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Studies of the anion position parameter chi of the ternary semiconductor CuGaS2 by use of Ni+ ion probe

Materials Science and Engineering B-Solid State Materials for Advanced Technology

The anion position parameter chi of NiS4 cluster formed in the ternary semiconductor CuGaS2 by substitution of Ni+ for Cu+ has been determined by studying the optical spectra and EPR data for CuGaS2:Ni+. The result (chi approximate to 0.263(1)) is consistent with the mean value of the X-ray measurement results reported in two groups of references and also with the calculated value obtained from the conservation of tetrahedral bonds (CTB) plus eta = eta(tet) rule (where eta = c/2a). So, we suggest that the anion position parameter chi in pure CuGaS2 crystal is close to the above value obtained by use of Ni+ ion probe. The optical absorption bands and g factors g(parallel to), g(perpendicular to), of CuGaS2: Ni+ are therefore explained reasonably from the anion position parameter. (C) 2003 Elsevier B.V. All rights reserved.

关键词: structural parameter;electron paramagnetic resonance (EPR);optical;spectrum crystal-field theory;CuGaS2;Ni+;chalcopyrite semiconductors;superposition model;crystal

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

Broer-Kaup-Kupershmidt方程的新精确解

杨立娟 , 杨琼芬 , 杜先云

量子电子学报 doi:10.3969/j.issn.1007-5461.2012.02.003

CK方法是求解非线性发展方程的一种有效的直接方法.利用推广的CK方法,求得(2+1)维Broer-Kaup-Kupershmidt方程的Backlund公式,从而获得方程的大量新的精确解,推广了Xu和Zhang的结果.

关键词: 非线性发展方程 , Broer-Kaup-Kupershmidt方程 , 精确解 , CK方法 , Backlund变换

Influences of variations of characteristic parameters of protein molecules on states of soliton transported bio-energy

International Journal of Modern Physics B

We simulate numerically the dynamic properties of new soliton with quasi-coherent two quanta in the improved model by fourth-order Runge-Kutta way. We observed that the window of formation of new soliton is shifted toward smaller values of coupling constants when compared with the Davydov's soliton with one quantum and Forner's soliton with two quantum model. The new soliton formation starts at (chi 1 + chi 2) = 20 PN, and pinning starts from (chi 1 + chi 2) = 86 PN. The pinned solitons are also observed if both quanta are on the same end of the chain in the initial state. The behaviors of new soliton are varied under influences for variations of characteristic parameters arising from the structure nonuniformity of protein molecules. Although the new soliton is also sensitive to the dipole-dipole interaction and diagonal disorder, the sensitivity to the impurity is weaker than that of the Davydov's and Forner's solitons. Therefore, the new soliton is robust against the fluctuations of coupled constant, dipole-dipole interaction and diagonal disorder arising from the impurity or structure nonuniformity, when compared with that of the Davydov's and Forner's solitons.

关键词: protein;bio-energy transport;soliton;structure nonuniformity;characteristic parameter;davydov soliton;living systems;improved model;thermodynamic;properties;biological temperature;finite-temperature;quantum;dynamics;disorder;lifetime

Three-dimensional (3D) Ising universality in magnets and critical indices at fluid-fluid phase transition

Phase Transitions

Experimental data for critical exponents in some magnetic materials are compared with recent theoretical results on the three-dimensional (3D) Ising model, as derived by one of us (ZDZ) based on two conjectures [Z.D. Zhang, Conjectures on the exact solution of three-dimensional (3D) simple orthorhombic Ising lattices, Phil. Mag. 87 (2007), pp. 5309-5419]. It is found that critical exponents in some bulk magnetic materials indeed form a 3D Ising universality. Our attention is then focused on the critical indices at fluid-fluid phase transition. We suggest to use Zhang's exponent = 3/8 to fit the experimental data over the wider asymptotic region near the critical point of a fluid-fluid phase transition. The 3D Ising universality should exist for critical indices in a certain class of magnets and at fluid-fluid phase transition.

关键词: magnetically ordered materials;fluid-fluid;phase transitions;order-disorder effects;ferromagnetic curie temperature;liquid critical phenomena;x-ray-scattering;critical exponents;critical-point;coexistence;curves;binary-solutions;ionic-solutions;behavior;equation

Response to the Comment on 'Conjectures on exact solution of three-dimensional (3D) simple orthorhombic Ising lattices'

Philosophical Magazine

The error of Equation (15b) in my article [Z.D. Zhang, Phil. Mag. 87 (2007) p.5309] in the application of the Jordan-Wigner transformation does not affect the validity of the putative exact solution, since the solution is not derived directly from that equation. Other objections of Perk's comment [J.H.H. Perk, Phil. Mag. 89 (2009) p.761] are the same as those in Wu et al.'s comments [F.Y. Wu et al., Phil. Mag. 88 (2008) p.3093; p.3103], which do not stand on solid ground and which I have sought to refute in my previous response [Z.D. Zhang, Phil. Mag. 88 (2008) p.3097]. The conjectured solution can be utilized to understand critical phenomena in various systems, whereas the conjectures are open to rigorous proof.

关键词: 3D Ising model;exact solution;conjecture;critical phenomena;ferromagnetism;magnetic phase transition;model;analyticity

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