanghai Jiaotong University
,
Shanghai 20030
,
China)(Department of Materials Science
,
Shanghai Jiaotong University
,
Shanghai 200030
,
China)
金属学报(英文版)
The morphology and structure of melt spinning Ni-33.6at% Al doped with B and RE were investigated.The results show that the alloy consists of L10 martensitic grains and L12 Ni3Al at the grain boundaries when it contains no B and RE.The addition of 0.11-0.31wt% B can suppress the martensitic transformation and Ni3Al separation at the boundaries,and a supersaturated B2 single phase NiAl is obtained.The addition of 0.05wt% RE can eliminate Ni3Al precipitated at the boundaries and get complete martensite,but 0.2-0.8wt% RE addition can suppress the martensitic transformation, and supersaturated B2 single phase NiAl is obtained.The formation mechanism of supersaturated B2 single phase NiAl has been analyzed.
关键词:
:NiAl
,
null
,
null
,
null
R.Shi
,
G.X.Hu
,
H.J.Li and M.K.Kang (The State Education Commission Open Research Laboratory for High Temperature Materials and Testing
,
Shanghai Jiao Tong University
,
Shanghai 200030
,
China)(Department of Materials Science and Engineering
,
Northwestern Polytechnical University
,
Xi'an 710072
,
China)
金属学报(英文版)
The steady-state creep behavior of unidirectional C/C(1-D-C/C) composite with pyrolytic carbon matrix was investigated at high temperatures up to 2160℃ and under tensile stress from 133.83 to 213.46MPa. Based on the creep experiment of single specimen method, the apparent activation energy and the stress exponent for steadystate creep were determined by the use of a self-made apparatus and an auto-testing system. Value of apparent activation volume is provided and the creep mechanism has also been discussed.
关键词:
1-D-C/C
,
null
,
null
G. Ya
,
X.Y Zhang and Y. L. Du(State Key Laboratory for Corrosion and Protection
,
Institute of Corrosion and Protection of Metals
,
The Chinese Academy of Sciences
,
Shenyang 110015
,
China)(Applied Chemistry Division of Sciences Institute
,
Shenyang Polytechnic University
,
Shenyang 110023
,
China)
金属学报(英文版)
It was proposed how the concentration distribution was calculated in the treble lager wall of hgdrogenation reactor according to the principle of hydrogen diffusion at the steady state in this paper. Based on the steady hydrogen permeation current density i∞ measund with the hydrogen probe at a given temperature, the hydmpen concentrationson the key interfaces and hydrogen distribution at any given mdial profile in the single, double or treble layer wall of hydrogenation reactor could be found by applying the presented equations throoph suitable parmeters ioput. The theoretical bases were provided for developing the nondestructive probing technique of the concentration of atomic hydmpen in the wallS of hydrogenation reactors.
关键词:
hydrogen permeation
,
null
,
null
ZHANG Yue
,
CHU Wuyang
,
XIAO Jimei(Department of Materials Physics
,
University of Science and Technology Beijing
,
Beijing 100083
,
China) OUYANG Shixi
,
YUAN Runzhang(State Key Laboratory for Synthesis and Processing of Advanced Materials.Wuhan University of Technology
,
Wuhan 430070
,
China)
金属学报(英文版)
For alloy Ti-24Al-11Nb,stress corrosion cracking(SCC) in methanol solution and hydrogen induced cracking(HIC) during dynamic charging at room temperature have been studied.Experiment has shown that the normalised threshold stress intensities of SCC failure for various microstructures are KISCC/KC =0.53 0.69 and the threshold value for SCC arresting KISCC/ KIC=0.61-0.79.The threshold values of HIC during dynamic charging are close to that of SCC,but da/dt or fracture time of HIC is one to three orders of magnitude smaller or longer than that of SCC,respectively.The.fracture surface for HIC is also different from that for SCC.For the Ti-24Al-Nb alloy-methanol systein,a kind of inierphase SCC has been found For the microstructures resulting from furnace cooling,SCC initiated and propagated preferentially along theα2/βinterphase boundaries,displaying the microstructure on the fracture surface of SCC.However,there is no interphase SCC for the microstructure resulting from air cooling.
关键词:
:Ti-24Al-11Nb
,
null
,
null
,
null
