马保国
,
许婵娟
,
钟开红
,
蹇守卫
,
李相国
材料科学与工程学报
doi:10.3969/j.issn.1673-2812.2005.04.006
本文系统地研究了F、S、P元素对水泥熟料矿物形成过程和组成的影响及其叠加矿化效应,并通过化学分析和XRD分析探讨了其作用机理.研究结果表明:F、S、P元素在水泥烧成中均可降低液相出现和C3S形成温度,改善易烧性,但F、S叠加矿化效果最好,而且可以改善熟料的矿物组成及性能,避免了单掺F造成的熟料活性降低等问题.
关键词:
矿化效应
,
氟石膏
,
磷石膏
,
易烧性
鲁二敬
,
卢峰华
,
许鸿吉
,
谢明
,
钮旭晶
机械工程材料
通过周期浸润腐蚀试验，对比研究了S355．12W耐候钢和Q345R低合金钢在NariSOs溶液中的耐腐蚀性能，并用扫描电镜对腐蚀产物进行了观察和分析。结果表明：在相同试验条件下，S355J2W耐候钢的腐蚀速率低于Q345R钢的；S355J2W耐候钢会在表面形成黑褐色锈层，而Q345R钢表面形成橘红色易剥落的疏松锈层；S355J2W耐候钢腐蚀产物微观形貌为沿放射性方向生长的针状晶体，Q345R钢为颗粒状聚合物堆积而成，形状无规则，颗粒之间有较大的空隙。
关键词:
S355J2W耐候钢
,
周期浸润腐蚀试验
,
耐腐蚀性能
谷晓鹏
,
段珍珍
,
邓钢
,
谷晓燕
材料工程
doi:10.11868/j.issn.1001-4381.2015.02.004
利用激光-MAG复合焊和MAG焊进行了厚板S355J2W+N低碳钢的焊接实验,分析了两种焊接方法接头的微观组织和力学性能.结果表明:复合焊和MAG焊焊缝接头均由焊缝区、过热区、重结晶区和不完全重结晶区构成,复合焊接头截面呈“高脚杯”状特点,焊缝填充量和热影响区宽度较MAG焊明显减小.复合焊由于冷却速率快,过热区魏氏组织略有增多,硬度高于MAG焊,抗拉强度和弯曲性能与MAG焊相比,无显著差异,均能够满足生产标准的要求.
关键词:
S355J2W+N
,
激光
,
MAG
,
复合焊
,
接头组织
,
性能
赵文博
,
王明林
,
张慧
,
袁守谦
上海金属
针对S355J2钢连铸坯角部横裂纹,现场取样,利用扫描电镜、能谱仪等检测手段分别从裂纹形貌、夹杂物的组成及分布等方面进行分析;同时采用辐射温度计对连铸坯矫直段角部温度进行现场测量.结果表明,裂纹主要分为非封闭的主裂纹和许多细小的封闭裂纹,主裂纹内含有Al、Ca、Mg等氧化物夹杂,且裂纹已经被氧化;细小的封闭裂纹中有保护渣成分,说明钢液在凝固过程有保护渣卷入.夹杂物聚集导致连铸坯在矫直阶段因内弧受到拉应力作用而产生应力集中,成为横裂纹出现的内因.铸坯矫直段角部及其附近温度为850℃左右,处于第三脆性区,成为横裂纹产生的主要原因.优化保护渣制度和炼钢工艺可避免卷渣行为的发生;采用倒角结晶器可使角部温度避开第三脆性区.
关键词:
S355J2钢
,
角部横裂纹
,
夹杂物
,
角部温度
Superconductor Science & Technology
It is shown that the superconductivity in Ce(1-x)Gd(x)FeAsO(0.84)F(0.16) compounds can be modulated by internal (chemical) pressure. The internal pressure is induced by Gd substitution for Ce in CeFeAsO(0.84)F(0.16), which compresses the crystal lattice. The temperature dependences of resistivity and magnetization show that the superconducting-transition temperature T(c) is enhanced from 40 K for CeFeAsO(0.84)F(0.16) to 47.5 K for Ce(0.6)Gd(0.4)FeAsO(0.84)F(0.16). The increase and subsequent decrease of Tc upon application of external pressure, as observed previously in LaFeAsO(0.89)F(0.11), is entirely confirmed by the modulation of Tc of the Ce(1-x)Gd(x)FeAsO(0.84)F(0.16) superconductors by internal pressure.
关键词:
layered quaternary compound;43 k;iron
刘叔仪
金属学报
<正> 作为固体脆性断裂判据的J积分,其数值与其积分路径无关,这在文献中叫“守恒性”。这个守恒性已被推广到塑性断裂,这到底有否根据?本文目的是作这个问题的证明。未用原作者的方法,但由两个旋度判据得到应力应变函数行列式给出的一些否定结论,希望这对J积分应用条件的了解有所助益。1.弹塑性J积分守恒的条件 J积分
关键词:
郭艳青
,
任中洲
原子核物理评论
在单粒子势模型的框架下,计算了O同位素和F同位素的基态和某些低激发态的能级值、均方根半径值及密度分布.通过在伍兹-萨克逊势中引入同位旋依赖项,研究了同位旋效应对F同位素s-d能级间隙的影响.理论计算得到的均方根半径值和自旋宇称值与实验结果一致.尤其是,理论计算能够实现16F,15F和14F中2s1/2与1d5/2质子能级间的反转,且F同位素中s-d质子能级间隙及其整体变化趋势与已知实验结果符合较好.此外,理论结果表明12F的(1/2)+第一激发态为单质子晕态.
关键词:
同位旋效应
,
能级反转
,
质子晕
Journal of Applied Physics
Structural parameters have a critical impact on superconductivity in iron-based oxypnictide superconductors. Structural evolution study was performed on Ce(1-x)Gd(x)FeAsO(0.84)F(0.16) superconductors by the analysis of the x-ray diffraction patterns with Rietveld refinement. Substitution of Gd for Ce generates internal pressure that compresses the crystal lattice. The contraction of the c axis is also indicated by the reduction of Ce/Gd-As and Ce/Gd-O/F distances, while there is a slight increase in the As-Fe-As block size, which is compensated by a large reduction in the Ce/Gd-O/F-Ce/Gd block with Gd substitution. The diagonal Fe-As-Fe angle for Ce(0.6)Gd(0.4)FeAsO(0.84)F(0.16), with the highest T(c) among Ce(1-x)Gd(x)FeAsO(0.84)F(0.16) compounds, is 111.13 degrees. It is close to the ideal value of 109.47 degrees for the perfect FeAs tetrahedron, which is situated in the region of Fe-As-Fe bond angles where RFeAsO compounds tend to have the highest T(c). (C) 2011 American Institute of Physics. [doi:10.1063/1.3565408]
关键词:
layered quaternary compound;high-temperature superconductivity
