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Practice for Extending Blast Furnace Campaign Life at Wuhan Iron and Steel Corporation

ZHANG Shourong

钢铁研究学报(英文版)

One of the problems encountered in 60′s to 80′s of 20th century in China′s steel industry was short life of blast furnace shaft as well as the excessive erosion of blast furnace hearth. A series of research work was carried out in order to extend blast furnace campaign life. The concept of research and development was integrated in the construction of BF (blast furnace) No5 at WISCO (Wuhan Iron and Steel Corporation), and in October, 1991, the BF No5 was blown in. The blast furnace has worked smoothly for more than 15 years without any medium repair even guniting. It is expected that the campaign life of BF No5 would be longer than 16 years with a production over 11 000 t per unit inner volume (m3). A new blast furnace with an inner volume of 3 400 m3 is under construction, and is designed with a campaign life of 20 years without any medium repair. The campaign life of blast furnaces in China has been extended in recent years.

关键词: blast furnace;campaign life;erosion

Treatment of Reused Comprehensive Wastewater in Iron and Steel Industry With Electrosorption Technology

ZHANG Yunhua , GAN Fuxing , LI Meng , WANG Dihua , HUANG Zhongmai , GAO Yunpeng

钢铁研究学报(英文版)

Electrosorption technology was used to treat the reused comprehensive wastewater from iron and steel industry. A problem of relatively high conductivity of wastewater which greatly affects the reuse was examined, and industrial test was conducted for the reused water advanced deionization and purification in a comprehensive wastewater treatment plant of WISCO [Wuhan Iron and Steel (Group) Corporation]. The results of the onsite industrial test showed a satisfactory treatment performance for the reused water even at a flow rate of 1000 L/h in a standard 500 L/h unit. The average conductivity decreased by about 70%, from 580-780 μS/cm to 100-350 μS/cm. The average removal efficiency of Cl- and Ca2+ was about 75% and 68%, respectively, and CODCr of the treated water was also reduced in some degree while the pH value was almost unchanged. The energy consumption was as low as 06 kWh/t, which was remarkably superior to the conventional technologies. Therefore, it is entirely feasible that the novel electrosorption technology can be used in enhanced desalination and purification treatment of reused comprehensive wastewater in iron and steel industry.

关键词: electrosorption , desalination , purification , conductivity , industrial reused water

DYNAMIC SEGREGATION OF SULPHUR IN CAST IRON

QIN Ziqiang YU Zongsen University of Science and Technology Beijing , Beijing , China QIN Ziqiang Department of Metal Physics , University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The segregation of sulphur at iron/graphite interfaces in both grey and nodular iron was in- vestigated with AES.Sulphur was found to nonequilibratorily segregate at the interfaces in grey iron,but not in nodular iron.Such different behaviors of segregation,which will exagger- ate the difference of grey and nodular iron in sulphur content at iron/graphite interfaces, might be derived from the difference of solidification process between the two irons.

关键词: cast iron , null , null , null

Iron Extraction From Oolitic Iron Ore by a Deep Reduction Process

LI Ke-qing , NI Wen , ZHU Ming , ZHENG Mei-juan , LI Yuan

钢铁研究学报(英文版)

A laboratory experiment was carried out to extract iron from oolitic iron ore by a deep reduction and magnetic separation technique. The raw coal with fixed carbon of 66.54% was used as the reductant. The iron was successfully extracted from the oolitic iron ore which otherwise is nearly impossible to be separated due to its extremely fine-grain and mosaic nature. The results showed that an iron recovery rate of 90.78% and an iron content of 92.53% of iron concentrate could be obtained by such a technique. The optimized roast temperature is 1200 ℃ and time is 60 min. The subsequent magnetic separation was performed by using a magnetic field intensity of 111 kA·m-1 and a grinding fineness less than 45 μm of 96.19% for the sintered product.

关键词: oolitic hematite , deep reduction , magnetic separation

Technology of Iron Carbide Synthesis

M. Bahgat , null

材料科学技术(英)

Iron carbides are very promising metallurgical products and can be used for steelmaking process, where it plays as an alternative raw material with significant economic advantages. Also it has many other applications, e.g. catalysts, magnets, sensors. The present review investigates the different properties and uses of the iron carbides. The commercial production and the different varieties for the iron carbides synthesis (gaseous carburization, mechanochemical synthesis, laser pyrolysis, plasma pyrolysis, chemical vapor deposition and ion implantation) were reviewed. Also the effect of different factors on the carburization process like gas composition, raw material, temperature, reaction time, catalyst presence and sulfur addition was indicated.

关键词: Iron carbides , null , null , null

HYDROGEN-VACANCY INTERACTION IN IRON

WANG Xiaogang(Hunan Normal University , Changsha. China Manuscript received 3 June 1994)

金属学报(英文版)

The discrete variational method (DVM)and cluster model are used to study the electronic structure and atomic configuration of the hydrogen-vacancy complex in iron.The optimum location of hydrogen atom in the monovacancy in iron is determined by minimizing the total energy and the bond characteristic between hydrogen and iron atoms is analyzed Meanwhile, the positron annihilation characteristics of the hydrogen -vacancy complex is also calculated.

关键词: :vacancy hydrogen-vacancy complex , null , null

Nitriding iron at lower temperatures

Science

The microstructure in the surface layer of a pure iron plate was refined at the nanometer scale by means of a surface mechanical attrition treatment that generates repetitive severe plastic deformation of the surface layer. The subsequent nitriding kinetics of the treated iron with the nanostructured surface layer were greatly enhanced, so that the nitriding temperature could be as low as 300C, which is much lower than conventional nitriding temperatures (above 500degreesC). This enhanced processing method demonstrates the technological significance of nanomaterials in improving traditional processing techniques and provides a new approach for selective surface reactions in solids.

关键词: surface nanocrystallization;copper

Cooperation behavior of iron and phosphorus in electrodeposition of zinc-iron-phosphorus coating

Materials Chemistry and Physics

The co-operation behavior of iron and phosphorus in clectrodeposition of Zn-Fe-P alloy onto copper from light acid chloride solutions (LACS) was investigated by means of cyclic voltammetry and steady-state polarization techniques. It was found that, under the experimental conditions, the phosphorous and the iron promote the reduction of each other and their contents in Zn-Fe-P coating change synchronously, which has been interpreted theoretically in the view of quantum chemistry. The theoretical results showed that, because the orbital radius of 4S of iron atom is shorter than that of zinc atom, the overlapping integral of iron and phosphorus (SFe-P) is smaller than that of zinc and phosphorus (SZn-P) which resulted in the synchronous variation of the contents of the phosphorus and the iron in the electrodeposits, and which also showed that there exist the cooperative effect of phosphorus with iron series metal among their co-depositing coatings. (C) 2002 Elsevier Science B.V. All rights reserved.

关键词: electrodeposition;Zn-Fe-P alloy;cyclic voltammetry;light acid;chloride solution;alloys

THERMODYNAMIC PARAMETERS IN THE NUCLEATION OF LIQUID IRON

C.Huang , B.Song , J.H.Mao , Q.Lin , P.Zhao

金属学报(英文版)

By using of electrolytic pure iron, the specimens containing different oxide content were made in a Mo wire furnace. The DTA method was employed to measure the undercooling of liquid iron during solidification. The relations between the cleanness of liquid iron and undercooling, thermodynamic driving force of nucleation, the nucleus forming energy, as well as the critical radius of nucleus have been investigated. The results showed that with the increase of cleanness of liquid iron the undercooling and thermodynamic driving force increased, while the nucleus forming energy and critical radius of nucleus decreased.

关键词: pure iron , null , null

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