F.S.Liu
,
J.L.Xu
,
C.G.Zhou
,
S.K.Gong
,
H.B.Xu
金属学报(英文版)
The halide-activated pack cementation method is utilized to codeposit aluminum and silicon on Mo substrate. Emphasis is placed on the microstructure and elevated-temperature oxidation resistance of coatings. The results show that hexagonal Mo (Si, Al)2 as a main phase and a little amount of the lower disilicide Mo3Si3 was formed on Mo substrate through the halide-activated pack cementation method. The resultant Si-Al coating on Mo substrate exhibits excellent cyclic oxidation resistance. The excellent cyclic oxidation resistance of the coatings is attributed to the formation of alumina on the coatings during the oxidation.
关键词:
Mo(Si
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null
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null
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null
X.F.Bi
,
S.K.Gong
,
H.B.Xu
金属学报(英文版)
Fe-Cu thin films of 0.2μm in thickness with different Cu contents were prepared byusing r.f. magnetron sputtering onto glass substrate. The effect of sputtering param-eters, including Ar gas pressure and input rf power, on the structure and magneticproperties was investigated. It was found that when the power is lower than 70W,the structure of the films remained single bcc-Fe phase with Cu solubility of up to50at.%. TEM observations for the bcc-Fe phase showed that the grain size was inthe nanometer range of less than 20nm. The coercivity of Fe-Cu films was largelyaffected by not only Ar gas pressure but also rf power, and reached about 2.5Oe in thepressure of 0.67-6.67Pa and in the power of less than 100W. In addition, saturationmagnetization, with Cu content less than 60at.%, was about proportional to the con-tent of bcc-Fe. When Cu content was at 60at.%, however, saturation magnetizationwas much smaller than its calculation value.
关键词:
Fe-Cu thin film
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null
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null
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null
D.B.Zhang
,
S.K.Gong
,
H.B.Xu
金属学报(英文版)
Conventional two-layered structure thermal barrier coatings (TBCs) were preparedonto γ'-Ni3Al based alloy IC-6 by electron beam physical vapor deposition (EB-PVD).Isothermal oxidation and thermal cycling tests were carried out to investigate theeffect of Mo content at the interface between bond coat and ceramic top coat causedby diffusion. It has been found that the alloy coated with TBCs presented the lowestoxidation weight gain value for the reason that the ceramic top coat in TBC systemcan effectively stop Mo oxides evaporating. The life time of TBCs has close relationwith Mo content at the interface between the bond coat and top coat. Spallation ofceramic top coat occurred during thermal cyclic testing when Mo atoms accumulatedat the interface up to certain amount to decline the combination between the bond coatand top coat.
关键词:
EB-PVD
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null
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null
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null
材料科学技术（英文）
Creep testing was conducted on K40S alloy. The detailed creep deformation and fracture mechanisms under constant load were studied. The results show that the stress exponent ranges between 7 and 14.4 at elevated temperature 973similar to1173 K, and that the activation energy is approximately 449.1 kJ/mol. During creep, the grain boundary sliding cut off primary carbides at the boundary, generating the "O" model cracks. The creep failure mode of K40S alloy is transgranular ductile and cracks originate at the primary carbides. A long carbide and matrix interface is often a preferential path for crack propagation. The creep mechanism is discussed in light of the creep microstructure, the stress exponent and the activation energy.
关键词:
K40S alloy;creep;fracture;crack propagation;activation-energies;superalloy;term
王宝奇
,
谷南驹
,
郭素珍
,
马晓莉
金属学报
利用Bain点阵对应对K-S模型的晶格改建过程进行了严密的数学描述.对于不同的马氏体正方度,提出了计算第一切变、第二切变及晶格调整的计算依据,并给出了普遍的计算公式.以Fe-1.4C和纯铁为例,计算了马氏体相变的点阵畸变.进一步分析表明,K-S模型实质是Bain模型的旋转.计算的结果与实测的取向关系相符合.
关键词:
K-S模型
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null
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null
Corrosion Science
Arc ion plating had been employed on a cobalt-base superalloy K40S to deposit a NiCrAlYSi coating to improve its oxidation resistance at 1323-1423 K in air. The K40S superalloy had poor oxidation resistance because a non-protective and easy spalling surface oxides scale mixed of Cr2O3 and CoCr2O4 was formed on its surface. After coated with NiCrAlYSi coating, a dense and protective alpha-Al2O3 scale was formed on the coating and excellently improved its oxidation resistance. Inter-diffusion obviously occurred between the coating and the substrate K40S superalloy in oxidation process, which resulted from Co atoms in K40S outwards diffused. A richen Cr and W carbides inter-diffusion layer was formed, which could acted as a diffusion barrier that barred Al atoms in coating inwards diffusion. Though the NiCrAlYSi changed into NiCoCrAlYSi during oxidation process, it still possessed a good oxidation resistance and. had a considerable long-term life. (C) 2008 Elsevier Ltd. All rights reserved.
关键词:
cobalt-base superalloy K40S;NiCrAlYSi coating;arc ion plating;high;temperature oxidation;inter-diffusion;aluminide coatings;cyclic oxidation;alloys
