F. Zhang1)
,
X. D. Sun1)
,
J. You2)
,
Z. Zhang2)
,
L. X. Ding3)and Y. M. Wang3)1) School of Materials and Metallurgy
,
Northeastern University
,
Shenyang 110006
,
China2) Liaoning Analyzing and Testing Research Center
,
Shenyang 110015
,
China3) Department of Materials
,
School of Mechanical Engineering
,
Shenyang University
,
Shenyang 110044
,
China
金属学报(英文版)
Synthesis of a m m oniu m alu min u m carbonate hydroxide ( A A C H) w as investigated usinga m m oniu m alu min u m sulfate and a m moniu m hydro carbonate as the starting m aterials . Itw as found that A A C Hcan be synthesized by adding a m m oniu m alu m inu m sulfate solution torapidly stirred a m moniu m hydro - carbonate solution at a tem perature of 30 ℃. A A C Hcantransfor m to α Al2 O3 co m pletely by calcining at 1100 ℃ for 1 hour , and the obtained po w ders , with a particle size of 100 n m , can be sintered to 98 99 % relative density at 1500 ℃for 2 hours .
关键词:
a m moniu m alu m inu m carbonate hydroxide
,
null
,
null
,
null
Y. Q. Jia1)
,
J. G. Li1)
,
Y. M. Wang2)
,
L. X. Ding2)
,
X. M . Qin1) and X. D. Sun1)1) School of Materials and Metallurgy
,
Northeastern University
,
Shenyang 110006
,
China2) Department of Materials
,
School of Mechanical Engineering
,
Shenyang University
,
Shenyang 110044
,
China
金属学报(英文版)
Using yttriu m nitrate as the m other salt , synthesis of ultrafine yttria po w der through w et che mical route w as investigated . Choice of precipitant has dra m atic effects on co m position ,particle size distribution and particle m orphology of the precipitates . When a m m onia solutionw as used as the precipitant , the precursor precipitate w as m ainly Y2( O H) 5 14( N O3) 0 86· H2 O with co m paratively large particle size , broad size distribution and co m plex particleshapes . When sodiu m hydroxide solution w as used , roughly spherical α Y( O H)3·3 H2 Opre cipitate w ith sm all particle size and narro w size distribution w as obtained . The transfor m a tion sequence of dry α Y( O H)3 ·3 H2 O gel during calcination w as determ ined to be α Y( O H) 3·3 H2 O→ Y O O H→ Y2 O3 . After calcining at 600 ℃ for 1 hour , both Y2( O H) 5 14( N O3) 0 86· H2 O and α Y( O H) 3·3 H2 O transfor m to well crystallized Y2 O3 pow ders ,w ith particle sizes of 50 ～3000 n m and 20 n m , respectively .
关键词:
KEYW ORDS yttria
,
null
,
null
,
null
Chinese Science Bulletin
A study was carried out in order to investigate the effect of contaminants and meteorological variables on the rust layer of carbon steel exposed in Shenyang urban atmosphere. Seven kinds of contaminants and twelve kinds of meteorological parameters were also registered in order to correlate the data with respect to corrosion rate and the stepwise multiple regression analysis was carried out in order to obtain the best regression model. The sum of rainfall time as well as sunshine time and the concentration of H(2)S could stimulate initial atmospheric corrosion of carbon steel. The initial atmospheric corrosion kinetics of carbon steel was observed to follow the cubic equation. The corrosion products were analyzed by XRD and the transformation of phases in different periods was discussed.
关键词:
contaminants;meteorological parameters;carbon steel;urban atmospheric;corrosion;stepwise multiple regression;corrosion products;rust;pollution
