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ELECTROCHEMICAL STUDY ON THE LOCALIZED CORROSION OF TWO DIFFERENT TEMPER LY12 ALLOYS

F.H. Cao , L. Guo , L.J. Zhang , Z. Zhang , J.Q. Zhang

金属学报(英文版)

The corrosion behavior of two different aged LY12 alloys in EXCO (234g/L NaCl, 50g/L KNO3, 0.1M HNO3) and MIL-H-600 (35g/L NaCl, 5g/L (NH4)2SO4) solutions were studied using electrochemical impedance spectroscopy (EIS) in conjunction with SEM technique respectively, and the pH variation of the above accelerated corrosion solution during materials corroding was also measured to characterize the corrosion processes. At the beginning of corrosion, EIS plots exhibited two capacitive arcs in the high frequency range (Cdl) and mediate frequency range (Clf) originating from the original corroded surface and the newly formed interface respectively, and a low frequency inductive loop due to the relaxation phenomenon of reaction intermediates. In the EXCO solution, the EIS results showed that once the exfoliation corrosion occurred, the inductive loop disappeared. The results also showed that the exfoliation corrosion susceptibility of state T6 is much higher than that of state T3, but the intergranular corrosion susceptibility has a reverse order. Based on the relationship of EIS results with SEM and metalloscopy morphologies of the corroding substrates and physic-chemical meaning of EIS parameters, an index (Clf / Cdl) has been proposed to characterize the extent of the localized corrosion, which variation tallies with the real corrosion extent correctly. Meanwhile, good agreement was found between the experimental results and the electrochemical model proposed and, good coherence between the electrochemical features and the distribution type of constituent particles of corroding material was observed.

关键词: electrochemical impedance spectroscope , null , null

Z超重核的禁戒α衰变

许昌 , 任中洲

原子核物理评论 doi:10.11804/NuclPhysRev.30.03.308

采用密度依赖的结团模型研究了奇Z超重核的禁戒α衰变,α粒子与子核之间的微观核势通过双折叠模型对M3Y核子-核子相互作用势以及α粒子与子核的密度积分给出.α粒子与子核之间的库仑相互作用也通过α粒子与子核的电荷密度积分给出.计算发现,由于非零角动量带来的禁戒效应和小的α粒子预形成几率,奇Z超重核的α衰变寿命会明显变长.

关键词: α衰变 , 超重核 , 结团模型

Z-pin的拔出强度试验研究

王晓旭 , 陈利

材料工程 doi:10.3969/j.issn.1001-4381.2011.11.001

通过单根Z-pin从复合材料层合板中拔出的试验方法,测试了Z-pin的拔出强度,计算了Z-pin的临界埋入深度,并引入抗拉强度利用率概念来表征Z-pin的抗拉强度在拔出过程中的利用程度.结果表明,直径0.50mm和0.28mm的Z-pin临界埋入深度分别约为5.1mm和3.1mm.当Z-pin的埋入深度小于临界埋入深度时,Z-pin从层板中拔出;Z-pin拔出强度与埋入深度成正比,与Z-pin的直径成反比;当Z-pin的埋入深度大于临界埋入深度时,Z-pin发生断裂,Z-pin的抗拉强度利用率达到100%.最后提出了提高抗拉强度利用率的建议.

关键词: Z-pin , 拔出强度 , 复合材料 , 拔出试验 , 抗拉强度

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

复合材料Z-pin的压缩试验研究

王晓旭 , 陈利

航空材料学报 doi:10.3969/j.issn.1005-5053.2011.4.017

通过三种复合材料Z-pin的轴向压缩试验,观察了各Z-pin的压缩行为,分析了三种复合材料Z-pin在不同长度时的极限应力及其失效形式.结果表明,直径为0.50mm的碳纤维Z-pin的压缩性能最好,其各长度Z-pin所能承担的极限应力都较大.直径0.28mm的碳纤维Z-pin易发生失稳现象,芳纶纤维Z-pin在压缩力的作用下,接触端容易受到破坏.两种碳纤维Z-pin临界应力的理论值与试验值吻合较好,但芳纶纤维Z-pin的临界应力的试验值比理论值偏低.

关键词: Z-pin , 复合材料 , 压缩试验 , 临界应力

Z-parameter Method for Damage Evaluation in HK40 Steel

Li XING , Jie ZHAO , Fuzhong SHEN , Wei FENG

材料科学技术(英文)

A Z-parameter method is used to evaluate the damage process of HK40 austenitic steel. By using Z-parameter based on the Larson-Miller method, the nonlinear master curve of the log stress vs Larson-Miller parameter P can be expressed as: P=27.74-3.4lgσ-0.032σ, and a family of curves parallel to the master curve can be written as: P=(27.74-Z)-3.4lgσ-0.032σ, where Z represents the magnitude of the deviation from the master curve. According to the creep rupture data both from different segments of a serviced tube and from the same segment locations with different service time, the value of parameter Z has close relationship with the deterioration of creep rupture properties. The damage state of the samples is evaluated by monitoring the changes in natural frequency f and Young0s modulus E, and the relationships between Z and the damage parameters are discussed.

关键词: Damage evaluation , 蠕变断裂 , 奥氏体钢 , Z参数

Z扫描技术及其在材料学中的应用

詹勇军 , 王锋 , 白黎 , 张素银 , 唐永健 , 吴卫东 , 谌家军

材料导报

以材料非线性光学性质的测试为基础,介绍了原始Z扫描技术的基本原理与数据处理;重点论述了双色时间分辨Z扫描技术的理论,并分析了它在材料光学非线性效应测试中展现的优越性以及应该注意的关键问题.根据Z扫描技术理论和实验的最新研究成果,总结了Z扫描技术的两条发展思路,即:CCD相机代替能量或功率计进行信号的采集和多种改进方法应用于实验测试.

关键词: Z扫描技术 , 非线性光学效应 , 双色时间分辨Z扫描技术 , CCD相机

z向流动RTM工艺树脂的流动浸润行为

李伟东 , 刘刚 , 安学锋 , 益小苏

复合材料学报

研究了层间“离位”附载多孔薄膜结构形式增韧层的大厚度纤维预成型体中等代流体(树脂)沿预成型体厚度方向(z向)的流动行为,通过压力传感器监测z向流动RTM(z-RTM)工艺注射过程中进、出胶口压力的变化规律,进一步反推树脂在层间“离位”增韧与非增韧预成型体中的宏观流动及微观浸润模式.结果表明,在z-RTM工艺注射过程中,树脂在沿纤维束间z向快速流动的同时完成对纤维丝束内部的浸润.层间“离位”附载的增韧层虽延缓了树脂的宏观流动,但使流动前锋曲面更加平滑.层间“离位”增韧预成型体z向渗透率为3.5×10-15m2,与非增韧预成型体的z向渗透率2.9×10-14m2相比,降低约一个数量级.

关键词: z向流动 , 树脂传递模塑 , 预成型体 , “离位”增韧 , 渗透率

120mm Q390GJC-Z35特厚板z向性能不合的研究

朱书成

钢铁研究学报

采用高倍金相检验、扫描电镜及能谱分析等方法对120mm Q390GJC-Z35特厚板的z向性能不合缺陷进行了研究。结果表明:z向性能不合主要是由于钢锭存在着较严重的中心偏析,在不合试样断口处存在着较多的块状(Nb、Ti)C聚集,块状的(Nb、Ti)C成为裂纹源。此外,偏析处还存在贝氏体等硬相组织,更加剧了断裂扩展,导致z向性能不合。通过优化成分设计,加强精炼过程控制,改进模铸浇注工艺,制定合理热处理工艺等相关措施,取得了良好的效果。

关键词: Q390GJC-Z35 , z-direction property , disqualification , cause analysis , measure

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