Y.Chen X.Chen A.M.Guo D.X.Luo
,
B.F.Xu
,
Z.X.Yuan
,
P.H.Li
,
S.K.Pu
,
S.B.Zhou
金属学报(英文版)
The different chemical composition of silicon and manganese as well as different re-tained austenite fraction ranged from 4to 101163326174f the high strength and high elon-gation steels were studied in the paper.The dislocations and carbon concentration in retained austenite were observed by a transmission electron microscope and an electric probe analyzer,respectively.The experimental results showed that silicon and manganese are two fundamental alloying elements to stabilize austenite effectively but retaining austenite in different mechanis-↑ms.Meanwhile,the cooling processing played an important role in controlling the fraction of retained austenite of the hot-rolled high strength and high plasticity steels.
关键词:
high strength
,
null
,
null
材料科学技术(英文)
Creep testing was conducted on K40S alloy. The detailed creep deformation and fracture mechanisms under constant load were studied. The results show that the stress exponent ranges between 7 and 14.4 at elevated temperature 973similar to1173 K, and that the activation energy is approximately 449.1 kJ/mol. During creep, the grain boundary sliding cut off primary carbides at the boundary, generating the "O" model cracks. The creep failure mode of K40S alloy is transgranular ductile and cracks originate at the primary carbides. A long carbide and matrix interface is often a preferential path for crack propagation. The creep mechanism is discussed in light of the creep microstructure, the stress exponent and the activation energy.
关键词:
K40S alloy;creep;fracture;crack propagation;activation-energies;superalloy;term
王宝奇
,
谷南驹
,
郭素珍
,
马晓莉
金属学报
利用Bain点阵对应对K-S模型的晶格改建过程进行了严密的数学描述.对于不同的马氏体正方度,提出了计算第一切变、第二切变及晶格调整的计算依据,并给出了普遍的计算公式.以Fe-1.4C和纯铁为例,计算了马氏体相变的点阵畸变.进一步分析表明,K-S模型实质是Bain模型的旋转.计算的结果与实测的取向关系相符合.
关键词:
K-S模型
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null
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null
于静
,
司高华
,
黄云贵
,
刘东旭
应用化学
doi:10.3724/SP.J.1095.2011.00388
Pu(Ⅲ)、Pu(Ⅳ)、Pu(Ⅴ)和Pu(Ⅵ)在自然水的pH和Eh(氧化还原电势)值范围内能够共存.在自然环境中主要以Pu(Ⅴ)的PuO2(H2O)n+和Pu(Ⅳ)的Pu(OH)4形式存在.采用静态法测定了Pu(Ⅳ)和Pu(Ⅴ)在砂土介质中的分配系数Kd,Pu(Ⅳ)和Pu(Ⅴ)在砂土中的分配系数范围分别为5.5×103~4×104mL/g和3.2×103~1.1×104mL/g.表明在砂土介质中Pu(Ⅳ)的分配系数(Kd)大于Pu(Ⅴ)的,并且分配系数随砂土介质中粘土矿物含量的增加及介质颗粒粒径减小而增大.
关键词:
Pu(Ⅳ)
,
Pu(Ⅴ)
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砂土
,
分配系数
Corrosion Science
Arc ion plating had been employed on a cobalt-base superalloy K40S to deposit a NiCrAlYSi coating to improve its oxidation resistance at 1323-1423 K in air. The K40S superalloy had poor oxidation resistance because a non-protective and easy spalling surface oxides scale mixed of Cr2O3 and CoCr2O4 was formed on its surface. After coated with NiCrAlYSi coating, a dense and protective alpha-Al2O3 scale was formed on the coating and excellently improved its oxidation resistance. Inter-diffusion obviously occurred between the coating and the substrate K40S superalloy in oxidation process, which resulted from Co atoms in K40S outwards diffused. A richen Cr and W carbides inter-diffusion layer was formed, which could acted as a diffusion barrier that barred Al atoms in coating inwards diffusion. Though the NiCrAlYSi changed into NiCoCrAlYSi during oxidation process, it still possessed a good oxidation resistance and. had a considerable long-term life. (C) 2008 Elsevier Ltd. All rights reserved.
关键词:
cobalt-base superalloy K40S;NiCrAlYSi coating;arc ion plating;high;temperature oxidation;inter-diffusion;aluminide coatings;cyclic oxidation;alloys
Transactions of Nonferrous Metals Society of China
Fatigue crack propagation behavior of K40S cobalt-base superalloy under ambient atmosphere at 700 degreesC and 900 degreesC was investigated. The detailed fatigue crack propagation and fracture mechanism under the alternating loads were studied. The results show that, there is a defined threshold for K40S alloy at elevated temperatures. The fatigue threshold is 23. 9 MPa . m(1/2) at 700 degreesC and 12 MPa . m(1/2) at 900 V. The significant decrease of the threshold with increasing temperature is associated with the oxidation induced embrittlement at crack tip. Observation on the fatigue fracture surfaces indicates a ductile fracture mechanism related to the fatigue crack growth.
关键词:
cobalt-base superalloy;fatigue crack propagation;fatigue threshold;ductility;growth-behavior;alloy;steel