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INFLUENCE OF TIN ON THE HOT DUCTILITY OF A LOW-CARBON STEEL

Z.X.Yuan , J.Jia , A.M.Guo , D.D.Shen , S.H.Song , J.Liu

金属学报(英文版)

The influence of tin on the hot ductility of a 0.15wt steel is investigated using a continuous-casting thermal simulator with three cooling rates. Tin can apparently deteriorate the hot ductility of the steel. Non-equilibrium grain boundary segregation of tin occurs during cooling and plays an important role in reducing the hot ductility of the steel. There is a critical cooling rate for the Sn segregation being between 5 and 20K/s.

关键词: hot ductility , null , null

ANTIMONY GRAIN BOUNDARY SEGREGATION AND ITS SUPPRESSION BY CERIUM IN Fe—2Mn—Sb STRUCTURAL STEELS

Z.X.Yuan , A.M.Guo , J.Liu , D.D.Shen , J.Jia , S.H.Song

金属学报(英文版)

Antimony grain boundary segregation in Fe-2Mn-Sb stucture steels has been studied through measurements of the ductile-brittle transition temperature in conjunction with scanning electron microscopy ,Auger electron spectroscopy and secondary ion mass spectroscopy.The research result reveals that during tempering or ageing after quenching at 980℃,Sb segregates to grain boundaries with both equilibrium and nonequilibrium natures and brings about temper embrittlement in the steels.Cerium can relieve temper embrittlement of the steels and its segregation to grain boundaries may play an important role in reducing this embrittlement.

关键词: segregation , null , null

H2S应力腐蚀试验用H2S气通设计

孙耀峰

腐蚀学报(英文) doi:10.3969/j.issn.1002-6495.2001.z1.007

在满足H2S应力腐蚀试验的试验条件下,设计了H2S应力腐蚀实验室中H2S气体的通气装置.设计方案切实易行,安全可靠;实现了出口H2S气体的吸收再利用,减少了对环境的污染.

关键词: H2S气体 , 设计方案 , H2S应力腐蚀试验 , 环境保护

炼油工业中H_2S的腐蚀

郦建立

腐蚀学报(英文)

综述了含H2 S介质中材料的各种腐蚀形态 ,阐述了H2 S腐蚀发生的机理和影响因素 (外部环境 ,材料条件等 ) .介质温度和浓度对腐蚀有较大的影响 ;腐蚀过程中析出的H是引起SSCC的重要因素 ;硬度、夹杂和带状组织降低材料对H2 S腐蚀开裂的阻力 .

关键词: 硫化物应力腐蚀 , hydrogen induced cracking

H2S分压对油管钢CO2/H2S腐蚀的影响

张清 , 李全安 , 文九巴 , 白真权

腐蚀学报(英文)

1974-),男,硕士研究生,研究方向为腐蚀与防护.〖ZK)〗 Tel:0379-4231846〓E-mail:FQ)〗〖HT〗〖HJ〗〖HT5”SS〗 〖JZ(〗〖HT2H〗〖STHZ〗〖WTHZ〗 采用高温高压釜,辅以失重法和扫描电镜,对不同H2S分压下(1.4 kPa,20 kPa,60 kPa,120 kPa)油管钢N80、P110的CO2/H2S腐蚀进行了研究.结果表明,在试验H2S分压范围内,随着H2S分压的升高,两种钢的腐蚀速率先增后降,且都在H2S分压为20 kPa时取得最大值. 

关键词: H2S分压 , null , null , null

C-S-H 凝胶及其研究方法

杨南如

硅酸盐通报 doi:10.3969/j.issn.1001-1625.2003.02.011

在分析C-S-H凝胶的复杂性和特征的基础上,就测定它的化学组成、C-S-H凝胶中[SiO4]4-四面体的聚合度及其结构的化学和物理的方法作了简要介绍.现代各种测试方法的出现和使用,对C-S-H凝胶的组成和集中[SiO4]4-四面体的聚合结构有了较为完整的概念.

关键词: C-S-H凝胶 , 化学组成 , 凝胶结构 , 测定方法

H2S分压对油管钢CO2/H2S腐蚀的影响

张清 , 李全安 , 文九巴 , 白真权

腐蚀学报(英文) doi:10.3969/j.issn.1002-6495.2004.06.015

采用高温高压釜,辅以失重法和扫描电镜,对不同H2S分压下(1.4 kPa,20 kPa,60 kPa,120kPa)油管钢N80、P110的CO2/H2S腐蚀进行了研究.结果表明,在试验H2S分压范围内,随着H2S分压的升高,两种钢的腐蚀速率先增后降,且都在H2S分压为20 kPa时取得最大值.

关键词: H2S分压 , N80钢 , P110钢 , CO2/H2S腐蚀速率

HCl-H2S-H2O体系中HCl与H2S对20碳钢腐蚀的交互作用

郭金彪 , 李艳

材料保护

目前有关HCl-H2S-H2O体系中HCl与H2S对碳钢腐蚀的交互作用的试验数据较少.利用电化学方法测试了20碳钢在90℃,不同浓度的HCl,H2S单一腐蚀液及HCl和H2S混合腐蚀液中的腐蚀速率,分析了HCl-H2S-H2O体系中HCl与H2S对20碳钢腐蚀的交互作用.结果表明:20碳钢在单一的HCl或H2S腐蚀液中的腐蚀速率随HCl或H2S浓度的增大而增大;在HCl-H2S-H2O体系中,不论H2S浓度高低,HCl的存在均会促进H2S对20碳钢的腐蚀;只有当HCl的浓度较低(≤248.72 mg/L)时,H2S的存在才会促进HCl对20碳钢的腐蚀;而当HCl浓度较高(≥499.16 mg/L)时,H2S的存在不仅不会促进HCl对20碳钢的腐蚀,还会在一定程度上起阻碍作用.

关键词: 20碳钢 , HCl , H2S , 腐蚀 , 交互作用

Sulfidation behavior of Fe-40Al sheet in H-2-H2S mixtures at high temperatures

Intermetallics

The sulfidation behavior of a 200 mum thick Fe-40at.%Al sheet has been investigated at temperatures between 973 K and 1273 K in H-2-H2S mixtures with H,S contents of 0.052-9.7vol%. The Fe-40Al sheet exhibited excellent sulfidation resistance at temperatures below 1073 K in all the H2S-H-2 mixtures. This may be attributed to the formation of a thin alumina film on the surface of the Fe-40Al sheet during sulfidation, identified by AES analysis. At temperatures higher than 1173 K, the Fe-40Al sheet also exhibited good sulfidation resistance in the 0.052%H2S-H-2, mixture. and there was only a slight increase in mass gain with tempe rat Lire. This compares favorably with Fe-200-11Al (in at.%) foil which was severely sulfidized even at 973 K in the 0.052% H2S-H-2 mixture, and showed markedly increased mass gain with increased H2S content and temperature. (C) 2004 Elsevier Ltd. All rights reserved.

关键词: iron aluminides (based on FeAl);corrosion;fe-al alloys;corrosion behavior;oxidation behavior;iron aluminides;sulfur vapor;al2o3 scales;1273 k;atmospheres

H_2S石油套管钢的设计

褚武扬 , 王燕斌 , 关永生 , 阎应龙

金属学报

理论研究表明,为满足高强度抗H2S套管钢的使用要求,可选用C,Mn,Cr和Mo为合金元素,要求S,P和Si的含量尽量低,回火温度尽量高.本文用正交设计来确定C,Mn,Cr和Mo的范围.用国外同类钢种的数据代管实验室试验进行正交分析.按设计的成分直接进行批量生产,获得成功,在两年内完成了新钢种的设计,开发和使用.

关键词: H_2S , C90 tubular steel , alloy design

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