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Novel magnetorheological suspensions based on Co-phthalocyanine/Fe nanocomposite particles

Rongzhou GONG , Zekun FENG , Jianguo GUAN , Runzhang YUAN

材料科学技术(英文)

A novel magnetorheological (MR) suspension was based on methyl silicone oil and cobalt-phthalocyanine (Co-Pc)/Fe nanocomposite particles, which were synthesized by thermally decomposing liquid carbonyl Fe in the solution of Co-Pc in N, N-dimethyl formamide. The nanocomposite particles were fully characterized by XRD, SEM and HREM, and the thermal, magnetic and MR properties of nanocomposite particles were measured. Such factors as weight percent of particles (w), magnetic field strength (H), temperature (T) and shear rate (gamma) etc influencing on MR properties were investigated. The results indicated that Co-Pc/Fe nanocomposite with density of 3.66 g/cm(3) was almost micro-sized regular spheroids consisting of tens of Co-Pc coated alpha -Fe nanoparticles in inner and Co-Pc layers on surface of the spheroids. They showed good characteristics of anti-oxidation and soft magnetic. Increment of w increased field-induced shear stress (Delta tau) and zero-field viscosity (eta (0)) of MR suspensions monotonously, and improved anti-settlement stability, but eta (0) increased more markedly than Delta tau with increasing w. Delta tau was basically independent on T and gamma while increased obviously with increasing H. With increasing T, response time of the MR suspension to external magnetic field seemed to decrease. As a result, MR suspensions with satisfactory stability and rapid, completely reversible and significant MR effect can be obtained from Co-Pc/Fe nanocomposite particles.

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Structural and Magnetic Studies of CTAC-assisted NiZn Ferrite Films within 0.1–3.5 GHz

Xiang SHEN , Rongzhou GONG , Zekun FENG , Huahui HE

材料科学技术(英文)

Spinel NiZn ferrite thin films were prepared on glass substrates by spray plating method. Adding cetyltrimethylammoniumchloride (CTAC), adsorptive energy of substrate surface increased, and smooth surface and uniform columnar film structures were observed. The optimum reaction temperature up to 85℃ and pH up to 7.5 were obtained. As the solution pH value increases from 6.5 to 7.5, the film saturation magnetization increases to 2.48×105 A/m and electric resistivity to 5.6×102 mΩ•cm. The high real part of complex permeability μ′ up to 36.1 and the imaginary part μ′′ up to 53.2 for NiZn ferrite film at 500 MHz were achieved, and higher magnetic resonance at 508 MHz was observed. As the ferrite plate thickness is 50 μm, the attenuating characteristics for reflection loss ≤-0.8 dB can be obtained in the wide frequency ranging from 0.5 to 2.7 GHz. The μ′′ of thin film has values higher than 20 at the frequencies between 0.5 and 2 GHz, and the thin film can be applied as shielding material in GHz range.

关键词: NiZn ferrite films , Spray

提高本钢265 m2冷烧结矿及原料检验代表性的实践

李凤娟 , 吕国光

金属世界 doi:10.3969/j.issn.1000-6826.2014.04.14

通过对烧结配料所需原料及对冷烧结矿成品检验采制样方法的分析,找出影响检验结果真实性的因素,采取有效的改进措施,使本钢原料厂一次配料、本钢炼铁厂265 m2烧结二次配料及265 m2烧结系统各项稳定率有了很大的提高,烧结矿实物质量和各项技术质量指标有了很大的进步,保证了高炉的稳定顺行。
  提高本钢265 m2冷烧结矿及原料检验代表性的实践
  Practice of Improving the 265 m2 Cold Sinter and Raw Material Inspection Representative
  供稿|
  李凤娟,吕国光/
  LI Feng-juan, LV Guo-guang
  DOI:10.3969/j.issn.1000-6826.2014.04.14
  导读内容
  本钢炼铁厂265 m2烧结机生产所需要的含铁原料比较复杂,一次配料料种较多,且烧结含铁原料是由本钢原料厂二车间供料,原料质量的不稳定,会影响烧结矿质量的提高和新一号高炉的强化及高炉技术指标的改善。本钢质量管理中心驻冷烧检查站加强了对烧结配料所需原料及对冷烧结矿成品检验采制样代表性的研究,采取了一些改进措施,达到了良好的效果。含铁料成分稳定率、烧结矿各项质量和技术指标在稳步地提高。下面,对本钢质量管理中心驻冷烧检查站就提高采样及检验过程的准确性所采取的措施和办法进行说明。
  烧结矿采样是半自动采样,每两小时采样一次,作为一个批次,来代表整个2h烧结矿的成份。

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