材料期刊网

A STUDY OF ELECTROCHEMICAL BEHAVIOUR OF VARIOUS THERMAL HISTORY ZONES AND DIFFERENT PHASE STRUCTURES ON THE WELDMENT FOR LOW ALLOY STEEL 16Mn IN NITRAfE SOLUTION

Y.S.Wu , D.Y. Liu , B. Cao , F. L. Wang , X.Y. Wang , Z.Fang and Z.G.Du (Department of Surface Science and Corrosion Engineering , University of Science and Technology Beijing , Beijing 100083 , China)

金属学报(英文版)

The electrochemical behaviour, including free corrosion potential, free corrosion current density and polarization curve, of various thermal history zones on the weldment was measured in this paper. The weldment consisted of matrix, tempering zone. incomplete normalized zone, normalized zone, overtemperature zone, fusion line zone and weld metal zone. The electrochemical behaviour of the ferrite, pearlite and mixed structure in various zones have successfully measured. The results showed that there was a difference of free corrosion potential which is smaller than ca. 200mV between various zones and about 20-150mV potential difference between ferrite and pearlite in every zone. The free cormsion potential of fusion line zone was the most negative between various zones. The free corrosion potential of pearlite was some dozens mV more negative than ferrite. The corrosion course of various zones and of different phase structures on the weldment and their effect on corrosion attack of weldment were discussed.

关键词: weldment , null , null , null

CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,University of Science and Technology Beijing,Beijing 100083,China

QIAO Lijie LIU Rui XIAO Jimei University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词: stress corrosion cracking , null , null , null

奇Z超重核的禁戒α衰变

许昌 , 任中洲

原子核物理评论 doi:10.11804/NuclPhysRev.30.03.308

采用密度依赖的结团模型研究了奇Z超重核的禁戒α衰变,α粒子与子核之间的微观核势通过双折叠模型对M3Y核子-核子相互作用势以及α粒子与子核的密度积分给出.α粒子与子核之间的库仑相互作用也通过α粒子与子核的电荷密度积分给出.计算发现,由于非零角动量带来的禁戒效应和小的α粒子预形成几率,奇Z超重核的α衰变寿命会明显变长.

关键词: α衰变 , 超重核 , 结团模型

Z型复合催化剂g-C3N4/Vo-ZnO光催化活性的研究

刘亚男 , 王瑞霞 , 杨正坤 , 杜虹 , 姜一帆 , 申丛丛 , 梁况 , 徐安武

催化学报 doi:10.1016/S1872-2067(15)60985-8

随着科学技术的不断进步和经济的快速发展,人类对自然资源的需求量越来越大,在开发利用自然资源的同时,大量的有机污染物也随之进入自然环境.这些物质不仅污染环境、破坏生态,更对人类的生活和健康带来了巨大的威胁.研究证实,半导体光催化剂在光照条件下可以破坏有机污染物的分子结构,最终将其氧化降解成CO2、H2O或其它不会对环境产生二次污染的小分子,从而净化水质.近年来,有关光催化降解有机污染物的报道日益增多. ZnO作为一种广泛研究的光催化降解材料,因其无毒、低成本和高效等特点而具有一定的应用前景.但是ZnO较大的禁带宽度(3.24 eV)导致其只能吸收紫外光部分,而对可见光的吸收效率很小,极大地制约了其实际应用.除此之外, ZnO受光激发产生的电子-空穴分离效率较低、光催化过程中的光腐蚀严重也是制约其实际应用的重要因素.为了提高ZnO的光催化活性和稳定性,本文合成了用g-C3N4修饰的氧空位型ZnO(g-C3N4/Vo-ZnO)复合催化剂,在有效调控ZnO半导体能带结构的同时,通过负载一定量的g-C3N4以降低光生电子-空穴对的复合速率和反应过程中ZnO的光腐蚀,增强催化剂的光催化活性和稳定性.本文首先合成前驱体Zn(OH)F,然后焙烧三聚氰胺和Zn(OH)F的混合物得到g-C3N4/Vo-ZnO复合催化剂,并采用电子顺磁共振波谱(EPR)、紫外-可见光谱(UV-vis)、高分辨透射电镜(HRTEM)和傅里叶变换红外光谱(FT-IR)等表征了它们的结构及其性质. EPR结果表明,ZnO焙烧后具有一定浓度的氧空位,导致其禁带宽度由3.24 eV降至3.09 eV,因而提高了ZnO对可见光的吸收效率. UV-vis结果显示, Vo-ZnO复合g-C3N4后对可见光的吸收显著增强. HRTEM和FT-IR结果均表明, g-C3N4纳米片和Vo-ZnO颗粒之间通过共价键形成了强耦合,这对g-C3N4/Vo-ZnO复合催化剂中光生载流子的传送和光生电子-空穴对的有效分离起到重要作用.可见光催化降解甲基橙(MO)和腐殖酸(HA)的实验进一步证明, g-C3N4/Vo-ZnO复合材料具有较好的光催化活性,优于单一的g-C3N4或Vo-ZnO材料.同时还发现, g-C3N4的负载量对光催化活性有显著影响,当氮化碳的负载量为1 wt%时,所制材料具有最高的光催化活性：可见光照射60 min后,MO降解率可达到93%, HA降解率为80%.复合材料光催化活性的增强一方面是因为氧空位的形成减小了ZnO的禁带宽度,使得ZnO对可见光的吸收能力大大增强；另一方面, g-C3N4和Vo-ZnO的能带符合了Z型催化机理所需的有效能带匹配,使得光生电子-空穴对得到了有效的分离,从而提高了光催化活性.降解MO的循环实验表明, g-C3N4/Vo-ZnO催化剂具有很好的稳定性且不容易发生光腐蚀.与此同时,我们对比了用不同方法制备的g-C3N4/ZnO材料的催化性能.结果显示,本文制备的g-C3N4/Vo-ZnO复合材料具有更好的降解效率.总体而言,对于降解有机污染物, g-C3N4/Vo-ZnO可能是一个更为有效可行的催化体系.此外,本文也为设计与制备其他新型光催化剂提供了一条新的思路.

关键词: 氧空位氧化锌 , 石墨化氮化碳 , 复合光催化剂 , 光降解 , Z型

Z-pin的拔出强度试验研究

王晓旭 , 陈利

材料工程 doi:10.3969/j.issn.1001-4381.2011.11.001

通过单根Z-pin从复合材料层合板中拔出的试验方法,测试了Z-pin的拔出强度,计算了Z-pin的临界埋入深度,并引入抗拉强度利用率概念来表征Z-pin的抗拉强度在拔出过程中的利用程度.结果表明,直径0.50mm和0.28mm的Z-pin临界埋入深度分别约为5.1mm和3.1mm.当Z-pin的埋入深度小于临界埋入深度时,Z-pin从层板中拔出；Z-pin拔出强度与埋入深度成正比,与Z-pin的直径成反比；当Z-pin的埋入深度大于临界埋入深度时,Z-pin发生断裂,Z-pin的抗拉强度利用率达到100％.最后提出了提高抗拉强度利用率的建议.

关键词: Z-pin , 拔出强度 , 复合材料 , 拔出试验 , 抗拉强度

复合材料Z-pin的压缩试验研究

王晓旭 , 陈利

航空材料学报 doi:10.3969/j.issn.1005-5053.2011.4.017

通过三种复合材料Z-pin的轴向压缩试验,观察了各Z-pin的压缩行为,分析了三种复合材料Z-pin在不同长度时的极限应力及其失效形式.结果表明,直径为0.50mm的碳纤维Z-pin的压缩性能最好,其各长度Z-pin所能承担的极限应力都较大.直径0.28mm的碳纤维Z-pin易发生失稳现象,芳纶纤维Z-pin在压缩力的作用下,接触端容易受到破坏.两种碳纤维Z-pin临界应力的理论值与试验值吻合较好,但芳纶纤维Z-pin的临界应力的试验值比理论值偏低.

关键词: Z-pin , 复合材料 , 压缩试验 , 临界应力

Z-pin增强复合材料层合板断裂韧性试验研究

郑锡涛 , 李泽江 , 杨帆

复合材料学报

针对Z-pin增强复合材料层合板,开展了断裂韧性的试验研究.研究选取了3种Z-pin直径(0.28、0.52、0.80 mm)且每种直径下分别以3种分布形式(5×5、8×8、10×10)排布Z-pin的增强方式,为了确定比较基准,试验中同时测试了不含Z-pin的复合材料层合板试样.通过Z-pin拔出试验测试了3种直径Z-pin从基体拔出过程中的载荷-位移关系.利用双悬臂梁试验和端部开口弯曲试验分别测试了不含Z-pin和含Z-pin试样的Ⅰ型断裂应变能释放率GIC、Ⅱ型断裂应变能释放率GⅡC.试验结果表明:与不含Z-pin的结构相比,Z-pin增强试样的Ⅰ型断裂应变能释放率GIC增大了83%～1110%,Ⅱ型断裂应变能释放率GⅡC增大了23%～438%;在相同Z-pin体积含量下,与增大Z-pin直径相比,增大Z-pin分布密度能更有效地提高复合材料层合板的断裂韧性.

关键词: Z-pin增强 , Ⅰ型断裂 , Ⅱ型断裂 , 应变能释放率 , 断裂韧性

Z-parameter Method for Damage Evaluation in HK40 Steel

Li XING , Jie ZHAO , Fuzhong SHEN , Wei FENG

材料科学技术（英文）

A Z-parameter method is used to evaluate the damage process of HK40 austenitic steel. By using Z-parameter based on the Larson-Miller method, the nonlinear master curve of the log stress vs Larson-Miller parameter P can be expressed as: P=27.74-3.4lgσ-0.032σ, and a family of curves parallel to the master curve can be written as: P=(27.74-Z)-3.4lgσ-0.032σ, where Z represents the magnitude of the deviation from the master curve. According to the creep rupture data both from different segments of a serviced tube and from the same segment locations with different service time, the value of parameter Z has close relationship with the deterioration of creep rupture properties. The damage state of the samples is evaluated by monitoring the changes in natural frequency f and Young0s modulus E, and the relationships between Z and the damage parameters are discussed.

关键词: Damage evaluation , 蠕变断裂 , 奥氏体钢 , Z参数

Frontiers of Surface and Interface Science and Engineering 2004 (FSISE 2004)Conference

金属学报(英文版)

关键词:

Hot Working Characteristics of CorrosionResistant Alloys G3 and 825

YU Man , LI Jingshe , TANG Haiyan , BAO Yaozong

钢铁研究学报(英文版)

The G3 and 825 alloys, with excellent combination of mechanical properties and corrosion resistance, can be used in hot, and acid environments. Thermal simulation tests were conducted on the alloys G3 and 825 in the THERMECMASTORZ simulator, at temperature between 1030 and 1300 ℃, with strain rate from 1 to 50 s-1 and strain ε=08. The variations of flow stress with deformation temperature and strain rate were presented. Change of alloy structure with hot deformation and effect of strain rate on alloy dynamic recrystallization have been studied through microstructure observation by OM, SEM and TEM. Moreover, hot plasticity characteristics of alloy were analyzed by temperaturereduction of area curves. The results showed that available hot working temperature for G3, G3Z and 825 was 1100 to 1240 ℃, 1130 to 1220 ℃ and 1050 to 1240 ℃, respectively. The reliable information on hot working in the alloy pilot production in steelwork is given.

关键词: corrosionresistant alloy; G3; 825; stressstrain curve; hot plasticity