材料期刊网

COMPUTER SIMULATION OF NEURAL NETWORK CONTROL SYSTEM FOR CO_2 WELDING PROCESS

D. Fan , B. Li , Y.Z. Ma and J.H. Chen (Welding Institute , Gansu University of Technology , Lanzhou 730050 , China)

金属学报(英文版)

In this paper, neural network control systems for decreasing the spatter of CO2 welding have been created. The Generalized inverse Learning Architecture(GILA), the SPecialized inverse Learning Architecture(SILA)-I & H and the Error Back Propagating Model(EBPM) are adopted respectively to simulate the static and dynamic welding control processes. The results of simulation and experiment show that the SILA-I and EBPM have betted properties. The factors affecting the simulating results and the dynamic response quality have also been analyzed.

关键词: welding spatter , null , null

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

A Hydrogen Sensor Using SrCe_0:95Yb_0:05O_3-α as Proton Conductor and YH_x+Y H_2-z as Reference Electrode for Determining Hydrogen Pressure in Solid Steel

Ying Liy Changzhen Wang Zhongli Zhang Jiangxin Wang

材料科学技术（英文）

The steel contains a small amount of hydrogen which will escape during the heat treatment. The hydrogen pressure in 16MnRE steel was investigated with a hydrogen sensor, which used SrCe_0:95Yb_0:05O_3-α proton conductor as a solid electrolyte, YH_x+YH_2-z as a solid state reference electrode and Ni wire as electrode constructing a hydrogen concentration cell, shown as Ni|_YH_x+YH_2-z |SrCe_0:95Yb_0:05O_3-α |[H]_steel |Ni. The response time of sensor is less than 10 s. The relational expression of hydrogen partial pressure with temperatures was determined using two shape proton conductors. The results showed the regularity in experimental temperature range, and the hydrogen partial pressure increased as its temperature was raised.

关键词: Hydrogen sensor , Proton conductor , Solid electrolyte

Prediction Models on Distribution of Inherent Strains in T Type Welding Structure

Peng HE , Jicai FENG , Jiecai HAN , Yiyu QIAN

材料科学技术（英文）

A fundamental theory for the analysis of residual welding stresses and deformation based on the inherent strain distribution along the welded joint is introduced. The method of predicting maximum hardness Hv(y, z) and maximum inherent strain gmax is given. The model T.E.P-Tav-hardness calculation is proposed to predict distribution of inherent strains in T type welding structure. By T.E.P-Tav-hardness calculation, distribution of longitudinal inherent strains can be predicted in T type welding structure, and calculation and experimental results are consistent.

关键词: Inherent strain , null , null

快速凝固Al—Li─Cu—Mg—Zr合金中H相和Z相的TEM研究

张立春 , 何安强 , 叶恒强 , 张永昌

材料研究学报

用HRTEM、TEM及EDAX分析研究了Al─Li—Cu—Mg—Zr合金中的一种新相(暂名H相)和六角Z相的结构,确定H相具有四方点阵,点阵参数为α=2.8nm,c=2.4nm,EDAX分析表明H相和Z相均含Al、Mg、Cu发现H相与Z相的共存取向关系为[100]‖[1120]Z,[1010]H‖[0001]Z。还观察到Z相中一种特有的旋转畴结构

关键词: Al─Li─Cu─Mg─Zr合金.四方H相 , tetragonal H phase , hexagonal Z phase

合金元素对低合金高强度H型钢Z向性能的影响

李虎 , 王作成 , 薛长深 , 庄栋栋 , 王晓 , 张思勋

材料热处理学报

为了研究钢中合金元素Nb、B、Ni对低合金高强度H型钢抗层状撕裂能力(Z向性能)的影响,设计了对照试验,通过常温下拉力试验,对其力学性能尤其是断面收缩率进行了测试,使用XRD、SEM、TEM以及EDS对其组织和成分进行了分析.结果表明:微合金元素Nb、B和微量元素Ni对钢材的Z向性能产生了明显的不良影响,含有Nb、B和Ni,经过钢包精炼的Q345E钢的Z向性能显著低于不含Nb、B和Ni,未经钢包精炼且含有较多夹杂物的Q345B钢.其原因主要在于Nb、B、Ni的存在阻碍了钢材变形过程中位错在晶界和晶内的移动.

关键词: 低合金高强度钢 , Z向性能 , 合金元素 , 夹杂物 , 阻碍位错

新型金配合物——NH4[Au(MA)2]·H2O的合成、性质及镀金应用

冯能清 , 李德良 , 刘玺 , 盛国军 , 张闯

材料保护

为了减少和避免镀金过程中剧毒物质氰、腈的使用,以巯基乙酸为配体合成了一种新型亚金配合物巯基乙酸亚金铵;采用试金法和元素分析仪分析了其成分,用红外光谱、紫外光谱、热失重分析和导电性测量等研究了其基本理化性质,并将其用于电镀金.结果表明:合成产物的分子式为NH4[Au(MA)2]·H2O,以巯基乙酸的巯基和金配位为成键特征,在200℃之前热稳定性较好;以NH4[Au(MA)2]·H2O为金源,通过四因素三水平的正交试验获得了最佳镀金参数:电流密度200～ 300 A/m2,光亮剂十二烷基磺酸钠浓度5 ～8 mL/L,温度35 ～ 50℃,金浓度15～25 g/L;所得电镀金层表面光滑,颗粒尺寸在0.5 ～1.0μm内为单质金,均匀性好,镀层色泽、结合力优良.

关键词: 巯基乙酸亚金铵 , 合成 , 结构 , 理化性质 , 电镀金 , 应用

H_2气氛保护热处理1J50组织结构与性能的研究

孙建春 , 盛光敏 , 陈登明 , 周安若 , 朱光俊

功能材料

1J50软磁合金的性能主要是通过H_2热处理获得的,在1130℃和H2气氛保护下对冷轧态1J50软磁合金进行了热处理.运用MATS-2010SA软磁测试仪对处理前后1J50软磁合金的磁性能进行了检测,运用金相显微镜、XRD等手段对处理前后1J50软磁合金的组织结构进行了分析.结果表明,通过H_2热处理,1J50软磁合金的矫顽力显著降低,起始磁导率和最大磁导率提高;组织结构发生明显变化,冷轧态1J50软磁合金组织为孪晶奥氏体,平均晶粒尺寸为200μm,处理过后,晶粒显著长大,平均晶粒尺寸为100μm;由于在600℃时采取了快冷,处理后1J50软磁合金中未出现大量FeNi相和FeNi_3相.

关键词: H2热处理 , 1J50 , 组织结构 , 性能

新型SOFC阳极材料La0.7Sr0.3Cr0.5-yMn0.5-zCo(y+z)O3的制备和性能表征

何恩全 , 马文会 , 刘荣辉 , 于洁 , 戴永年

稀有金属 doi:10.3969/j.issn.0258-7076.2007.04.019

采用了甘氨酸-硝酸盐法制备了La0.7Sr0.3Cr0.5-yMn0.5-zCo(y+z)O3(y, z=0.1, 0.2)系列阳极材料.借助XRD, SEM对所制备的材料进行了物相和形貌分析.XRD表明利用GNP法制得的粉体在1350 ℃烧结5 h可以形成完整的钙钛矿相;SEM分析可知所得物料颗粒呈球状,尺寸约为1 μm,且没有团聚现象.同时,XRD显示La0.7Sr0.3Cr0.5Mn0.4Co0.1O3和La0.9Sr0.1Ga0.8Mg0.2O3电解质之间具有较好的化学相容性.采用直流四探针法测试了不同组成材料在250～800 ℃温度范围内在空气中的电导率,发现该系列材料在该温度段范围符合小极化子导电机制.另外,利用直流四探针法测试了La0.7Sr0.3Cr0.5Mn0.4Co0.1O3在不同还原气氛下的电导率,在CH4和H2气氛中,La0.7Sr0.3Cr0.5Mn0.4Co0.1O3最大电导率分别达到了4.5和0.42 S·cm-1.

关键词: 钙钛矿 , 阳极 , 电导率

SOFC阴极材料(La_(0.85)Sr_(0.15))_y(Mn_(1-z)Cr_z)O_3的物理性能和化学稳定性

杨威 , 隋智通

材料研究学报

采用烧结法制备阴极材料(La0.85Sr0.15)y(Mn1z-Crz)O3(y=0.85;1;z=0.1,0.2).研究了多孔锰酸镧与致密ZrO2(8mol%Y2O3)界面的成分变化和显微形貌(La0.85Sr0.15)(Mn0.9Cr0.1)O3呈现高电子电导率、良好的热膨胀系数匹配和化学稳定性而(La0.85Sr0.15)MnO3未起到阻止界面退化的作用在1300～1500℃范围内Mn、La、Zr和Sr发生扩散,其中Mn的扩散明显

关键词: SOFC , lathanum manganite. chemical stability , thermal expansion , conductivity , null