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THE STUDY OF ELECTROLESS NICKEL ACCELERATING AGENT

Q. Zhang , S. Guan and S.M. Li Beijing University Of Aeronautics And Astronautics , Beijing 100083 , China

金属学报(英文版)

The effects of accelerating agent on the deposition speed of Electroless Nickel Plating, the stability of solution and the corrosion resistant of The EN coatings were studied. The influence of A1 content on EN activation energy, the rest potential and polarization cures are measured. The mechanism of the acceleration effect of A1 on the EN plating was proposed.

关键词: electroless nickel plating , null

CORRELATION BETWEEN STRESS COMPONENTS AND STRESS CORROSION CRACKS IN BRASS Lecturer,Department of Materials Physics,University of Science and Technology Beijing,Beijing 100083,China

QIAO Lijie LIU Rui XIAO Jimei University of Science and Technology Beijing , Beijing , China

金属学报(英文版)

The effects of stress components on nucleation sites and propagation directions of stress cor- rosion cracks in brass were investigated with specimens under mode Ⅱ and mode Ⅲ loadings. The results indicated that under mode Ⅱ loading,stress corrosion cracks nucleated on the site with maximum normal stress component and propagated along the plane perpendieular to the maximum normal stress,under mode Ⅲ loading,the stress corrosion crack was not evident on the 45°plane due to the general corrosion in aqueous solution with high NH_4OH concentra- tion,while stress corroded in aqueous solution with low NH_4OH concentration, numerous cracks with spacings of 10—150μm were found on the 45°plane with maximum normal stress and no stress corrosion cracks was observed on the plane with maximum shear stress.

关键词: stress corrosion cracking , null , null , null

Li_2S-GeS_2-LiI和Li_2S-GeS_2-LiBr-LiI系统玻璃的电导率

杨如玺

材料研究学报

实验得知0.5Li_2S-0.5GeS_2玻璃的电导率高于0.4Li_2S-0.6GeS_2玻璃的电导率。当在这两种组成的玻璃中分别掺杂LiI 后,则后者的电导率可高于前者。在0.4Li_2S-0.6GeS_2玻璃中同时掺杂LiBr 和LiI 后,其电导率约为掺杂一种同量盐玻璃电导率的两倍。本文用弱电解质理论解释了Li_2S-GeS_2玻璃经掺杂LiBr 和LiI 后电导率变化的原因。

关键词: 解离常数 , activity , ameliorator(modification) , organisator(formation) , transition temperature(transus temperature).

A flexible nanostructured sulphur-carbon nanotube cathode with high rate performance for Li-S batteries

Energy & Environmental Science

We report the template-directed synthesis of sulphur-carbon nanotubes and their use to form a membrane that is binder-free, highly conductive and flexible. This nanostructured membrane is used as a self-supporting cathode without metal current-collectors for Li-S batteries. The membrane cathode has a high electrical conductivity and renders a long life of sulphur of over 100 charge-discharge cycles. High discharge capacity of sulphur was attained at 712 mA h g(sulphur)(-1) (23 wt% S) and 520 mA h g(sulphur)(-1) (50 wt% S) at a high current density (6 A g(sulphur)(-1)). The overall capacity of the flexible cathode correspondingly reaches 163 mA h g(-1) (23 wt% S) and 260 mA h g(-1) (50 wt% S). These results demonstrate the great potential of this nanostructured flexible membrane as a cathode for Li-S batteries with fast charge-discharge performance and long life.

关键词: rechargeable lithium batteries;positive electrode materials;cell;temperature;composites;capacity;oxide

Secondary M6C precipitation in K40S cobalt-base alloy

Materials Letters

Secondary M,C precipitation was investigated in K40S cobalt-base alloy after 100 h aging at 950 degreesC. The results showed that it was closely related to the tungsten-rich zones inherited from the as-cast condition and the degeneration of the primary M7C3 carbide. A direct element reaction, 6M + C --> M6C, in which C comes from the decomposition of the M7C3 carbides, is suggested as the mechanism of secondary M6C precipitation in K40S alloy. (C) 2001 Elsevier Science B.V. All rights reserved.

关键词: M6C precipitation;aging;M7C3 carbide;superalloy

INFLUENCE OF GRAIN SIZE AND ORDERING OF PARENT PHASE ON M_s IN A CuZnAl ALLOY CONTAINING BORON

WU Jianxin JIANG Bohong XU Zuyao (T.Y.Hsu) Shanghai Jiaotong University , Shanghai , China Associate Professor , Dept.of Materials Science and Engineering , Shanghai Jiaotong University , Shanghai , China

金属学报(英文版)

The effect of grain size and ordering of the parent phase on the critical points of thermoelastic martensitic transformation in Cu-25.62 Zn-3.97 Al-0.0018 B(wt-%)shape memory alloy has been investigated.Based on the thermodynamics of phase transformation,a linear rela- tionship between the starting temperature of martensitic transformation and the reciprocal of the square root of grain size is obtained,i.e.M_s temperature rises with increasing grain size. It shows a good agreement with the results of electric resistance measurement.Applying the Landau's theory,a quantitative relationship between M_s and the ordering parameter of the parent phase is set up,which is well confirmed by the results of X-ray diffraction and electric resistance measurement.The activation energy of the ordering process in the parent phase of the alloy is calculated to be 46 kJ/mol.

关键词: Cu-Zu-Al , null , null , null , null

Prediction of Solid-Liquid Interface Stability by Coupling M-S Model with CALPHAD Method

Ruijie ZHANG , Zhi HE , Zhongwei CHEN , Wanqi JIE

材料科学技术(英文)

A method to predict the solid-liquid interface stability during unidirectional solidification is developed by coupling M-S model with CALPHAD method. The method was applied to Al-0.38 Zn and Al-0.34 Si-0.14 Mg (wt pct) alloys, and the predicted results were compared with some former experimental data of the two alloys. The good agreement between the calculation results and the experimental data demonstrates the superiority of the present method to the classical one based on constant parameter assumptions.

关键词: Interface stability , null , null

反渗透系统的2m/s流速管道与径流方向模拟分析

汪艳宁 , 张智超 , 苑宏英 , 靖大为

膜科学与技术 doi:10.16159/j.cnki.issn1007-8924.2016.06.003

以反映管道压降的系统模拟软件为工具,以特定基准系统参数及2 m/s管道流速为基础,分析了各种径流方向组合的反渗透系统运行工况,提出了全壳产水量与全壳错流比两个分别表征各壳元件污染速度与清污力度的运行指标,证明了各壳元件产水量失衡是其污染失衡的主要原因,明确了目前工程中常用的2 m/s流速管道系统中底层膜壳污染最重.

关键词: 反渗透系统 , 管道压降 , 径流方向 , 污染分布

D2、M2、S5模具扁钢脱碳特性实验研究

赵德文 , 郭长武 , 刘相华 , 王国栋 , 徐辉 , 戴建明

钢铁

开展了在空气和氮气两种气氛下,采用Gleeble-1500热模拟机与普通电炉两种加热方式、不同加热温度、加热时间对D2、M2、S5钢脱碳层深度影响的试验研究。依据试验结果,结合现场实际制定了较为合理的生产工艺并在现场成功应用,使上述模具扁钢脱碳层指标达到了美国ASTM-A681技术标准。

关键词: 脱碳层深度 , 模具扁钢 , ASTM-A681

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