Weili CAI
,
Chimei MO
,
Lan ZHANG
,
Yuanhong LI and Lianzeng YAO)(Dept. of Materials Science and Engineering
,
University of Science and Technology of China
,
Hefei 230026
,
China)
材料科学技术(英文)
Porous Al2O3 host/NiO nanocomposites have been prepared by pyrolysis of Ni2(OH)2CO3 inthe nanostructured Al2O3 hosts. Diffuse reflection spectra in the wavelength range of 200 to800 nm were measured. Results show that (1) in each spectrum exist several absorption bandsof nano-NiO. With increasing the pyrolysis temperature from 550 to 1000℃, the numbers ofabsorption bands of NiO increase from 2 to 6 (P1-P6), (2) comparing with optical absorptionbands of single crystal NiO, for porous nanocomposites the P1, P2 and P4 present "blue shift"and the P3, P5 and P6 exhibit "red shift"; (3) when the pyrolysis temperature, Tp, is 550℃, theabsorption bands become so weak that only two bands (P1 and P6) can be observed and inverselywhen Tp=1000℃ all six absorption bands of NiO are strong, (4) for porous Al2O3/NiOnanocomposites prepared by pyrolysis at 1000℃ the PF+ caused by the F+ centers in theAl2O3 host moves towards the short wavelength at first with increasing the doping amount ofNiO from 5 to 50 wt pct and then shifts to the long wavelength with further increasing NiO. Inthis paper, the above phenomena and mechanism of the absorption bands of NiO are discussedin detail.
关键词:
LIANG Yong LI Ruiguo Institute of Metal Research
,
Academia Sinica
,
Shenyang 110015
,
ChinaInstitute of Corrosion and Protection of Metals
,
Aademia Sinica
,
Shenyang
,
110015
,
China
材料科学技术(英文)
Recent advances in laser coating technology including laser cladding,laser surface alloying and laser vapour deposition in China are reviewed in this paper.
关键词:
laser
,
null
,
null
,
null
,
null
QIAO Lijie LIU Rui XIAO Jimei University of Science and Technology Beijing
,
Beijing
,
China
金属学报(英文版)
The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.
关键词:
stress corrosion cracking
,
null
,
null
,
null