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THE EFFECT OF SILICON ADDITIVE ON THE STRUCTURE AND PROPERTIES OF C-B_4C-SiC COMPOSITE

HUANG Qizhong , YANG Qzaoqin and WU Lijun(Powder Metallurgy Research institute , Central Sonth University of Technology , Changsha 410083 , China Materials Research and Test Center , Hnnan University , Changsha 410082 , ChinaLab. of Atomic Imaging of Solids , Institute of Metal Research , Chinese Academy of Sciences , Shenyang110015 , ChinaState Key Laboratory for Corrosion and Protection , Institute of Corrosion and Protection of Metals , Chinese Academy of Sciences , Shenyang 110015 , China)Manuscript received 4 August 1995 , in revised form 6 April 1996

金属学报(英文版)

A Preliminary study of the effect of silicon additive on the structure and properites of C-B_4C-SiC composite was conducted. A liquid Phase has formed and the liquid Si reacts with C to form SiC at the grain boundary when sintering, which accelerates the sintering process and retards the grain growth. Consequently, the density and strength of the composite increase markedly. And the increase in the density increases the oxidation resistance and decreases the specific resistance of the composite. Furthermore,the C-B_4 C-SiC composite has good heat-shock resistance. The phenomena may be dueto the strengthening and toughening of microcracks.

关键词: :Si additive , null , null

在碳钢墓材上激光熔覆玻璃涂层及其物理化学行为研究

喻家庆

腐蚀学报(英文)

在碳钢墓材上激光熔覆玻璃涂层及其物理化学行为研究喻家庆(中国科学院金属腐蚀与防护研究所九三届博士,沈阳110015)LASERCLADGLASSCOATINGSONSTEELSANDTHEIRPHYSICAL—CHEMICALBEHAVIORS$(AstractofDissertationforDoctorofEngineeringatInstituteofCorrosionandProtectionofMetals,TheChineseAcademyofSciences,Shenyang110015)b

关键词:

The effect of environmental variables on atmospheric corrosion of carbon steel in Shenyang

Chinese Science Bulletin

A study was carried out in order to investigate the effect of contaminants and meteorological variables on the rust layer of carbon steel exposed in Shenyang urban atmosphere. Seven kinds of contaminants and twelve kinds of meteorological parameters were also registered in order to correlate the data with respect to corrosion rate and the stepwise multiple regression analysis was carried out in order to obtain the best regression model. The sum of rainfall time as well as sunshine time and the concentration of H(2)S could stimulate initial atmospheric corrosion of carbon steel. The initial atmospheric corrosion kinetics of carbon steel was observed to follow the cubic equation. The corrosion products were analyzed by XRD and the transformation of phases in different periods was discussed.

关键词: contaminants;meteorological parameters;carbon steel;urban atmospheric;corrosion;stepwise multiple regression;corrosion products;rust;pollution

CRYOGENIC MECHANICAL BEHAVIOUR OF MARAGING STEEL CONTAINING HYDROGEN

LIU Zhonghao CHEN Lian Institute of Metal Research , Academia Sinica , Shenyang , China

金属学报(英文版)

Within the range of 77 to 295 K,the strength and plastieity of 18Ni maraging steel increase with decreasing temperature and decrease with increasing hydrogen content.The susceptibility to hydrogen embrittlement of the maraged specimens is superior to solid solution ones.The dislocations after plastically deforming will tangle into dislocation cells which reduce thermselves in size as the temperature decreases,and coarsen as the hydrogen content in- creases.No cryogenie deformation twin was found.The tensile fracture surfaces of the solu- tion and maraged specimens containing 5.90 ppm hydrogen under 295 to 223 K are revealed as quasi-cleavage and intergranular features respectively and as transgranular ones under other experimental conditions.The influence of hydrogen on the mechanical behaviour of steel and the mechanism of hydrogen induced deformation and fracture are discussed. Research Assistant, Institute of Metal Research,Academia Sinica, Shenyang 110015,China

关键词: maraging steel , null , null , null

METALLOGRAPHIC STUDY ON SEGREGATION BEHAVIOUR OF P IN COLD-ROLLED Fe-P ALLOYS DURING ANNEALING

NING Hua ZHANG Lixin Institute of Corrosion and Protection of Metals , Academia Sinica , Shenyang , China

金属学报(英文版)

The segregation behaviour of P and its effect on structure of 70%-reduction cold rolled Fe-P alloys containing different contents of P,e.g.,0.007,0.06 and 0.09% P,during annealing at 200-700℃ under vacuum have been studied by means of metallography and EPMA.The P was found to segregate preferentially along dislocation line during recovery annealing.The P-riched dislocation densing region,the P-depleted region and the sub-grain-like boundary thus formed.The nuclei grow preferentially during recrystallization in such region that the P segregation is more evident and the residual strain by dislocation densing increases to large extent.After recrystallizing,the P segregates along grain boundaries and makes the grains in alloy fine. Engineer,Institute of Corrosion and Protection of Metals,Academia Sinica,Shenyang 110015,China

关键词: P , null , null , null

Characterisation of initial atmospheric corrosion carbon steels by field exposure and laboratory simulation

Corrosion Science

The early stages of the evolution of atmospheric corrosion of carbon steels exposed in both a laboratory simulated and a natural atmosphere environment in Shenyang have been observed by in situ scanning electron microscopy. In the case of laboratory cyclic wet-dry tests, even though the chloride content level is very low, filiform corrosion is initiated in the early stage. The filiform corrosion grows in random directions, forming a network of ridges. White nodules nucleate and grow on the ridges during continued corrosion and eventually connect with each other to form the initial corrosion scale. Pits were also found on the surface beneath corrosion products. In the case of a natural atmospheric environment, both filiform corrosion and other localized corrosion, such as pitting and inter-granular attack take place in the initial stage. It is obvious that there is variety of localized corrosion in the initial stage of atmospheric corrosion. (C) 2007 Elsevier Ltd. All rights reserved.

关键词: steel;atmospheric corrosion;initial stage;localized corrosion;in-situ;iron;electrolyte;thickness

原位生成金属间化合物/Fe-Cr-Ni复合材料的耐蚀性

杨霓虹 , 柯伟 , 张玉生

中国腐蚀与防护学报

原位生成金属间化合物/Fe-Cr-Ni复合材料的耐蚀性杨霓虹,柯伟,张玉生(西南交通大学成都610031)(中国科学院金属腐蚀与防护研究所沈阳110015)1前言铬、镍和铝含量很高的铁基合金在一定条件下可生成大量均匀分布的金属间化合物,形成原位生成的金属间化合物/Fe-Cr-Ni复合材料l‘].金属间化合物具有很高的硬度,而且耐蚀性良好,同具有优良耐蚀性的Fe-Cr-Ni合金基体复合所形成的?...

关键词: null , Intermetallics / Fe-Cr-Ni composite , Passivity

锌在SO_2污染环境中的腐蚀规律

王振尧 , 郑逸苹 , 刘寿荣

中国腐蚀与防护学报

锌在SO_2污染环境中的腐蚀规律王振尧,郑逸苹,刘寿荣(中国科学院金属腐蚀与防护研究所沈阳110015)1前言在我国西南地区,由于地理环境的影响,酸沉降日趋严重.含硫煤燃烧所排放的SO2造成雨水酸化,酸沉降引起的腐蚀问题受到人们关注.因此,在该地区进行材料的腐蚀研究具有重要的现实意义.SO。在高湿条件下对大多数金属和合金有强烈的加速腐蚀作用[1].Sherry等[2-4]就高湿条件下低浓度SO....

关键词: null , Zinc , SO_2 polluted environment

NiAl-20at%Fe合金的高温氧化与热腐蚀行为

王淑荷 , 郭建亭 , 赖万慧 , 谭明晖 , 李辉 , 孙超

中国腐蚀与防护学报

NiAl-20at%Fe合金的高温氧化与热腐蚀行为王淑荷,郭建亭,赖万慧,谭明晖李辉,孙超(中国科学院金属研究所沈阳110015)1引言NIAI金属间化合物具有熔点高、密度低、热传导性好和抗高温氧化能力优异等特点,是一种很有前途的航空航天耐热结构材料;但由于其室温塑性差,超过500oC时的高温强度低、限制了它们的应用I‘-3j.近年来发现加入Fe可提高NIAI的低温塑性,并提高其高温强度l‘?...

关键词: null , NiAl , Ni-Al-Fe , Oxidation , Hot corrosion

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