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Nanostructured Electrode Materials for Rechargeable Lithium-ion Battery Applications

G.X.Wang , Steve Bewlay , L.Yang , J.Z.Wang , Y.Chen , Jane Yao , H.K.Liu , S.X.Dou

材料科学技术(英)

Nanocrystalline LiFePO4 and Si-C powders were prepared as electrode materials for lithium-ion batteries. Near full capacity (170 mAh/g) was achieved at the C/8 rate at room temperature for LiFePO4 electrodes. Nanosize Si-C composite anode materials demonstrated a reversible lithium storage capacity of 1450 mAh/g with good cyclability when used as anodes in lithium-ion cells. Nanostructured electrode materials have an important role to play in developing a new generation of lithium-ion batteries that will offer a dramatic improvement in power delivery.

关键词: Lithium-ion battery , null , null , null

Chen系统的状态变量周期性反馈控制

李开明 , 李亚洲 , 冯维贵 , 林长

量子电子学报 doi:10.3969/j.issn.1007-5461.2007.05.014

采用非线性反馈控制,用附加了带参数的正弦项对Chen系统进行了有效的控制.随着参数k的逐渐增大,系统的动力学行为呈现出一系列的变化.数值研究结果表明:随控制参数的增大,驱动信号的强度渐大,混沌系统由混沌运动到周期轨道,最终到一相点.

关键词: 混沌 , Chen系统 , 不动点 , Lyapunov指数 , 反馈控制

Ion sputter erosion in metallic glass-A response to "Comment on: Homogeneity of Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass" by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z Jiang J. Mater. Res. 24, 3116 (2009)

Journal of Materials Research

The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.

关键词: room-temperature

ELECTRONIC STRUCTURE OF Pd-Y-Si GLASSES

LUO Meiqing CHEN Nianyi Shanghai Institute of Metallurgy , Academia Sinica , Shanghai , ChinaYU Zhizhong Shanghai Institute of Testing Technics , Shanghai , ChianNING Yuantao ZHOU Xinming Kunming Institute of Precious Metals , Kunming , China CHEN Nianyi , Professor , Shanghai Institute of Metallurgy , Academia Sinica , Shanghai 200050 , China

金属学报(英文版)

The electronic structure of Pd-Y-Si glass has been investigated by ESCA and quantum chem- ical calculation.It was found that the valence electrons of Y transferred to Si atoms in this metallic glass,forming polar covalent bonds.Perhaps these strong covalent bonds link Si and Y atoms to form clusters that hinder the process of crystallization.

关键词: Pd-Y-Si glass , null , null , null

SOLUBILITIES OF Ce,Nd AND Y IN α-Fe

LI Laifeng XING Zhongshu Institute of Metal Research , Academia Sinica , Shenyang , China XING Zhongshu , professor , Institute of Metal Research , Academia Sinica , Shenyang 110015 , China

金属学报(英文版)

The solubilities of Ce,Nd and Y in α-Fe at 873 to 1153 K have been deter mined by means of electron microprobe quantitative analyses.The temperature dependences of the solubilities were obtained from the experimental data.The results have been compared with those deter- mined by three other technigues,very good agreement was obtained between the results of all these techniques.

关键词: α-Fe , null , null , null , null

沸石Y用于组装纳米CdS

翟庆洲 , 蔡建岩 , 于淼

稀有金属材料与工程

以沸石Y及以甲基三甲氧基硅烷对沸石Y进行表面改性后的Y(m)沸石作主体,用离子交换法制备Cd-Y及Cd-Y(m)样品,然后以硫代乙酰胺取代有毒的硫化氢作硫源,水热法制备Y-CdS及Y(m)-CdS主-客体纳米复合材料.利用粉末XRD、化学分析、红外光谱、固体扩散漫反射吸收光谱、发光研究对制备的样品进行了表征.化学分析表明,CdS已进入沸石Y(Ym)主体中;XRD结果表明,CdS进入沸石Y(Ym)后,制得的复合材料沸石骨架仍然存在,且保持高度有序性,不改变骨架的长程有序性;红外光谱结果表明,在所制备的Y-CdS及Y(m)-CdS样品中,有Si-O-Cd新键生成;固体扩散漫反射吸收光谱结果表明,沸石YY(m)对可见光基本无吸收,Y-CdS和Y(m)-CdS吸收无明显差别;组装CdS后,Y-CdS及Y(m)-CdS产生发光现象.所制得的Y-CdS及Y(m)-CdS主-客体纳米复合材料具有作为发光材料的潜在性.

关键词: Y沸石 , Y改性沸石 , 甲基三甲氧基硅烷 , 纳米CdS , 主-客体纳米复合材料 , 表征

Microstructure Formation and Mechanical Property Involving Icosahedral Quasicrystal Phase of Y Rich Mg-Zn-Y Quasicrystal Alloy

D.Q. Wan , G.C. Yang

金属学报(英文版)

The microstructure formation and mechanical property involving icosahedral quasicrystal (I-phase) in the Y-rich Mg-Zn-Y alloy have been studied. The equilibrium formation of I-phase from the Y-rich Mg-Zn-Y melt is through a peritectic reaction between the Y-rich melt and the primary W-phase, which is discussed in detail. The independent nucleation and coupling growth mechanism between the W-phase and the I-phase, from the melt, are revealed, which is significant for understanding the peritectic reaction process involving icosahedral quasicrystal in the Mg-Zn-Y alloy. The mechanism of the quasicrystal phase strengthened magnesium alloys is also discussed here.

关键词: Mg-Zn-Y , null , null

EFFECT OF Y ON MECHANICAL PROPERTIES OF Fe-20Cr-4Al-Y ALLOY

LI Bei WU Shuangxia MENG Guang'en JIANG Liping PANG Wenjie Baotou Research Institute of Rare Earth , Baotou , China Baotou Research Institute of Rare Earth , P.O.Box 131 , Baotou 014010 , China

金属学报(英文版)

With the increase of Y content in the Fe-20Cr-4AI-Y alloy,the uniform deformability of tensile specimens was found to be slightly decreased,as well as,the fracture strength and re- duction after necking remarkably dropped.This seems to be dependent upon the brittle phase containing Y.The behaviour of Y-containing phase may be improved by adjusting the metallurgical technological process.

关键词: Fe-Cr-A1 alloy , null , null

THE EFFECTS OF Y,Zr AND Si ADDITIONS ONCYCLICOXIDATIONBEHAVIOUROFFeAlINTERMETALLICS

腐蚀科学与防护技术

研究了Y、Zr、Si对FeAl金属间化合物在1000~1200℃下循环氧化性能的影响,并用X射线衍射、扫描电镜及能谱分析等手段分析了氧化产物。结果表明,Y、Zr、Si的加入大大提高了FeAl金属间化合物表面氧化膜的抗剥落能力。从氧化动力学上看,Y和Zr或Y和Si的同时加入比单独加Zr效果好。

关键词: FeAl金属间化合物 , null , null

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