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Studies of the anion position parameter chi of the ternary semiconductor CuGaS2 by use of Ni+ ion probe

Materials Science and Engineering B-Solid State Materials for Advanced Technology

The anion position parameter chi of NiS4 cluster formed in the ternary semiconductor CuGaS2 by substitution of Ni+ for Cu+ has been determined by studying the optical spectra and EPR data for CuGaS2:Ni+. The result (chi approximate to 0.263(1)) is consistent with the mean value of the X-ray measurement results reported in two groups of references and also with the calculated value obtained from the conservation of tetrahedral bonds (CTB) plus eta = eta(tet) rule (where eta = c/2a). So, we suggest that the anion position parameter chi in pure CuGaS2 crystal is close to the above value obtained by use of Ni+ ion probe. The optical absorption bands and g factors g(parallel to), g(perpendicular to), of CuGaS2: Ni+ are therefore explained reasonably from the anion position parameter. (C) 2003 Elsevier B.V. All rights reserved.

关键词: structural parameter;electron paramagnetic resonance (EPR);optical;spectrum crystal-field theory;CuGaS2;Ni+;chalcopyrite semiconductors;superposition model;crystal

Longitudinal magnetotransport in long-period semiconductor superlattices

Physical Review B

Longitudinal electron transport is investigated for a long-period semiconductor superlattice in the presence of a magnetic field applied along the growth direction of the superlattice. It is shown that the longitudinal magnetoresistance exhibits a complicated dependence on the magnetic-field strength. In contrast with the conventional Shubnikov-de Haas oscillations, the magnetoresistance shows periodic oscillations only in the region of low reciprocal magnetic field.

关键词: magnetoresistance

LONG-TERM CREEP AND RUPTURE PROPERTIES OF HEAT RESISTING STEELS AND ALLOYS

K.Yagi and F.Abe (National Research Institute for Metals , 1-2-1 Sengen , Tsukuba 305-0047 , Japan)

金属学报(英文版)

The present status of NRIM Creep Data Sheet Project and the recent activities of long-term creep and rupture studies on heat resisting steels are described. The project has been continued to produce long-term data such as 100 000h-creep rupture strength for 47 kinds of principal heat resisting steels and alloys, including welded joints. The long-term creep deformation behavior and microstructural evolution during creep have been shown to be complicated.

关键词: heat resisting steel and alloy , null , null

Twinning in Intermetallic Compounds Are Long Shear Vectors and/or Shuffles Really Necessary?

F.M.Chu David P.Pope Dept.of Materials Science and Engineering , University of Pennsylvania , Philadelphia , PA 19104 , USA

材料科学技术(英文)

In this paper the geometric description and general theory of mechanical twinning are reviewed, the twins in general lattices and superlattices are summarized, and the kinetic process by which mechanical twins form is revisited. A case study of mechanical twinning of HfV2+Nb, (cubic) Laves phase, is presented and the synchroshear of selected atomic layers is proposed to explain the physical process of twin formation. If the twins form in this way, then long shear vectors and / or atomicshuffles are not really necessary.

关键词: twin , null , null , null

A NEW METHOD FOR MEASURING LONG-TERM CREEP DEFORMATION IN A SMALL REGION

J.M. Gong , S.T. Tu , J. Xia and X. Ling (School of Mechanical Engineering , Nanjing University of Chemical Technology , Nanjing 210009 , China)

金属学报(英文版)

Creep deformation localization is generally found in structures at high temperamture,typically in weldments. As the heat affected zone (HAZ) in a weldment is very narrow, deformation in HAZ region can hardly be measured by conventional displacement gauge. A new method for measuring long-term local creep deformation was developed by quartz optical fiber and technique of digital image analysis. The creep deformations of base metal, weld metal and HAZ in weldments are thereby determined with crossweld specimens.

关键词: creep deformation , null , null , null

Long periodic structure in ZrO2-Y2O3 ceramics

材料科学技术(英文)

A new type of long periodic structure has been found in ZrO2-Y2O3 ceramics in annealed states. High resolution electron microscopy (HREM), selected area electron diffraction, and computer simulation have been used to reveal the presence of the long periodic structure. The unit cell of the long periodic structure consists of a cubic ZrO2 unit cell and L1(0)- like phase one.

关键词: ceramics;electron diffraction;electron microscopy;crystal structure;microstructure

Long Periodic Structure in ZrO2-Y2O3 Ceramics

Jiancun RAO , Yu ZHOU , Douxing LI

材料科学技术(英文)

A new type of long periodic structure has been found in ZrO2-Y2O3 ceramics in annealed states. High resolution electron microscopy (HREM), selected area electron diffraction, and computer simulation have been used to reveal the presence of the long periodic structure. The unit cell of the long periodic structure consists of a cubic ZrO2 unit cell and L10- like phase one.

关键词: Ceramics , null , null , null , null

Role of long-range elastic energy in relaxor ferroelectrics

Applied Physics Letters

The dipole configuration of relaxor ferroelectrics (RFs) is investigated by numerically solving the time-dependent Ginzburg-Landau equation based on the dipole defect model. The domain structure of RFs is revealed to consist of dipole ordered clusters embedded in the paraelectric matrix. We demonstrate that the role of long-range elastic energy in RFs is much less important than in normal ferroelectrics, although the shape of the dipole clusters depends on the elastic energy. Based on the numerical results, a phase diagram of temperature-defect density for RFs is constructed, which identifies four distinct phase regimes. (c) 2006 American Institute of Physics.

关键词: monte-carlo-simulation;dielectric-properties;computer-simulation;domain formation;defects;field;model;glass

LONG-TIME-CORRELATION EFFECTS AND BIASED ANOMALOUS DIFFUSION

Physical Review A

This paper investigates the motion of a Brownian particle experiencing both a friction (biased) force and a randomly fluctuating force with a long-time-correlation function C(f)(t) approximately t(-B), 0 < beta < 1, 1 < beta < 2, and beta = 1, instead of a Dirac delta-function. The generalized Langevin equation and Fokker-Planck equation and corresponding solution are presented. It is shown that when 0 < beta < 1 or 1 < beta < 2, the diffusion motion of the Brownian particle is the anomalous diffusion that is related to fractal Brownian motion (FBM). But when beta = 1 the diffusion motion is anomalous diffusion with no connection to FBM. The effects of friction retardation result in a probability density function for finding the particle at displacement X at time t that depends on the initial value of velocity of the particle. The approach in this paper may provide a systematic method for the study of particles diffusing in fractal media.

关键词: disordered media;brownian-motion

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