C.C. Chang C.P. Chou S.N. Hsu G.Y. Hsiung J.R. Chen
材料科学技术（英）
This study discusses the welding properties for the components of an aluminum-alloy ultra-high vacuum chamber and beam position monitor (BPM). The welding parameters include the modes of laser output (pulsed wave and continuous wave), welding speed, shield gas flow, welding bead structure, and focusing distance. The results showed that the welding defect rate of the pulsed wave type was larger than that of the continuous wave type. The crack in the welding bead reduced with decreasing welding speed. The fusion penetration of the welding bead was higher when the focusing distance was long enough to deepen into the welding material. Weld morphology during the experimental process revealed the proper flow of shield gas.The adaptability design of the welding bead structure in the preceding processes had more effect on overall welding structure and morphology.
关键词:
Laser welding
XU Zuyao(T.Y.Hsu) PAN Mu Shanghai Jiaotong University
,
Shanghai
,
China Correspondent:XU Zuyao(T.Y.Hsu) Professor
,
Department of Materials Science
,
Shanghai Jiaotong University
,
Shanghai
,
China
金属学报(英文版)
A Central Atom Model is introduced and the LFG and Hsu models are modified in order to evaluate the driving force for the martensitic transformation in Fe-Mn-C and Fe-Ni-C al- loys.The results show that the relationship between the driving force and the yield strength of austenite at Ms temperature,σ_(0.2)~γ/M_s,fits Hsu's formula;ΔG~=2.1σ_(0.2)~γ/M_s+907 J/mol.The M_s temperatures of Fe-Mn-C and Fe-Ni-C alloys are also calculated.The calculated results are in good agreement with experimental values.
关键词:
Fe-Mn-C alloy
,
null
,
null
Journal of Applied Physics
The magnetic properties of R2Co14B1-xCx (x=0, 0.5 and R=Y, Sm) compounds have been studied by measuring the temperature dependence of the easy- and hard-magnetization curves on magnetically aligned samples between 1.5 and 300 K for Y2Co14(B,C) and at 4.2 K for Sm2Co14(B,C). The magnetic anisotropy of Y2Co14B increases due to the substitution of C for B, whereas the saturation magnetization decreases. Between 1.5 and 300 K, the anisotropy field of Y2Co14B0.5C0.5 increases about 2 T and the Co moment decreases about 0.05mu(B). The anisotropy field Of Sm2Co14B also increases upon C substitution and the saturation magnetization decreases slightly. The ac susceptibilities of both SM2Co14B and Sm2Co14B0.5C0.5 exhibit anomalies that may arise from a spin reorientation within the basal plane.
关键词:
nd2fe14b;exchange;nd2co14b;r2fe14b;field
杭祖圣
,
谈玲华
,
黄玉安
,
应三九
,
徐复铭
功能材料
在半封闭系统中采用直接热解三聚氰胺的方法制备了C3N4,XRD、XPS及元素分析的结果证明了产物是类石墨相C3N4(g-C3N4).用热分析(TG/DTG)研究了g-C3N4的热分解过程.通过迭代法计算了热分解反应活化能Ea,采用积分法结合36种动力学函数来判断g-C3N4热分解的机理函数.计算结果表明,g-C3N4的平均热分解活化能Ea为178.59kJ/mol,可能的动力学函数积分形式是g(a)=[-In(1-a)]4,指前因子A为21.67s-1,对应的热分解动力学方程为:dα/dT=(21.67/β)exp(-178.59×103/RT)×1/4(1-α)[-ln(1-α]-3
关键词:
非等温热重法
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g-G3N4
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热分解动力学
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迭代法
Xifeng Lu Qilong Wang Deliang Cui
材料科学技术（英）
g-C3N4/TiO2 composite were prepared by hydrolysis of Ti(OC4Hn 9 )4 and the precursors of g-C3N4 at room temperature and annealing in nitrogen atmosphere. X-ray diffraction results revealed that all the products were anatase structure. The chemical nature of O, N of the g-C3N4/TiO2 were identified by X-ray photoelectron spectroscopy, presenting N-Ti-O and N-Ti-N doping status of the composite. The g-C3N4/TiO2 composite showed better photocatalytic activity for the UV and visible-light degradation of Rhodamine B.
关键词:
Composite materials
,
Chemical synthesis
,
X-ray photoelectron spectroscopy (XPS)
楚增勇
,
原博
,
颜廷楠
无机材料学报
doi:10.15541/jim20130633
利用光催化剂将太阳能转化为人类可以直接利用的能量，并用其解决地球资源的枯竭和生存环境的恶化是可再生清洁能源研究的一个方向。g-C3N4的独特结构赋予其良好的光催化性能，使之成为光催化领域的研究热点。目前在光催化领域， g-C3N4主要用于催化污染物分解、水解制氢制氧、有机合成及氧气还原。在实际应用中，为进一步提高 g-C3N4的光催化效果，科研工作者开发了多种改进方法，例如物理复合改性、化学掺杂改性、微观结构调整等。本文主要论述了 g-C3N4在光催化领域的应用以及光催化性能的改进方法，简要阐述了光催化和各种改进方法的机理，分析了目前g-C3N4在光催化领域面临的问题和挑战，展望了g-C3N4的应用前景。
关键词:
g-C3N4
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光催化
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改进方法
,
综述
郑小刚
,
杜京城
,
李子黎
,
付孝锦
,
由耀辉
,
刘勇
人工晶体学报
采用浸渍法制备不同掺杂量的负载型光催化剂Ni/g-C3N4,并考察其在可见光照下对亚甲基蓝的光降解性能.利用XRD、FT-IR、SEM、TEM、XPS、N2-sorption和ICP-OES等手段表征Ni/g-C3N4样品.研究表明,Ni/g-C3N4催化剂的光催化活性随着金属镍粒子掺杂量的增加而增大,随着亚甲基蓝浓度的增大而减小,其中金属镍掺杂量4.0wt%的样品4-Ni/g-C3N4表现出优异的光催化活性和光降解稳定性.这是由于4-Ni/g-C3N4样品的光降解过程中产生了超氧自由基、羟基自由基和空穴等活性物质,其中超氧自由基起主导作用.金属Ni0离子在光生电子作用下生成Ni2+,O2分子得到电子生成O2·-自由基.这些活性物质的产生有助于光生电子-空穴对的分离和抑制其复合速率,从而实现可见光下高效催化降解亚甲基蓝.
关键词:
Ni/g-C3N4
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掺杂效应
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亚甲基蓝
,
光降解性能
赵芳霞
,
张振忠
,
丘泰
,
施兵兵
机械工程材料
doi:10.3969/j.issn.1000-3738.2005.03.019
研究了高碳钢表面Ni-P/纳米Ti(C,N)化学复合镀工艺以及热处理对复合镀层性能的影响.结果表明:施镀工艺中各因素对镀速影响的显著性顺序是pH值＞镍磷比＞施镀温度＞纳米Ti(C,N)加入量;较好的施镀工艺为硫酸镍为25 g/L、次亚磷酸钠为29.9 g/L、乳酸为34 g/L、乙酸钠为4 g/L、PbCl2为0.001 g/L、Ti(C,N)为6 g/L、pH值为4、施镀温度为80℃;复合镀层较佳的热处理工艺为400℃保温45 min,空冷.在最佳工艺下,得到的Ni-P/纳米Ti(C,N)复合镀层的硬度为975.2 HV,是高碳钢基体硬度的3.8倍,且镀层与基体的结合力强.
关键词:
高碳钢
,
纳米Ti(C,N)
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化学复合镀
,
施镀工艺
