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ANISOTROPY IN Nd_(12)Fe_(77)Co_5B_6 MELT SPUN FLAKES

J. Han , Y.S. Wang , Y.D. Gao , W.L. Guo and B.C. Liu Beijing Institute of Aeronautical Materials , Beijing 100095 , China

金属学报(英文版)

Alloyof composition Nd12 Fe77 Co5 B6 was melt spun into flakes and then annealed. The magnetic propertiesandthe microstructureoftheflakesand powders were analyzed via VSMdemagnetization curves and XRDpatterns. New phenomenon that anisotropy existsin an nealed flakes wasfounded. Theorientationofthetextureparallelstothec axisthatistheeasy magnetization axisof Nd Fe B typecrystal.Itisveryusefulfor manufacturing high perfor mancebonded magnets with good magneticandtemperature properties.

关键词: Nd Fe B , null , null , null , null

B4C(W,Ti)C陶瓷复合材料的制备及其性能

邓建新 , 周军

硅酸盐通报 doi:10.3969/j.issn.1001-1625.2002.01.004

采用热压烧结工艺制备了B4C/(W,Ti)C陶瓷复合材料.研究表明:B4C/(W,Ti)C陶瓷材料烧结时将产生化学反应,反应产物为TiB2和W2B5.B4C/(W,Ti)C陶瓷材料的性能与(W,Ti)C的含量密切相关,随(W,Ti)C含量的增加,材料的致密度、抗弯强度和断裂韧性逐渐增加,硬度逐渐减小;当保温时间低于50min时,材料的致密度、抗弯强度和硬度显著降低;B4C/(W,Ti)C陶瓷复合材料的最佳性能参数为:抗弯强度693MPa,维氏硬度23.5GPa,断裂韧性3.9MPa·m1/2.磨损实验表明,B4C/(W,Ti)C陶瓷材料在低速小载荷的实验条件下,耐磨性能优异,在高速大载荷的实验条件下,磨损过程中局部点的高温导致试样表面发生氧化,加剧了材料的磨损.

关键词: B4C , 陶瓷材料 , 复合材料

Image analysis of periodic rain accelerated corrosion of aeronautical aluminium alloys

Materials Science and Engineering a-Structural Materials Properties Microstructure and Processing

Periodic rain tests have been carried out for simulating atmospheric corrosion of aeronautical aluminium alloys. A digital image preprocessing and analysis method based on wavelet transformation was used to study the corrosion morphology of aluminium alloys samples, through which an image feature parameter 8 was extracted and discussed. The influences of orthogonal experiment parameters on acceleration were analyzed according to image feature parameter 6 with analysis of variance (ANOVA) method, and the optimal parameters for accelerated corrosion test were also obtained. The result was shown to be consistent with that from weight loss method. (c) 2007 Elsevier B.V. All rights reserved.

关键词: aeronautical aluminium alloys;accelerated corrosion;linage analysis;simulated environment;atmospheric corrosion;electrochemical impedance;pitting corrosion;exposure;steel;zinc

Novel hard materials with controlled (W0.5Al0.5)C grain shapes: in-situ high pressure preparation and mechanical properties

Zhuhui QIAO

金属学报(英文版)

A novel hard material with various (W0.5Al0.5)C grain shapes was successfully prepared through mechanical alloying and in-situ high-pressure sintering process. X-ray diffraction apparatus and scanning electron microscopy were used to characterize the phase and the microstructures of the samples. The novel hard materials with ``fibrous", ``rounded" and ``plate-like" grains, which do not contain sharp edges, have the improved mechanical properties. The bulk boundless (W0.5Al0.5)C hard material with various (W0.5Al0.5)C grain shapes possesses good mechanical properties and light weight. The formation mechanism for the non-equilibrium (W0.5Al0.5)C grains during in-situ high-pressure sintering is also discussed.

关键词: Novel hard material

电沉积RE-Ni-W-P-B4C-PTFE

郭忠诚 , 陈凌 , 杨显万 , 翟大成

电镀与涂饰 doi:10.3969/j.issn.1004-227X.2000.03.001

研究了RE-Ni-W-P-B4C-PTFE复合镀层的性能.结果表明:热处理温度对RE-Ni-W-P-B4C-PTFE复合镀层的硬度影响很大,当温度达到400℃时,复合镀层的硬度达到极大值(1145 Hv);在同一热处理温度下,当保温时间达到3小时,镀层的硬度值最佳.当热处理温度达到300℃时,RE-Ni-W-P-B4C-PTFE复合镀层的耐磨性最好.高温氧化试验表明:RE-Ni-W-P-B4C-PTFE复合镀层随氧化时间和温度的延长,被氧化的程度增加.

关键词: 电沉积 , RE-Ni-W-P-B4C-PTFE复合镀层 , 性能

电沉积RE-Ni-W-B-B4C-MoS2复合镀层的性能研究

郭忠诚 , 朱晓云 , 翟大成 , 徐瑞东 , 曹建春 , 龙晋明

材料保护 doi:10.3969/j.issn.1001-1560.2002.07.012

研究了RE-Ni-W-B-B4C-MoS2复合镀层在不同氧化温度和时间下的抗高温氧化性.结果显示,当温度小于800 ℃时,RE-Ni-W-B-B4C-MoS2复合镀层被氧化的程度较小;温度超过800 ℃,氧化膜的增重呈直线增加.RE-Ni-W-B-B4C-MoS2复合镀层的硬度随着热处理温度的升高而增加,当热处理温度达到400 ℃时,复合镀层的硬度升到极大值(1 368 HV);若继续升高温度,镀层硬度逐渐降低.RE-Ni-W-B-B4C-MoS2复合镀层的耐磨性经400 ℃热处理后最好.工艺条件对RE-Ni-W-B-B4C-MoS2复合镀层的表面形貌影响较大,随着电流密度或镀液温度的升高,复合镀层结晶粗,晶粒大;反之,镀层结晶细,表面晶粒细小.RE-Ni-W-B-B4C-MoS2复合镀层的镀态下以非晶态为主,部分已晶化;当经500 ℃热处理后,复合镀层已晶化;经800 ℃热处理后,CeO2和B4C仍以化合物的形式存在,由此可以说明,CeO2和B4C的加入,可以提高RE-Ni-W-B-B4C-MoS2复合镀层的热稳定性.

关键词: 电沉积 , 复合镀层 , 抗高温氧化 , 耐磨性 , 表面形貌

45钢上Ni-W-Co-B4C复合镀层的制备及其摩擦学性能

许长庆 , 田静 , 李贵江

材料保护 doi:10.3969/j.issn.1001-1560.2007.11.002

利用电沉积技术在45钢表面制备了Ni-W-Co-B4C复合镀层,并研究了油润滑磨损条件下Ni-W-Co-B4C复合镀层的磨损特性.结果表明,Ni-W-Co镀层磨损形貌中有很深的犁沟,局部并有黏着磨损的特征,镀层的抗磨损性能较差;加入B4C颗粒的Ni-W-Co-B4C复合镀层磨损形貌试验中的犁沟较浅,没有发现黏着磨损现象,但B4C颗粒与金属基体结合不牢,有颗粒脱落现象.B4C颗粒含量、大小和载荷都对复合镀层的耐磨性有影响.当镀层中含有20%(体积分数)的B4C颗粒时,磨损性能最好.

关键词: Ni-W-Co-B4C复合镀层 , 电沉积 , 摩擦学性能 , 油润滑 , 45钢

MICROSTRUCTURE AND PROPERTIES OF SiC_w/6061Al COMPOSITE The Author is now with Institute of Metal Research,Academia Sinica,China

MA Zongyi YAO Zhongkai Harbin Institute of Technology , Harbin , China

金属学报(英文版)

The SiC_w/Al composite prepared by squeeze casting has a combination of superior room temperature specific strength and modulus together with excellent thermal properties.The extrusion can make an improvement on the strength and ductility of the composite from 582 MPa as squeeze casted up to 639 MPa,and on the transformation from isotropic to the anisotropic structure.This seems to be explained by the orientation of whiskers and the densification of dislocations in matrix.TEM observation indicates that the stacking fault is the usual planar defect on the SiC_w surface. composite;;SiC whisker;;Al alloy;;microstructure

关键词: composite , null , null , null

反应热压烧结制备C/W2B5复合材料的结构与性能

吕毅 , 温广武 , 宋亮 , 雷廷权 , 周玉

稀有金属材料与工程

通过B4C和WC之间的固相反应热压烧结制备C/W2B5复合材料,并研究了W2B5含量对复合材料显微结构和性能的影响.结果表明该复合材料具有较高的致密度,最高达100%;生成的W2B5颗粒呈板片状,且随碳含量的增加,其尺寸减小.复合材料具有优异的力学性能和导电性,其强度和韧性最大值分别为786.2±91.2 MPa和8.89±0.68MPa·m1/2,电阻率最低仅为0.61μΩ·m.分析认为高强度和低电阻率主要归因于高致密度和高强度、低电阻率的W2B5相的生成,而较高的韧性来源于板片状W2B5颗粒和残余应力所产生的裂纹桥接,偏转增韧机制.

关键词: 致密度 , 抗弯强度 , 断裂韧性 , 电阻率

结晶器表面电沉积RE-Ni-W-P-B4C镀层性能的研究

彭其春 , 李源源 , 朱诚意 , 周飞

材料保护

在新开发的RE-Ni-W-P-B4C结晶器表面镀层的基础上,研究了热处理工艺对此复合镀层的硬度、物相的影响,并借助氧化失重试验分析了复合镀层的高温抗氧化性能.采用HM-114型显微硬度仪测定镀层的硬度;采用Phlip X射线衍射仪进行镀层物相分析;采用电阻炉对不同镀层试样进行氧化.结果表明:热处理温度<400℃时,随着温度的升高镀层硬度增加,>400℃时,硬度变化不大;当热处理温度达500℃、时间为3 h时硬度达到最大值,为1 236.4 HV,此时镀层主要为晶态物相:CeO2、Ni、W、P、Ni3P、Ni3B.对比了不同镀层在不同温度下的抗氧化性能,发现RE-Ni-W-P-B4C镀层在<650℃时有很好的抗氧化性能.

关键词: 电沉积 , 结晶器 , RE-Ni-W-P-B4C复合镀层 , 高温抗氧化性能

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