Z.Y. Lu 1)
,
S.M.An 2)
,
B.H.Cuo 2)
,
W.M.Li 1)
,
Y.Mei
,
Y.L.Xia 2) and J.Xu 2) 1) Department of Mechanical Engineering
,
Yangzhou University
,
Yangzhou 225009
,
China 2) Dalian University of Technology
,
Dalian 116024
,
China
金属学报(英文版)
This study raised a new assisted technique used for chemical vapor deposition (CVD) in which a laser beam irradiated the surface of substrate and simultaneously the plasma surroundings created in the reactive room, but both laser and plasma were at lower energy level in order to perform easily. The chemical vapor deposition reaction could be performed only just using simultaneously above two assisted methods. If not, the reaction could not be performed, too. It is laser plasma assisted chemical vapor deposition (LPCVD). For these reasons, a LPCVD device had been designed and manufactured, and was carried on practical operation. The results indicated that this technique is successful and feasible. Acting on the system of SiH 4 NH 3 N 2 with both CO 2 laser and RF plasma, expectant film of silicon nitride had been obtained on the surface of stainless steel.
关键词:
CVD
,
null
,
null
,
null
赵德文
,
郭长武
,
刘相华
,
王国栋
,
徐辉
,
戴建明
钢铁
开展了在空气和氮气两种气氛下，采用Gleeble-1500热模拟机与普通电炉两种加热方式、不同加热温度、加热时间对D2、M2、S5钢脱碳层深度影响的试验研究。依据试验结果，结合现场实际制定了较为合理的生产工艺并在现场成功应用，使上述模具扁钢脱碳层指标达到了美国ASTM-A681技术标准。
关键词:
脱碳层深度
,
模具扁钢
,
ASTM-A681
汪艳宁
,
张智超
,
苑宏英
,
靖大为
膜科学与技术
doi:10.16159/j.cnki.issn1007-8924.2016.06.003
以反映管道压降的系统模拟软件为工具,以特定基准系统参数及2 m/s管道流速为基础,分析了各种径流方向组合的反渗透系统运行工况,提出了全壳产水量与全壳错流比两个分别表征各壳元件污染速度与清污力度的运行指标,证明了各壳元件产水量失衡是其污染失衡的主要原因,明确了目前工程中常用的2 m/s流速管道系统中底层膜壳污染最重.
关键词:
反渗透系统
,
管道压降
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径流方向
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污染分布
Journal of Materials Research
MAX-phase carbides (M is an early transition metal, A is an A-group element) exhibit an interesting bonding characteristic of alternative stacking of strong M-C bonds and relatively weak M-A bonds in one direction. In the present first-principles total energy calculations, we establish the relationship between mechanical properties and electronic structure for ternary M(2)AC (M = Ti, V, Cr. A = Al, Si, P, S) carbides. By systematically tuning elements on the M and A sites, pronounced enhancements of bulk modulus, elastic stiffness, and ideal shear strength are achieved in V-containing V(2)AC (A = Al, Si, P, and S) carbides. It is suggested that tailoring on the A site is more efficient than on the M site in strengthening the mechanical properties of studied serial carbides. The results highlight a general trend for tailor-made mechanical properties of ternary M(2)AC carbides by control of chemical bonding.
关键词:
strength;solids;shear;dislocations;ti3sic2
张建
,
秦晓英
,
李地
,
辛红星
,
宋春军
材料科学与工程学报
层状结构TiS_2具有准二维结构,高热电势(室温时S≈250μV/K)和大的热电功率因子,作为热电材料具有很好的开发和应用前景.通过固相反应法,我们分别用原子量大于和小于Ti的原子部分替代Ti位引入替位缺陷(Ni_(Ti)",Al_(Ti)',Mg_(Ti)"),合成了不同元素替代掺杂化合物M_(0.04)Ti_(0.96)S_2(M=Ni,Al,Mg),在5-310K的温度范围内研究了各化合物的电阻率、热导率及热电势率与温度的对应关系.结果表明Ni、Al、Mg三种元素的掺杂均引起了主体材料从金属性到半导体导电性质的转变,且在低温范围内呈现莫特二维变程跳跃电导规律,In σ∝T~(-1/3),表明了TiS_2的二维导电机制.值得注意的是:①Mg、Al的掺杂引起了热电势绝对值的显著增高,特别是Al掺杂的化合物在310K时热电势率为-500μV/K,达到了纯TiS_2的200%;②Ni掺杂也在整个研究温区引起热导率的明显下降,而Mg、Al的掺杂却在整个研究温区引起热导率的明显升高.由于电阻率的增大,Ni、Al的掺杂均没能使得材料的ZT值有所提高,而Mg的掺杂明显地提高了TiS_2的ZT值,在310K其ZT值是纯TiS_2的1.6倍.这表明元素掺杂是提高材料的热电优值的有效途径之一.
关键词:
TiS_2
,
热电
,
电阻率
,
热导率
达力玛
,
白音孟和
人工晶体学报
在乙二胺溶剂体系中,180 ℃条件下合成了两种化合物[Mn (en)3]2[Sn2Se4S2](1)和[Co(en)3]2[Sn2Se4S2](2).通过X-射线单晶衍射、SEM、IR、TGA和UV-Vis等手段对其进行了表征.X-射线单晶衍射结果表明化合物1和2是类质同晶,均为正交晶系,并属于Pbca空间群,结构中均含有Sn和两种硫属元素S、Se组成的二聚体阴离子[Sn2Se4S2]2-.两种晶体的晶胞参数分别为:化合物1,a=1.6020(8) nm,b=1.1842(6) nm,c=1.9658(10) nm,Z=8;化合物2,a=1.549t(5) nm,b=1.1688(4) nm,c=1.18666(6) nm,Z=8.紫外-可见漫反射光谱研究结果表明,化合物1和2的禁带宽度分别为1.54 eV和1.64 eV,均有半导体性能.
关键词:
溶剂热合成
,
锡硫属化物
,
晶体结构
,
表征
Materials Letters
Secondary M,C precipitation was investigated in K40S cobalt-base alloy after 100 h aging at 950 degreesC. The results showed that it was closely related to the tungsten-rich zones inherited from the as-cast condition and the degeneration of the primary M7C3 carbide. A direct element reaction, 6M + C --> M6C, in which C comes from the decomposition of the M7C3 carbides, is suggested as the mechanism of secondary M6C precipitation in K40S alloy. (C) 2001 Elsevier Science B.V. All rights reserved.
关键词:
M6C precipitation;aging;M7C3 carbide;superalloy
WU Jianxin JIANG Bohong XU Zuyao (T.Y.Hsu) Shanghai Jiaotong University
,
Shanghai
,
China Associate Professor
,
Dept.of Materials Science and Engineering
,
Shanghai Jiaotong University
,
Shanghai
,
China
金属学报(英文版)
The effect of grain size and ordering of the parent phase on the critical points of thermoelastic martensitic transformation in Cu-25.62 Zn-3.97 Al-0.0018 B(wt-%)shape memory alloy has been investigated.Based on the thermodynamics of phase transformation,a linear rela- tionship between the starting temperature of martensitic transformation and the reciprocal of the square root of grain size is obtained,i.e.M_s temperature rises with increasing grain size. It shows a good agreement with the results of electric resistance measurement.Applying the Landau's theory,a quantitative relationship between M_s and the ordering parameter of the parent phase is set up,which is well confirmed by the results of X-ray diffraction and electric resistance measurement.The activation energy of the ordering process in the parent phase of the alloy is calculated to be 46 kJ/mol.
关键词:
Cu-Zu-Al
,
null
,
null
,
null
,
null
Ruijie ZHANG
,
Zhi HE
,
Zhongwei CHEN
,
Wanqi JIE
材料科学技术（英文）
A method to predict the solid-liquid interface stability during unidirectional solidification is developed by coupling M-S model with CALPHAD method. The method was applied to Al-0.38 Zn and Al-0.34 Si-0.14 Mg (wt pct) alloys, and the predicted results were compared with some former experimental data of the two alloys. The good agreement between the calculation results and the experimental data demonstrates the superiority of the present method to the classical one based on constant parameter assumptions.
关键词:
Interface stability
,
null
,
null
