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乌洛托品与碘化镧配合物的合成、表征及抗菌活性研究

彭鹏 , 刘斌 , 王丽 , 张晨鼎

稀土 doi:10.3969/j.issn.1004-0277.2002.06.003

报道了配合物LaI3*C6H12N4*HI*13H2O的新的合成方法,通过元素分析、X射线粉末衍射、红外光谱、核磁共振谱、质谱、差热椚戎胤治?确定了配合物的组成和结构,首次测定了配体和配合物的抗菌活性.

关键词: 碘化镧 , 乌洛托品 , 配合物 , 抗菌活性

镧(Ⅲ)与硫脲配合物的合成、表征及抗菌活性研究

彭鹏 , 刘斌 , 王丽 , 张晨鼎

稀土 doi:10.3969/j.issn.1004-0277.2002.03.010

本文报道了配合物LaI3·2CS(NH2)2·10H2O的新的合成方法,通过元素分析、X射线粉末衍射、红外光谱、核磁共振谱、质谱、差热-热重分析,确定了配合物的组成和结构,首次测定了配体和配合物的抗菌活性.

关键词: 碘化镧 , 硫脲 , 配合物 , 抗菌活性

ION HEATING PROCESS DURING PLASMA IMMERSION ION IMPLANTATION

X.B. Tian , X.F. Wang , A.G. Liu , L.P. Wang , S. Y. Wang , B. Y. Tang and P. K. Chu 1)Advanced Welding Production & Technology National Key Laboratory , Harbin Institute of Technology , Harbin 150001 , China 2)Department of Physics & Materials Science , City University of Hong Kong , China

金属学报(英文版)

The research on plasma immersion ion implantation has been conducted for a little over ten years. Much is needed to investigate including processing technlogy, plasma sheath dynamics, interaction of plasma and surface, etc. Of the processing methods elavated temperature technique is usually used in PIII to produce a thick modified layer by means of the thermal diffusion. Meanwhile plasma ion heating is more recently developed by Ronghua Wei et al[1]. Therefore the temeperature is a critical parameter in plasma ion processing. In this paper we present the theoretical model and analysize the effect of imlantation voltage, plasma density, ion mass,etc on the temperature rise.

关键词: plasma immersion ion implantation , null , null

介观LC电路在时变电源作用下量子态的演化

夏小建

量子电子学报 doi:10.3969/j.issn.1007-5461.2009.06.010

采用Wei-Norman方法,求出含时变电压源的介观LC电路随时间演化的精确解,应用相空间准概率分布函数,研究了时变电源作用下介观LC电路相干态的量子特性,结果表明此函数是一个二维运动的Gauss波包,其中心电量和磁通呈余弦和正弦变化.

关键词: 量子光学 , LC回路 , 介观电路 , 相干态 , 量子态演化 , 相空间的准概率分布函数

Oxidation of Alloying Elements during ESR of Stainless Steel

WEI Jihe Xi'an Institute of Metallurgy and Construction Engineering , China.

材料科学技术(英文)

The oxidation of alloying elements during the ESR of stainless steel has been studied. The model previously developed by WEI and Mitchell for the chemical reactions and mass transfer processes during ESR was applied to the remelting of the high Cr steel 1Cr18Ni9(Ti).The laboratory data for the unsteady state A.C.ESR were analyzed and dealt with by the model.When the remelting process reached a steady state,an oxidant(Fe_2O_3 powder)or a deoxidant(Ca-Si powder or metallic Ca)was added to the slag bath.The results showed that this model is applicable to the remelting of stainless steel rather precisely, and it is expected that the model may offer a reliable basis for the control of composition during practical ESR of high alloy steel. Also,the oxidation of Cr in the steel must be noticed when its content is high;but it is entirely possible to adjust the Cr content of ingot within a considerable range,using a special technique by means of the slag-metal reactions during the remelting.

关键词: ESR , null , null , null , null

LaBr3晶体本征点缺陷研究

姜威 , 刘廷禹 , 孙颖 , 孙羽

人工晶体学报

基于密度泛函理论平面波赝势法对LaBr3晶体本征点缺陷进行了系统研究.通过第一性原理和热动力学方法,计算得到了不同温度及溴分压下LaBr3晶体中本征点缺陷的缺陷形成能,并讨论了不同环境条件下本征点缺陷的形成能随费米能级的变化关系.计算结果表明,当费米能级位于导带底附近时,LaBr3晶体中的主要点缺陷为Lai…能级位于价带顶附近时,LaBr3晶体中主要的点缺陷为Vlao…VBr在高温/低溴分压相对稳定,Vla在低温/高溴分压更稳定.本文还做出了最稳定点缺陷随温度、溴分压及费米能级变化的三维空间分布图,清晰地呈现了不同条件下,该晶体最可能出现的点缺陷类型,从而为调控晶体的点缺陷改善晶体光学性能提供参考.

关键词: LaBr3晶体 , 密度泛函理论 , 点缺陷 , 热力学

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