D.Y.Li(Dept. of Mater. Sci & Eng.
,
The Pennsylvania State University
,
University Park
,
PA 16802
,
USA )B.Debray and J.A.Szpunar(Dept. of Metall. Eng.
,
McGill University
,
3450 Uuiversity Street
,
Molitreal
,
PQ
,
Canada H3A 2A7)
材料科学技术（英文）
The (100) texture of solidified fcc metals, caused by the preferential (100) dendrite growth, could be closeIy related to solid/melt interfaces which behave differently along different crystallographic orientation. The stability and roughness of {111} and {100} solid/melt interfaces of fcc metals were investigated using a modified Temkin multi-layer model. It is demonstrated that {100}crystal/melt interface is more unstable and rougher than {111} interface. The effect of the stability of crystal/melt interface on the (100) texture formation in solidified fcc metals has been analysed and discussed.
关键词:
D.Eylon
,
S.R.Seagle
材料科学技术（英文）
The state of Ti research, development and industry is reviewed in this article. The fifty-year anniversary of Ti technology commercialization in the USA provides an opportunity for a historical perspective. Incorporation of "information-age" tools into alloy development, processing, and production invigorates the technology. Consolidation, diversification and globalization have been transforming the Ti industry in the recent years.
关键词:
梁浩
,
赵明久
,
陈胜虎
,
徐勇
,
王永利
,
戎利建
金属学报
doi:10.11900/0412.1961.2015.00255
采用OM,SEM,TEM,EPMA和二次离子质谱(SIMS)等手段,研究了B对J75抗氢合金晶界η相析出的抑制作用机制,采用饱和热充氢、三维原子探针(3DAP)技术和氢渗透实验方法,研究了B对合金抗氢性能的影响机制.结果表明,不含B合金中存在Ti的晶界偏聚,导致晶界7相在时效过程中析出;含B合金中,由于B抑制了Ti的晶界偏聚,使玎相难以形核长大,从而抑制了晶界η相的析出.B和H原子存在位置竞争关系,B降低合金的氢扩散系数,阻碍H原子的扩散和迁移,减少晶界偏聚H原子数量,抑制氢致裂纹形成.
关键词:
J75合金
,
B
,
抗氢性能
,
η相
杨金瑞
,
余尚先
,
顾江楠
高分子材料科学与工程
通过对resol(羟甲基酚化合物和低分子量羟甲基酚树脂)DEPT135图谱的分析讨论,得到一系列计算resol微细结构参数的经验公式.根据DEPT135图谱可判断是否发生缩聚反应,根据经验公式可计算酚单体各个活性点参与反应百分率或酚羟基导入率、不同类型缩聚所占百分率及低分子量羟甲基酚树脂的平均核体数.
关键词:
羟甲基酚化合物
,
羟甲基酚树脂
,
DEPT135
,
结构参数
Journal of Crystal Growth
The microstructure and room temperature compressive deformation behavior of a rapidly solidified NiAl-Cr(Mo)-Dy eutectic alloy fabricated by water-cooled copper mold method were studied by a combination of SEM, EDS and compressive tests. The morphology stability after hot isostatic pressing (HIP) treatment was evaluated. Rapid solidification resulted in a shift in the coupled zone for the eutectic growth towards the Cr(Mo) phase, indicating a hypoeutectic composition, hence increasing the volume fraction of primary dendritic NiAl. Meanwhile, significantly refined microstructure and lamellar/rod-like Cr(Mo) transition were observed due to trace rare earth (RE) element Dy addition and rapid solidification effects. Compared with the results in literature [H.E. Cline, J.L. Walter, Metall. Trans. 1(1970)2907-2917; P. Ferrandini, W.W. Batista, R. Caram, J. Alloys Comp. 381(2004)91-98], an interesting phenomenon, viz., NiAl halos around the primary Cr(Mo) dendrites in solidified NiAl-Cr(Mo) hypereutectic alloy, was not observed in this study. This difference was interpreted in terms of their different reciprocal nucleation ability. In addition, it was proposed that the localized destabilization of morphology after HIP treatment is closely related to the presence of primary NiAl dendrites. The improved mechanical properties can be attributed to the synergistic effects of rapid solidification and Dy addition, which included refined microstructure, suppression of the crack development along eutectic grain boundaries, enhancement of density of geometrically necessary dislocations located at NiAl/Cr(Mo) interfaces and the Cr solubility extension in NiAl. (c) 2006 Published by Elsevier B.V.
关键词:
lamellar/rod-like transition;morphological stability;nucleation;solubility;rapid solidification;rod-plate transition;mechanical-properties;electronic-structure;growth-rate;cr alloys;toughness;chromium;strength;nucleation;interface
Journal of Physics-Condensed Matter
The temperature dependences of the magnetization, internal energy and specific heat in a three-sublattice ferrimagnet or ferromagnet with /J(ab)/ = /J(bc)/ not equal /J(ca)/ are calculated within the framework of the linear spin-wave approximation, by employing retarded Green's functions. For both the ferromagnet and the ferrimagnet, the internal energy and the specific heat decrease with increasing J ' /J and/or the value of the spins. For fixed values of S,, Sb, S, and J ' /J, the internal energy and the specific heat increase, whereas the sublattice magnetization decreases with increasing temperature theta. The three-sublattice ferrimagnet has some particular characteristics which are not shown by the systems with two sublattices. For ferrimagnets, the antiferromagnetism of the system becomes weaker with increasing J ' /J. The sublattice magnetization at low temperatures (also the magnetization M(0) at 0 K) of a ferrimagnet increases with increasing J ' /J for fixed values of S(a), S(b) and S(c). The effects of the spins S(a) (S,) and Sb On the magnetizations of other sublattices differ. The characteristics of the a-sublattice are the same as those of the c-sublattice, due to their similarity as well as the symmetry of the system. The behaviours of the b-sublattice are different from those of the a- and c-sublattices, due to the asymmetry of the three-sublattice system. The spin-value dependences of the spin deviation Deltam per spin land also the energy for the zero-point quantum fluctuation) of the system are different for different sublattices. These differences are ascribed to the asymmetry of the three-sublattice systems, which leads to the new intrinsic properties of the systems.
关键词:
layered heisenberg ferrimagnets;spin-wave theory;elementary;excitations;superlattices;systems;magnetoresistance;antiferromagnet;interfaces
Physical Review B
The Hamiltonian for a four-sublattice Heisenberg ferrimagnet or ferromagnet with different exchange constants (J(ab) = J(cd) not equal J(bc) = J(da)) was established. An extended Bogoliubov transformation was developed by solving an equation group, consisting of 20 equations and 20 unknowns. The procedure for solving the equation group was carried out by introducing a simple way of reducing the numbers of the equations and the unknowns. The spin-wave spectra in the present system have been determined by performing the standard Holstein-Primakoff transformation and the Bogoliubov one. It has been found that the spin-wave spectra of the present system depend on the exchange constants and that the degeneracy of the spin-wave spectra remains. The results for a special case (J(ab) = J(bc)) i.e., an antiferromagnet are discussed briefly. The spin-wave spectra of the four-sublattice Heisenberg antiferromagnet are found to be degenerative also and they are linear in k for small k.
关键词:
model
