Xianting SUN
,
Lianzeng YAO
,
Chimei MO
,
Gang SHI
,
Weili CAI
,
Yimin ZHANG
,
Lide ZHANG
材料科学技术（英文）
Alumina aerogels with high porosity of nanometer size were prepared from Al, n-butanol and ethyl acetoacetate by the sol-gel route and the Na supercritical extraction drying technique. Optical experiment results showed that for alumina aerogels after annealing at 500 degrees C for 4 h one intense blue emission band appeared in the wavelength range of 400 to 800 nm, and the optical absorption edge moved from 8.0 eV of coarse grain Al2O3 to 3 similar to 5 eV and with increasing the annealing temperature, this luminescence band presented blue shifts. The reasons of these new optical properties are discussed in detail.
关键词:
Qing LIN
,
Lianzeng YAO
,
Guowei JIANG
,
Chuangui JIN
,
Weifeng LIU
,
Weili CAI
,
Zhen YAO
材料科学技术（英文）
Aligned silicon dioxide nanotubes with diameter of 60~70 nm were synthesized inside the nanoholes of an anodic Al membrane (AAM) template by pressure impregnating the AAM pores with the SiO¬2 sol. The SiO¬2 nanotubes with different wall thickness were produced by repeating the process. Using the second-order template of porous AAM with silicon dioxide nanotubes, it was fabricated the nanostructure of Fe nanowires encapsulated by SiO¬2 nanotubes by electrochemical deposition. Scanning electron microscope (SEM) and transmission electron microscope (TEM) observations show that the nanotubes and nanocables are compact, continuous and uniform. Selected area electron diffraction (SAED) pattern shows the Fe nanowire is a single crystal. The magnetic properties of these samples were checked by a vibrating sample magnetometer (VSM). The coercivities of the samples are greatly improved compared to the corresponding bulk materials.
关键词:
Template
,
null
,
null
,
null
Ye ZHANG
,
Lide ZHANG
,
Chimei MO
,
Yuanhong LI
,
Lianzeng YAO
,
Weili CAI
材料科学技术（英文）
The synthesis of dispersions of MMA (methylmethacrylate) with different concentrations of oleic acid coated nano-TiO2 particles was performed by hydrolysis of TiCl4 in the mixture solutions of MMA, oleic acid and H2O with various concentrations. When MMA :oleic acid : H2O : TiCl4 1.00 : 0.064 : 0.01 : 0.032 (by mol fraction), the dispersion of MMA with oleic acid coated nano-TiO2 particles was very stable. Optical absorption result showed that the absorption band was located in the ultraviolet range from 200 to 400 nm. This dispersion was added to a kind of automobile surface lustering agent (type II), and then this lustering agent with nano-TiO2 was coated on the surface of automobile surface paint. When the doping amount of the dispersion in the lustering agent=10 vol. pet, the state of paint (color and glossiness) did not present any change after irradiation of an ultraviolet lamp with the power of 1000 watt for two days. The sample with surface paint and lustering agent doped by 10 percent dispersion after suffering from irradiation of the sunlight for half a year (from May to November) kept the original state. However, for the samples with automobile paint and lustering agent without doping of nano-TiO2, the color and glossiness lost easily after irradiation of an ultraviolet lamp. These results prove that nano-TiO2 is a kind of high-efficient additive of paint for protection against ultraviolet irradiation.
关键词:
Mingzai WU
,
Lianzeng YAO
,
Weili CAI
,
Guowei JIANG
,
Xiaoguang LI
,
Zhen YAO
材料科学技术（英文）
Ordered ZnO nanowire arrays embedded in anodic aluminum oxide (AAO) membranes were fabricated by electrochemical deposition of Zn(NO3)2+H3BO3 solution in a boiling bath. Scanning electron microscope (SEM) and transmission electron microscope (TEM) observation results show that the polycrystalline ZnO nanowires with diameters around 100 nm were uniformly assembled into the ordered nanochannels of the AAO. The results of the investigation into photoluminescence (PL) and electronic paramagnetic resonance (EPR) measurements reveal that the interfaces between the ZnO nanowires and the pore walls of the AAO create a lot of oxygen vacancies, which are responsible for the green light emission (peaking around 512 nm) and the huge enhancement of the PL emission.
关键词:
Nanowires
,
null
,
null
Yushuang LIU
,
Chimei MO
,
Weili CAI
材料科学技术（英文）
The change of the temperature coefficient of resistivity (cr) with the particle size, d(p), and the grain size, d(c), in the nanostructured Ag bulk samples was investigated. d(p) and d(c) were controlled by heating the nano-Ag powders over the temperature range from 393 to 453 K. The electrical resistance measurements of the nanostructured Ag bulk samples obtained by compacting the Ag powders after heat treatments showed a change in the sign of alpha with d(p) and d(c). When d(p) and d(c) are smaller or equal to 18 and 11 nm below room temperature or 20 and 12 nm above room temperature, respectively, the sign of the temperature coefficient of resistivity changes from positive to negative. The negative alpha arises mainly from the high resistivity induced by the particle interfaces with very lowly ordered or even disordered structure, a large volume fraction of interfaces and impurities existing in the interfaces, and the quantum size effect appearing in the nano-Ag grains.
关键词:
张宝艳
,
陈祥宝
,
李敏
,
邢丽英
,
汪亮
,
蒋诗才
航空材料学报
doi:10.3969/j.issn.1005-5053.2002.01.008
探讨了树脂基体、碳纤维增强体以及树脂基体-纤维的界面等对双马来酰亚胺(简称双马)树脂基复合材料冲击后压缩强度(CAI)值的影响,指出降低树脂基体的交联密度和产生微观两相结构是提高碳纤维/双马复合材料CAI值的两个典型方法.合适的树脂含量有利于保持复合材料体系较高的CAI值,采用高强高韧性的碳纤维可明显提高复合材料体系的CAI值.为获得较高的CAI值,保持合适的树脂基体-纤维界面性能也是必要的.
关键词:
双马来酰亚胺
,
纤维增强复合材料
,
韧性
,
界面
段友社
,
郭书良
,
吴刚
,
侯军生
复合材料学报
基于热压罐成型工艺,选择了树脂柱Z向增强泡沫芯材、碳纤维Z向增强泡沫芯材、Kevlar纤维缝纫增强泡沫芯材3种Z向增强复合材料结构,对夹芯结构进行了低速冲击损伤和冲击后压缩（CAI）性能研究,考察了不同Z向增强方式对冲击损伤面积和破坏模式的影响。结果表明,Z向增强对泡沫芯材产生了初始损伤,其冲击后损伤面积大于未增强泡沫夹芯结构;但Z向增强改变了夹芯结构的压缩破坏机制。通过选用合适的Z向增强材料和Z向增强参数,能够提高夹芯结构的压缩强度和CAI强度。其中当增强材料为碳纤维,增强参数为10mm×10mm时,压缩强度提高了13%,CAI强度提高超过40%。
关键词:
复合材料
,
泡沫夹芯
,
Z向增强
,
冲击损伤
,
冲击后压缩
张子龙
,
程小全
,
益小苏
复合材料学报
doi:10.3321/j.issn:1000-3851.2002.05.021
为了考察一种小试件CAI试验方法的有效性,本文作者对复合材料层合板的准静态横向压缩特性和损伤,以及损伤后的压缩破坏进行了试验研究,采用C扫描、热揭层等技术对层合板内的损伤进行测量,并将含准静态横压损伤层合板的剩余压缩强度与低速冲击后板的压缩强度进行了比较.结果表明:在横压过程中存在分层损伤起始门槛压缩载荷值或压入深度值,以及横压载荷极限值;小板试件各界面的分层面积沿厚度方向的分布和继后的压缩破坏形式等与SACMA的CAI试验标准的情况相异.
关键词:
复合材料层合板
,
低速冲击
,
准静态横向压缩
,
损伤
,
压缩破坏
王浩
,
郑亚萍
,
张娇霞
,
许亚洪
,
戴峰
宇航材料工艺
doi:10.3969/j.issn.1007-2330.2009.04.014
针对氰酸酯采用环氧树脂进行改性研究,对该体系的流变性能与DMA进行分析,并对浇注体的力学性能进行了研究.以聚砜作为增韧剂,采用"离位"增韧技术,制备复合材料层压板,测试了复合材料的力学性能与冲击后压缩强度(CAI),对微观增韧机理进行了研究.结果表明,在40℃时,氰酸酯/环氧树脂体系有较长的工艺适用期,很好的工艺操作性.Tg为200℃时,浇注体的力学性能优良.采用热塑性树脂作为"离位"增韧层,体系出现了相反转结构,具有较好的增韧效果,复合材料的CAI值从180 MPa增加到260 MPa,对复合材料的力学性能没有影响.
关键词:
氰酸酯
,
"离位"增韧改性
,
冲击后压缩强度
中国有色金属学报(英文版)
doi:10.1016/S1003-6326(16)64373-X
提出了一种从氧化铝中提取原铝的新方法。该方法的原理基于如下化学反应：AlI3+(3/2)Zn=Al+(3/2)ZnI2。首先通过氧化铝的碳热氯化反应得到氯化铝(AlCl3)，然后通过氯化铝和碘化钙的交换反应(AlCl3+CaI2→AlI3+CaCl2)得到碘化铝。在实验室条件下对这些反应进行了研究，同时对一些回收主要化学试剂的反应进行了研究(Cl2, ZnI2→Zn, CaCl2→CaI2)。采用XRD和SEM对反应产物的相组成及形貌进行分析。采用总自由能最小方法对化学反应平衡进行计算。结果表明，采用非电解方法，可以在没有非常高的温度和可消耗的化学试剂的条件下，从氧化铝中有效地提取铝。与当今采用燃煤发电提供电力的铝电解厂相比，本方法所产生的单位碳消耗和 CO2大气排放可以降低一半以上。
关键词:
铝
,
铝合金
,
氯化物
,
碘化物
,
锌
,
碘
,
高速冶金
